研究目的
To examine the optical and colour properties of gelatine gels prepared in saline solutions containing different transition metal chlorides and to investigate the effects of salt type and concentration on these properties.
研究成果
The properties of gelatine gels depend on salt type and concentration, with improved thermal stability and tunable optical/color properties. Gels can be used in optical thermometers, retroreflectors, laser components, and OLED coatings.
研究不足
The study focuses on specific metal chlorides and concentrations; toxicity of metal salts was noted but not fully investigated; applications may be limited by gel strength reduction and environmental factors.
1:Experimental Design and Method Selection:
Gelatine gels were prepared by gelation in solutions of NiCl2·6H2O, CoCl2·6H2O, and CrCl3·6H2O at concentrations of 5% to 50%. Properties were analyzed using FTIR spectroscopy, TGA, UV-vis spectroscopy, and colorimetry.
2:0%. Properties were analyzed using FTIR spectroscopy, TGA, UV-vis spectroscopy, and colorimetry. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: Gelatine type B food-grade powder (E. Merck) and metal chlorides (Strem Chemicals Inc.) were used. Samples were classified into three groups based on salt type.
3:List of Experimental Equipment and Materials:
Gelatine powder, metal chlorides, double-distilled water, autoclave (HL-320), water bath, glass dishes, micro-analytical balance (Sartorius), TGA instrument (TA-50, Shimadzu), FTIR spectrophotometer (FTIR-8400S, Shimadzu), UV-vis spectrophotometer (Perkin-Elmer 4-B).
4:Experimental Procedures and Operational Workflow:
Gelatine and salts were dissolved separately, sterilized, mixed, sterilized again, poured into dishes, and incubated to form gels. TGA was performed in nitrogen atmosphere, FTIR from 400 to 4000 cm?1, UV-vis from 200 to 800 nm.
5:Data Analysis Methods:
TGA data analyzed using Coats-Redfern equation for thermodynamic parameters; FTIR spectra interpreted for structural changes; UV-vis data used for Tauc plots to calculate band gaps and Urbach energies; color parameters calculated using CIE 1931 system.
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