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Direct Hot-Injection Synthesis of Lead Halide Perovskite Nanocubes in Acrylic Monomers for Ultrastable and Bright Nanocrystal–Polymer Composite Films

DOI:10.1021/acsami.8b20681 期刊:ACS Applied Materials & Interfaces 出版年份:2019 更新时间:2025-11-14 17:03:37
摘要: In recent years, lead halide perovskite nanocrystals (NCs) have attracted significant attention in both fundamental research and commercial applications due to their excellent optical and optoelectrical properties. However, the protective ligands on the surface of the perovskites NCs could be easily removed after the tedious process of centrifugation, separation, and dispersion, which greatly hampers their stability against light, heat, moisture, and oxygen and limits their practical applications. Here we report a new post-processing-free strategy (i.e., without centrifugation, separation, and dispersion process) of using an UV-polymerizable acrylic monomer of lauryl methacrylate (LMA) as the solvent to synthesize CsPbBr3 NCs, and then adding polyester polyurethane acrylates oligomer, monomer (IBOA) and initiator for directly UV polymerization to fabricate NC-polymer composite films. These films exhibited an improved photoluminescence quantum yield (85-90%) than classic NC-film (40-50%), which were processed using octadecene (ODE) as the solvent for NC synthesis and post-processed for UV polymerization. Significantly, the as-fabricated films by post-processing-free strategy exhibited excellent photostability against strong Xe lamp illumination; while the other films using classic methods were quickly photo-degraded. Meanwhile, these NC-polymer composite films showed good stability against moisture and heating when aging in water at 50oC for over 200 hours. These films, along with K2SiF6:Mn4+ (KSF) phosphor emitters, were used as downconverters for blue LEDs in liquid crystal displays with a wide color gamut of 115% in the International Commission on Illumination (CIE) 1931 color space. This work provides a facile and effective strategy for the preparation of ultrastable and bright color-conversion NC films for the development of the next-generation wide color gamut displays.
作者: Jianyu Tong,Jiajing Wu,Wei Shen,Yukang Zhang,Yao Liu,Tao Zhang,Shuming Nie,Zhengtao Deng
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To develop a post-processing-free strategy for synthesizing lead halide perovskite nanocrystals (NCs) and fabricating ultrastable and bright NC-polymer composite films for wide color gamut display applications, addressing the stability issues of perovskite NCs against light, heat, moisture, and oxygen.

The post-processing-free strategy using LMA as a solvent for synthesizing CsPbBr3 NCs and fabricating NC-polymer composite films results in high PLQY (85-90%), excellent photostability, and good resistance to moisture and heat. The films enable wide color gamut (115% in CIE 1931) LCD backlights, outperforming commercial CdSe-based displays. This approach provides a facile and effective method for developing stable perovskite NC-based optoelectronic devices, with potential for further improvements in device engineering.

The thermal stability of the films decreases at higher temperatures (e.g., PLQY drops to 48.3% after heating at 100°C for 5 hours). The method may not fully eliminate all nonradiative pathways, and scalability for industrial production is not addressed. Potential optimization areas include improving high-temperature stability and extending the method to other perovskite compositions.

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