- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Fluorescent Self-Healing Carbon Dot/Polymer Gels
摘要： Multicolor, fluorescent self-healing gels were constructed through reacting carbon dots produced from different aldehyde precursors with branched polyethylenimine. The self-healing gels were formed through Schiff base reaction between the aldehyde units displayed upon the carbon dots' surface and primary amine residues within the polyethylenimine network, generating imine bonds. The dynamic covalent imine bonds between the carbon dots and polymeric matrix endowed the gels with both excellent self-healing properties, as well as high mechanical strength. Moreover, the viscoelastic properties of the gels could be intimately modulated by controlling the ratio between the carbon dots and polymer. The distinct fluorescence emissions of the gels, originating from the specific carbon dot constituents, were employed for fabrication of light emitters at different colors, particularly generating white light.
关键词： imines,carbon dots,aldehydes.,dynamic covalent bonds,self-healing gels,fluorescent gels
更新于2025-09-23 15:23:52
-
Phenanthroline-Derivative Functionalized Carbon Dots for Highly Selective and Sensitive Detection of Cu2+ and S2? and Imaging inside Live Cells
摘要： Developing effective methods for the instant detection of Cu2+ and S2? is highly desired in the biological and environmental fields. Herein, a novel fluorescent nanoprobe was elaborately designed and synthesized by grafting a phenanthroline derivative onto the surface of carbon dots (CDs). The obtained functionalized CDs (FCDs) exhibited blue fluorescence (FL) with excellent photostability and possessed a mean diameter around 4 nm. Cu2+ can be selectively captured by the phenanthroline group of FCDs to generate an absorptive complex in situ, leading to obvious quenching of the FCDs’ FL signal through an inner filter effect. Furthermore, the FL of the FCD–Cu2+ can be effectively recovered by S2? anions due to the release of FCDs from the FCD–Cu2+ complex owing to the formation of stable CuS (Ksp = 1.27 × 10?36) between S2? and Cu2+. The detection limits of the FCDs were determined to be 40.1 nM and 88.9 nM for Cu2+ and S2?, respectively. Moreover, this nanoprobe can also be used for the imaging of intracellular Cu2+ and S2?, which shows strong application prospects in the field of biology.
关键词： carbon dots,fluorescent nanoprobe,(2,3-f)-pyrazino(1,10)phenanthroline-2,3-dicarboxylic acid,Cu2+,S2?
更新于2025-09-23 15:23:52
-
Ethanothermal synthesis of phenol-derived carbon dots with multiple color emission via a versatile oxidation strategy
摘要： Herein, we report an ethanothermal synthesis of multicolor fluorescent carbon dots (CDs) by using a series of phenols and oxidants as the precursors. The emission colors of CDs are well-controlled at blue, green, yellow or red wavelengths by adjusting the combination of a phenol and an oxidant. And the naphthalenediol with highly reactivity and the oxidant with heavy halogen atom result in CDs exhibiting long wavelength emission. The resulting nanodots are characterized as amorphous aggregates with abundant oxygen species. The phenol-derived CDs can be used as highly processible fillers to fabricate epoxy composites, and a white light-emitting diode (LED) employing the multicolor CDs/epoxy composite as the light converter is also demonstrated.
关键词： Carbon dots,Photoluminescence,Phenols
更新于2025-09-23 15:23:52
-
Photoluminescence carbon dot as a sensor for detecting of Pseudomonas aeruginosa bacteria: Hydrothermal synthesis of magnetic hollow NiFe2O4-carbon dots nanocomposite material
摘要： The purpose of this research is synthesis of photoluminescence nanoparticles for detection of Pseudomonas aeruginosa that is feasible for bio medial applications. Carbon nano-templates were prepared from soot by burning of almond as a green precursor. Then NiFe2O4 nanoparticles were synthesized on the carbon templates. For preparation of hollow structures, the product was calcinated for removing of carbon templates. Finally, carbon dots were synthesized on the hollow nickel ferrite cores by applying ethylene diamine and citric acid. Phase of the products was approved by X-ray diffraction (XRD), scanning electron microscopy (SEM) depict the morphology and transmission electron microscopy (TEM) probe the grain size and hollow structures of the nickel ferrite, carbon dot and nanocomposites. Fourier transform infrared (FT-IR) spectroscopy approved the purity of the nanostructures. Ultraviolet-visible (UV-Vis) absorption and photo-luminescence (PL) spectroscopy confirmed appropriate photo-luminescence under ultraviolet irradiation. Vibrating sample magnetometer (VSM) shows ferromagnetic property of the both hollow NiFe2O4 and nickel ferrite-carbon nanocomposite. This work presents a new nanostructure as green prepared photoluminescence sensor for detecting of Pseudomonas aeruginosa bacteria, lead and mercury ions. Outcomes confirm decreasing in photoluminescence intensity of the nanocomposite by enhancing of Pseudomonas aeruginosa, Pb(II) and Hg(II) ions. Antibacterial effect of NiFe2O4-carbon dot on the degradation of Pseudomonas aeruginosa bacteria was also examined.
