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Simplification and experimental investigation of geometrical surface smoothness model for multi-track laser cladding processes
摘要： The formation of large area parts requires construction of multi-track laser cladding layers which are significantly influenced by the overlapping coefficient. The geometrical model of optimal overlap ratio to obtain least surface fluctuation of multi-track claddings is derived into a simpler form in terms of the aspect ratio of single-track clads. The error analysis further demonstrates the effectiveness of these models. Multi-track single layer claddings are fabricated at a series of overlap ratios under two process conditions. The surface states of cladding layers are then evaluated by two types of smoothness definitions with two fitting methods to study the optimal overlap ratios. The results show that the experimental optimum conditions identified by two methods are slightly different from each other. The theoretical prediction is in good agreement with the experimental one when the aspect ratio is great enough to support the model assumptions.
关键词： Laser cladding,Multi-track clads,Overlap ratio,Geometrical model,Surface smoothness
更新于2025-11-28 14:24:20
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Optimization of Residual Stresses in Laser-Mixed WC(Co, Ni) Coatings
摘要： A ternary mixture of tungsten carbide (WC), cobalt (Co), and nickel (Ni) powders is prepared to form ceramic-metal composite coatings employed for laser cladding of 40Cr steel. This coating is investigated using the mixture design to evaluate the influence of its ratios on the residual stresses in the clads. The WC/Co/Ni ternary mixture exhibits higher residual stresses than those of the Co/Ni or WC/Ni binary mixtures, except for the WC/Co one. Single WC, Co, or Ni designs illustrate a high sensitivity of residual stresses, cracks pass through the interior of WC particles rather than around them, and the cracks mostly propagate along the eutectic phases at 50%Co–50%WC. A reduced special quartic model in the mixture design exhibits excellent fit, predicted and experimental values of residual stresses for these laser clads are in good agreement.
关键词： residual stress optimization,mixture,reduced special quartic model,tungsten carbide
更新于2025-11-28 14:24:20
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Low-level laser therapy affects dentinogenesis and angiogenesis of in vitro 3D cultures of dentin-pulp complex
摘要： To investigate the effects of gallium-aluminum-arsenide (GaAlAs) diode laser low-level laser therapy (LLLT) on angiogenesis and dentinogenesis of the dentin-pulp complex in a human tooth slice-based in vitro model. Forty tooth slices were prepared from 31 human third molars. Slices were cultured at 37 °C, 5% CO2, and 95% humidity and randomly assigned to one of the following groups: group I: no laser treatment, group II: 660-nm diode laser; energy density = 1 J/cm2, group III: 660-nm diode laser; energy density = 3 J/cm2, group IV: 810-nm diode laser; energy density = 1 J/cm2 and group V: 810-nm diode laser; energy density = 3 J/cm2. LLLT was applied on the third and fifth days of culture. After 7 days, tissues were retrieved for real-time RT-PCR analysis to investigate the expression of VEGF, VEGFR2, DSPP, DMP-1, and BSP in respect to controls. Lower energy density (1 J/cm2) with the 660 nm wavelength showed a statistically significant up-regulation of both angiogenic (VEGF: 15.3-folds and VEGFR2: 3.8-folds) and odontogenic genes (DSPP: 6.1-folds, DMP-1: 3-fold, and BSP: 6.7-folds). While the higher energy density (3 J/cm2) with the 810 nm wavelength resulted in statistically significant up-regulation of odontogenic genes (DSPP: 2.5-folds, DMP-1: 17.7-folds, and BSP: 7.1-folds), however, the angiogenic genes had variable results where VEGF was up-regulated while VEGFR2 was down-regulated. Low-level laser therapy could be a useful tool to promote angiogenesis and dentinogenesis of the dentin-pulp complex when parameters are optimized.
关键词： Low-level laser therapy,Dentinogenesis,Dentin-pulp complex,Angiogenesis,Tooth slice model
更新于2025-11-25 10:30:42
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Screening of two-photon activated photodynamic therapy sensitizers using a 3D osteosarcoma model
摘要： Photodynamic therapy (PDT) involves a photosensitizing agent activated with light to induce cell death. Two-photon excited PDT (TPE-PDT) offers numerous benefits compared to traditional one-photon induced PDT, including an increased penetration depth and precision. However, the in vitro profiling and comparison of two-photon photosensitizers (PS) are still troublesome. Herein, we report the development of an in vitro screening platform of TPE-PS using a 3D osteosarcoma cell culture. The platform was tested using three different two-photon (2P) active compounds – a 2P sensitizer P2CK, a fluorescent dye Eosin Y, and a porphyrin derivative (TPP). Their 2P absorption cross-sections (σ2PA) were characterised using a fully automated z-scan setup. TPP exhibited a remarkably high σ2PA at 720 nm (8865 GM) and P2CK presented a high absorption at 850 nm (405 GM), while Eosin Y had the lowest 2P absorption at the studied wavelengths (<100 GM). The cellular uptake of PS visualized using confocal laser scanning microscopy showed that both TPP and P2CK were internalized by the cells, while Eosin Y stayed mainly in the surrounding media. The efficiency of the former two TPE-PS was quantified using the PrestoBlue metabolic assay, showing a significant reduction in cell viability after two-photon irradiation. The possibility of damage localization was demonstrated using a co-culture of adipose derived stem cells together with osteosarcoma spheroids showing no signs of damage to the surrounding healthy cells after TPE-PDT.
