1：Experimental Design and Method Selection:

The study involved synthesizing a new fluorodiol (FMPG) and then using it along with hydroxypropyl-terminated polysiloxane (PSi), isophorone diisocyanate (IPDI), and hydroxyethyl methacrylate (HEMA) to prepare fluorine-silicon block urethane acrylates. UV-curing was employed with a high-pressure mercury lamp.

2：Sample Selection and Data Sources:

Materials included PFOA, AMPG, IPDI, DBTDL, EEDQ, HEMA, HFMA, 1173 photoinitiator, PSi, and various solvents. Samples were prepared with different FMPG contents (O1, O2, O3).

3：3). List of Experimental Equipment and Materials:

3. List of Experimental Equipment and Materials: Equipment included FT-IR spectrometer (Nicolet 5700), NMR spectrometer (Avance III HD 600 MHz), GPC instrument (Agilent), UV-vis spectrophotometer (UV-3600), TGA system (Rigaku Thermo Plus TG8120), tensile tester (SANS E

4：503), contact angle goniometer (JC2000-CG400), and high-pressure mercury lamp (500 W). Materials as listed in Section Experimental Procedures and Operational Workflow:

Synthesis of FMPG via amidation, synthesis of oligomers via reaction in THF with DBTDL catalyst, UV-curing process with specific weight ratios and irradiation conditions, followed by characterization using FT-IR, NMR, GPC, UV-vis, TGA, mechanical testing, contact angle measurements, and anti-adhesive tests.

5：Data Analysis Methods:

FT-IR and NMR for structural confirmation, GPC for molecular weight analysis, UV-vis for transmittance, TGA for thermal stability, tensile testing for mechanical properties, contact angle measurements for surface energy calculation using Owens and Wendt method, and peel strength tests for anti-adhesive performance.