研究目的
To develop a multifunctional cotton fabric with enhanced properties for photodegrading organic pollutants, UV shielding, and self-cleaning by immobilizing BiOI nanosheets using the SILAR method.
研究成果
The BiOI/SMD-C fabric demonstrated high photocatalytic efficiency (99% RhB degradation), excellent UV protection (UPF > 50), and superhydrophobicity, making it a promising multifunctional protective material. Future work could explore other substrates and long-term stability.
研究不足
The study is limited to cotton fabric and specific conditions; scalability and durability under real-world conditions were not extensively tested. The use of specific reagents and equipment may constrain broader application.
1:Experimental Design and Method Selection:
The study used the successive adsorption and reaction (SILAR) method to immobilize BiOI nanosheets on cotton fabric treated with NaOH and urea for micro-dissolution. This method was chosen for its ability to uniformly deposit nanosheets at room temperature.
2:Sample Selection and Data Sources:
Cotton knitted fabric (150 g/m2) was obtained from Lu Thai Textile Co., LTD. Reagents including potassium iodide (KI), bismuth nitrate pentahydrate (Bi(NO3)3·5H2O), sodium hydroxide (NaOH), and urea were analytical grade from Sinopharm Chemical Reagent Co., Ltd.
3:List of Experimental Equipment and Materials:
Equipment included SEM (TM-1000, Hitachi), FESEM (S-4800, Hitachi), XRD (Rigaku D/max-2500PC), UV-Vis DRS (Lambda 35, PerkinElmer), Raman spectrometer (Thermo Fisher DXR2xi), TGA (DSC204FI), XPS (Thermo ESCALAB 250), UV transmittance tester (UV-1000F), contact angle analyzer (DSA30, Kruss), and a 500 W Xe lamp with UV cut-off filter (Shanghai Bilon instruments Ltd.). Materials included cotton fabric, chemicals for treatment and synthesis.
4:Experimental Procedures and Operational Workflow:
Cotton fabric was treated with urea/NaOH solution at -10°C for micro-dissolution, washed, and dried. BiOI nanosheets were immobilized via SILAR cycles (0 to 20 cycles) at room temperature, involving adsorption of Bi3? ions, rinsing, reaction with I? ions, and washing. Samples were characterized using SEM, XRD, UV-Vis DRS, Raman, TGA, XPS. Photocatalytic tests involved degrading RhB under visible light, UV shielding was measured, and hydrophobicity was assessed via contact angle measurements.
5:Data Analysis Methods:
Data were analyzed using UV-Vis spectrophotometry for RhB concentration, calculations for UPF and transmittance, and kinetic analysis for photodegradation rates. Statistical methods included standard deviations for contact angles.
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SEM
TM-1000
Hitachi
Investigate sample morphology
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FESEM
S-4800
Hitachi
Investigate sample morphology with energy dispersive X-ray spectroscopy
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XRD
D/max-2500PC
Rigaku
Study phase structures of samples
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UV-Vis DRS
Lambda 35
PerkinElmer
Obtain diffuse reflection spectra
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Raman Spectrometer
DXR2xi
Thermo Fisher
Obtain Raman spectra
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XPS
ESCALAB 250
Thermo
Perform X-ray photoelectron spectroscopy
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TGA
DSC204FI
Determine weight percentages by thermal gravimetric analysis
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UV Transmittance Tester
UV-1000F
Measure UV transmittance of samples
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Contact Angle Analyzer
DSA30
Kruss
Measure contact angles between water and sample surfaces
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Xe Lamp
500 W with UV cut-off filter (400 nm)
Shanghai Bilon instruments Ltd.
Serve as visible light source for photocatalytic tests
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