关键词： two-photon excited photodynamic therapy,PrestoBlue assay,photosensitizers,cellular uptake,localized damage,z-scan,3D osteosarcoma model
更新于2025-11-21 11:08:12
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Electric and dielectric characteristics of Al/ZrO2/IL/n-Si MOS capacitors using three-frequency correction method
摘要： In this study, MOS capacitors of Al/ZrO2/IL/n-Si (IL: interface layer) have been fabricated. Bias scan and frequency scan data of measured parallel capacitance (Cm) and parallel resistance (Rm) have been taken in the frequency of ～1 kHz to 2 MHz. To correct external frequency dispersion of parasitic parameters, we have used five-element model (including MOS capacitance C, parallel resistance Rp, IL capacitance Ci, IL resistance Ri, and series resistance Rs) and three-frequency correction method. Extracted capacitance C by the three-frequency correction method has negligible frequency dependence from 0.38 nF to 0.34 nF in the average frequency of ～3.7 kHz to 1.54 MHz. The frequency dispersion of Rp, Ci, Ri, and Rs are explained by some physical mechanisms. Small relative errors ΔC/C, ΔRp/Rp, ΔCi/Ci, ΔRi/Ri and ΔRs/Rs are less than 0.2%, 2%, 3%, 1.2% and 0.4% respectively. We have also used two existing double-frequency methods of three- and four-element models for comparison, and the extracted capacitances show abnormal frequency dependence. Above results indicate the three-frequency method of five-element model is necessary, effective and convenient in providing sufficient list data for bias voltage dependence or frequency dependence. The dielectric parameters, such as relative dielectric constant, conductivity, imaginary part of complex dielectric constant, and dielectric loss tangent have been calculated. The mechanisms of frequency dispersion for the dielectric parameters have been analyzed.
关键词： Three-frequency correction,Parameter extraction,MOS capacitor,Five-element model,Dielectric characteristics,Frequency dispersion
更新于2025-11-14 17:28:48
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Full capacitance model, considering the specifics of amorphous oxide semiconductor thin film transistors structures
摘要： A full capacitance model for Amorphous Oxide Semiconductor Thin Film Transistors (AOSTFTs), considering the effect of the drain contact overlap in bottom gate passivated structures is presented. It is shown that this drain overlap, on top of the passivation layer, serves as a second gate with an applied voltage equal to VDS. When VDS>VT the semiconductor-passivation (S-P) interface will be in accumulation and the behavior of the different capacitance is affected. An expression to represent this effect is included in the present model. The overlap capacitance between gate and drain/source, as well as the effect of reducing the channel capacitance as the drain is increased, are also considered by the model. The calculated capacitance is a function of the threshold voltage, (VT), the mobility and saturation parameters (γα,αs), and the sharpness of the knee region m, which are extracted using the Unified Model and Extraction Method (UMEM) for AOSTFTs. Results are compared with simulated and experimental data.
关键词： AOSTFT modeling,Capacitance model,Dynamic modeling
更新于2025-11-14 17:28:48
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Structural characterization and electrical conductivity analysis of MoO3–SeO2–ZnO semiconducting glass nanocomposites
摘要： A series of glass nanocomposite samples of the general composition formula xMoO3–(1-x) (0.5SeO2–0.5ZnO) for x = 0.05, 0.1, 0.2, and 0.3 have been prepared by solid-state reaction, i.e., slow cooling process. The structural characteristics have been explored by analyzing X-ray di?raction patterns, Fourier-transform infrared, and UV–Vis spectra. The superposition of di?erent nanophases SeO2, SeO3, ZnO, MoO3, Zn (SeO3), Zn (SeO4), Zn (MoO4), Zn2Mo3O8 and ZnMo8O10 over the amorphous glassy matrices have been identi?ed, and their crystallite sizes have been evaluated as well. Fourier transform infrared (FTIR) spectra reveal di?erent types of bonding like Zn–O–Se type and stretching vibrations of MoO6 octahedral units. It is observed that with increasing MoO3 concentration, the estimated values of optical bandgap energy, Urbach energy, and average crystallite size reduce. The dependency of electrical conductivity on frequency and temperature have been analyzed using Almond-West formalism and Jonscher's universal power-law. The non-linear character of DC conductivity and di?erent activation energies at low and high-temperature regions a?rm that the present glassy systems exhibit semiconducting nature. Moreover, DC conduction process is due to small polaron hopping through localized or defect states. The decreasing trend of power-law exponent (s) with temperature rise reveals that AC conduction mechanism is consistent with the correlated barrier-hopping (CBH) model. The existing correlated barrier-hopping model has been modi?ed to attain reasonable values of ?tting parameters and to obtain theoretical values of ideal thermodynamic glass transition temperature. The AC conductivity activation energy and free energy required for small polaron migration reduce with increasing conductivity. The scaling property emphasizes that conductivity relaxation process is subjected to the structure of the composition and does not depend on temperature.
