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Synthesis of visible light responsive iodine-doped mesoporous TiO2 by using biological renewable lignin as template for degradation of toxic organic pollutants

DOI：10.1016/j.apcatb.2019.04.034 期刊：Applied Catalysis B: Environmental 出版年份：2019 更新时间：2025-11-14 17:03:37
摘要： The visible light responsive I-doped mesoporous TiO2 (I/TiO2-T) catalysts were synthesized by facile hydrolysis method with lignin as a template. The resulting I/TiO2-T catalysts synthesized from different amounts of I as a dopant and lignin as a template were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-Vis diffuse spectroscopy (DRS), Fourier transform infrared spectroscopy (FTIR), photoluminescence (PL), and electrochemical impedance spectroscopy (EIS). The photocatalytic activities of the resulting catalysts were investigated by the degradation of p-chlorophenol under artificial visible light irradiation. The results showed that the lignin-templated TiO2 with a suitable amount of I-doping (I/TiO2-T) had higher catalytic activity than the catalyst prepared form I-doped TiO2 without lignin template (I/TiO2). Complete degradation of p-chlorophenol was achieved by I/TiO2-T with suitable amount of I-doping at 60 min. However, 95.7, 10.7, and 5.5% of the p-chlorophenol was degraded with I/TiO2, TiO2-T, and P25 catalysts, respectively, under 140 min visible light irradiation. The enhanced catalytic activities of the samples with template and I-doping may be due to the small grain size and high specific surface area of the catalysts. The band gap and the electrical properties of TiO2 also could be adjusted with I-doping. The I-doped TiO2 with the extrinsic I5+-to-Ti4+ and the iodine-to-oxygen donor defects could be excited by visible irradiation for efficient pollutants degradation. A possible photocatalytic mechanism for the degradation of the pollutants with I/TiO2-T under visible light irradiation was also proposed.
作者： Xiaoyun Chen，Huizhi Sun，Jubin Zhang，Osman Ahmed Zelekew，Dongfang Lu，Dong-Hau Kuo，Jinguo Lin
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研究目的

Synthesis of visible light responsive iodine-doped mesoporous TiO2 by using biological renewable lignin as template for degradation of toxic organic pollutants.

研究成果

The I/TiO2-T catalyst with optimal I-doping (Ti/I=5/2) and lignin template exhibited superior photocatalytic activity under visible and solar light, achieving complete degradation of p-chlorophenol in 60 min. Enhancements are attributed to smaller grain size, high specific surface area, mesoporous structure, and adjusted band gap from I-doping defects (I5+ and I?). The lignin template inhibited phase transformation and agglomeration. The catalyst showed good reusability and pH stability. This approach provides a promising method for efficient pollutant degradation using renewable resources.

研究不足

The study focuses on specific pollutants (p-chlorophenol, nitrobenzene, phenol) and may not generalize to all organic pollutants. The optimal I-doping ratio (Ti/I=5/2) is specific to the synthesis conditions, and deviations could reduce efficiency. Calcination temperature optimization (600°C) might not apply to other templates or dopants. The use of artificial visible light (filtered Xe lamp) may not fully replicate natural solar conditions. Reusability tests showed slight activity decrease after multiple runs, indicating potential catalyst degradation over time.

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