关键词： Nanostructures,Carbon Dots,Magnetic,Photoluminescence,P. Aeruginosa Bacteria
更新于2025-09-23 15:23:52
-
Multi-fluorescent Cationic Carbon Dots for Solid-state Fingerprinting
摘要： Carbon nanomaterials have been widely explored in bioimaging and biosensing, but their application in forensic science and technology is rare. In this report, we show one-pot synthesis of cationic Carbon Dots (cCDs) and their application in fingerprinting analysis. The cCDs show narrow size distribution (<10 nm), decent quantum yield (c.a. 46%), and a band gap of 2.75 eV. The cCDs exhibit cationic charge and show excitation-dependent multi-fluorescence characteristics. The cCDs show no production of reactive oxygen species and thus are safe to use. Interestingly, they also possess bright liquid as well as solid-state fluorescence. We demonstrate that a well-resolved patterned fingerprint can be obtained within a short time (2-3 min) from different physical surfaces and can be studied using a simple cell phone camera enabling accurate visualization up to third-degree detailing of the fingerprint. Owing to multi-fluorescence characteristics of cCDs, a detailed investigation of the fluorescent patterns was carried out by a three-dimensional multiphoton confocal microscopy. In comparison to traditional methods, the cCDs fluorescence-based fingerprinting shows improvements towards rapid image capture and analysis. Thus, the cCDs form a promising material for rapid fingerprint detection in forensic sciences.
关键词： solid-state,confocal imaging,carbon dots,cell phone,fingerprint
更新于2025-09-23 15:23:52
-
Heterobimetallic (Fe <sup>II</sup> /Pt <sup>II</sup> )-Based Supramolecular Coordination Complexes Using 1,1′-Ferrocene Dicarboxylate: Self-Assembly and Interaction with Carbon Dots
摘要： The synthesis and characterization of a new pyrazine-based ditopic organoplatinum(II) complex having a bite angle of 180° is reported. The facile and efficient syntheses are described of three discrete neutral Fe(II)/Pt(II) heterobimetallic SCCs with Pt(II) acceptor clips of different binding angles, 0, 120, and 180°. These new SCCs were characterized by multinuclear NMR and mass spectrometry. Electrochemical response of these ferrocene containing self-assembled ensembles was studied using cyclic voltammetry. The diplatinum acceptor organometallic clips significantly quench the fluorescence of highly emitting carbon quantum dots (CD), while the self-assembled macrocycles tend to nullify the quenching effect of the organometallic clips. Interestingly, the inefficient quenching of CD fluorescence by these SCCs was found to be directly related to the angular disposition of the binding sites in the Pt(II) based organometallic clips.
关键词： carbon dots,heterobimetallic,electrochemical response,self-assembly,supramolecular coordination complexes,fluorescence quenching,ferrocene
更新于2025-09-23 15:23:52
-
Universal existence of fluorescent carbon dots in beer and assessment of their potential toxicity
摘要： Nanosized materials may produce adverse physiological effects or potential health risks due to their unique physical and chemical properties. Herein, the universal presence of fluorescent carbon dots (CDs) in commercial beers was confirmed through a systematic survey. The beer CDs were roughly spherically shaped in appearance and emitted bright blue fluorescence under ultraviolet light with quantum yields (QYs) ranging from 1.42% to 3.92%. Furthermore, digestion, biodistribution, and cytotoxicity assessments of CDs from Snow beer were conducted as an example. The CDs were significantly quenched during in vitro digestion. The dynamic distribution of CDs in mice showed that they easily accumulated in the intestine and liver, and more importantly, the beer CDs were found in the brain, which indicated that they were able to cross the blood–brain barrier. Acute toxicity of the beer CDs was evaluated using BALB/c mice, and the results revealed that the biochemical parameters of mice after administration of a single dose of 2 g kg?1 body weight were almost same as those of the control groups. Histological analysis showed no obvious organ damage in the tested mice. The in vitro results indicated that CDs dispersed onto both the cell membrane and the cytoplasm of MC3T3-E1 cells, alter the cell cycle progression, and caused cell apoptosis at high doses. This work reports the potential risk of CDs in beer and provides valuable information regarding CDs in food.