关键词： XRD,UV–vis spectroscopy,Glass nanocomposites,Correlated barrier hopping model,DC and AC conductivity,FTIR
更新于2025-11-14 17:28:48
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Analysis of Fluorescence and Biodegradability of Wastewater
摘要： Three-dimensional fluorescence spectrometer was adopted for the content analysis of different types of organics in coking wastewater before biochemical treatment and through biochemical treatment, and the model of parallel factors was employed to analyze fluorescence components and contents. It was found that tryptophan-like components were the most easily degraded by biology, while humic-like components were the least easily degraded. Meanwhile, it had been seen that the change trends over time of total fluorescence densities of proteinoid fluorescence, and degradable organic fluorescence were highly consistent with that of parameter values of COD, NH3-N in this wastewater after analyzing the trends of the two indexes. It was proved that the three-dimensional fluorescence spectrum method was appropriate for the accurate degradation analysis of wastewater components.
关键词： Coking wastewater,Analysis and evaluation,Biodegradation,Parallel factors model,Three-dimensional fluorescence spectrum
更新于2025-11-14 15:23:50
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Optical, charge transport and magnetic properties of palladium retrieved from photometric measurements: approaching the quantum mechanics background
摘要： A parametric Drude–Lorentz (DL) model is used to describe the spectral variation of the dielectric functions of bulk palladium samples at low and room temperature. In addition to the contribution of conduction electrons, the contribution of holes is also explicitly accounted for in the model. A simulated annealing method is applied to obtain the optimized values of the parameters involved in the model: volume plasma frequency of conduction electrons, high frequency dielectric constant, collision frequency of holes and corresponding relaxation time, and two additional parameters from which the effective mass of holes and collision frequency of conduction electrons are evaluated. Oscillatior strengths, resonance frequencies, and widths entering in the Lorentz contribution to the dielectric function are also optimized. Renormalization of the oscillator strengths requires the introduction of a new parameter in the context of the DL model: the ratio between number density of conduction electrons and number density of metal atoms, whose optimized value ?ts very well with its evaluation from band structure calculations and from independent measurements. Inclusion of this parameter in the framework allows us to evaluate additional quantities related to the charge-carrier transport: average effective masses, Fermi energies and electronic densities of states at the corresponding Fermi energies, intrinsic electrical resistivity, intrinsic mean free paths, heat capacities, mobilities, as well as paramagnetic and diamagnetic susceptibilities, for both electrons and holes. The optimized resonance frequencies are compared with energy differences between plausible interband transitions, in accordance with reported band structure diagrams and with our own band structure obtained from density functional theory calculations.
关键词： Drude–Lorentz model,palladium,density functional theory,simulated annealing,metal thin ?lms
更新于2025-11-14 15:19:41
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Module parameter extraction and simulation with LTSpice software model in sub-Saharan outdoor conditions
摘要： In this work, a hybrid algorithm of Levenberg-Marquardt and empiric analytic method is proposed to solve the recurring convergence problem that occurs during the module parameters extraction with the iterative method. The proposed method aims to avoid divergence and a long computation time due to the improper initial value. Elsewhere, LTSpice photovoltaic cell model is developed to simulate the extracted parameters in sub-Saharan outdoor conditions. The LTSpice model with it virtual component is expected to facilitate the understanding photovoltaic module behavior under these conditions. Measurements performed with VSP50P-12V polycrystalline module and compared to simulation results show the accuracy of the hybrid method and the ease of LTSpice model. The hybrid algorithm with RMSE value of 0.9% while correlation one is greater than 97% for simulated irradiation is more accurate than the Levenberg-Marquardt algorithm.
关键词： LTSpice model,empiric analytic,Levenberg-Marquardt algorithm,Cell model
更新于2025-09-23 15:23:52