1：Experimental Design and Method Selection:

The study employed an electrostatic assembly strategy to construct ReS2/CN heterojunctions, utilizing electrostatic and coordination interactions between CN and ReS2. Theoretical models included energy band level analysis and charge transfer mechanisms.

2：Theoretical models included energy band level analysis and charge transfer mechanisms. Sample Selection and Data Sources:

2. Sample Selection and Data Sources: Pure CN and ReS2 were prepared using reported methods. Re/CN heterojunctions were synthesized by dispersing ReS2 and CN powders in ethanol, followed by ultrasonication, boiling evaporation, and drying.

3：List of Experimental Equipment and Materials:

Materials included urea, thiourea, rhodamine B, salicylic acid, ethanol, ethylene glycol, PEDOT-PSS, NH4ReO4, DMPO, and TEMP. Equipment included XRD diffractometer, pH meter, zeta potential analyzer, XPS spectrometer, SEM, TEM, HRTEM, UV-vis spectrophotometer, PL spectrophotometer, time-resolved spectrofluorometer, N2 sorption analyzer, EPR spectrometer, electrochemical workstation, and photocatalytic reaction apparatus.

4：Experimental Procedures and Operational Workflow:

Samples were characterized using XRD, FT-IR, zeta potential, XPS, SEM, TEM, UV-vis, PL, time-resolved PL, N2 sorption, EPR, photoelectrochemical tests, and photocatalytic degradation experiments. Photocatalytic performance was evaluated by degrading RhB and SA under visible light irradiation.

5：Data Analysis Methods:

Data were analyzed using pseudo-first-order kinetics for degradation rates, bi-exponential model for PL lifetimes, and Mott-Schottky plots for energy band levels. Statistical analysis and software tools were not specified.