关键词： beer,cytotoxicity,biodistribution,Carbon dots,digestion
更新于2025-09-23 15:23:52
-
Assembly of shell/core CDs@CaF2 nanocomposites to endow polymer with multifunctional properties
摘要： Assembly of shell/core CDs@CaF2 nanocomposites to endow polymer with multifunctional properties. The shell/core structure of CDs@CaF2 nanocomposites (CCNCs) were prepared by assembling fluorescent carbon dots (CDs) inside the inorganic CaF2 substrates using co-precipitation interaction. CDs endow the CaF2 with the properties of good UV-absorbing behavior and efficient blue light emission instead of rare earth such as Eu that is expensive and susceptible to polluting environment during the mining process. Due to nanometer size and surface effect of nano CaF2, and approximate refractive index between CaF2 and polyethylene (PE), CCNCs/PE film exhibits better elongation at break than pure PE film while maintaining high transparency and visible light transmittance. Simultaneously, the CCNCs/PE film was experimentally demonstrated to have outstanding performance of anti-UV and blue light conversion, which decide that CCNCs can be a novel and promising multifunctional additive applied in polymers especially for greenhouse film.
关键词： CaF2,Carbon dots,Polymer,Light conversion,Anti-UV,Nano-toughening
更新于2025-09-23 15:23:52
-
Carbon Dots Dispersed on Graphene/SiO <sub/>2</sub> /Si: A Morphological Study
摘要： Low-dimensional carbon materials occupy a relevant role in the field of nanotechnology. Herein, the authors report a study conducted by atomic force microscopy and Raman spectroscopy on the deposition of carbon dots onto graphene surfaces. The study aims at understanding if and how the morphology and the microstructure of chemical vapor deposited graphene on Si/SiO2 may change due to the interaction with the carbon dots. Potential alteration in the graphene’s electrical properties might be detrimental for optoelectronic applications. The deposition of carbon dots dispersed in water and ethanol solvents are explored to investigate the effect of solvents with different fluidic properties. The obtained results indicate that the carbon dots do not alter the quality of graphene.
关键词： Raman spectroscopy,carbon dots,atomic force microscopy,chemical vapor deposited graphene
更新于2025-09-23 15:22:29
-
Functionalized fluorescent carbon nanoparticles for sensitively targeted of folate-receptor-positive cancer cells
摘要： The folic acid-functionalized fluorescent carbon dots (FA-CDs) was synthesized via the assembly of FA to the surface of CDs. A facile hydrothermal method with proline and ethylenediamine as precursors was used to fabricate CDs. The as-prepared CDs possessed active amino groups where the CDs could be further engineered for the conjugation with FA. The uptake of the as-synthesized FA-CDs by FR positive MCF-7 cells (FR++) and HepG-2 cells (FR+) via receptor-mediated endocytosis was demonstrated by confocal laser scanning microscopy, which is further verified by a comparative study with FR-negative PC-12 cells (FR-). The bright fluorescence can be observed in FR positive MCF-7 cells while negligible fluorescence was observed in PC-12 cells with low-expressed FR, demonstrating that FA-CDs could accurately identify FR-positive cancer cells from normal cells. The FA-CDs shared favorable biocompatibility, excellent optical properties and ultra-low toxicity etc. Holding these superior properties, the FA-CDs was implemented as a highly effective platform for biological labeling and imaging, which may provide a innovative vision for cancer diagnosis and succeeding personalized therapy.
关键词： Folic acid-functionalized,Targeted bioimaging,Cancer cells,Carbon dots
更新于2025-09-23 15:22:29