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Efficient White LEDs Using Liquid-state Magic-sized CdSe Quantum Dots
摘要： Magic clusters have attracted significant interest to explore the dynamics of quantum dot (QD) nucleation and growth. At the same time, CdSe magic-sized QDs reveal broadband emission in the visible wavelength region, which advantageously offer simple integration of a single-type of nanomaterial and high color rendering ability for white light-emitting diodes (LEDs). Here, we optimized the quantum yield of magic-sized CdSe QDs up to 22% via controlling the synthesis parameters without any shelling or post-treatment process and integrated them in liquid-state on blue LED to prevent the efficiency drop due to host-material effect. The fabricated white LEDs showed color-rendering index and luminous efficiency up to 89 and 11.7 lm/W, respectively.
关键词： Magic clusters,Quantum dots,Luminous efficiency,CdSe,White light-emitting diodes
更新于2025-11-20 15:33:11
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CLUSTER GLIMPSES WITH RAVEN: AO-CORRECTED NEAR AND MID-INFRARED IMAGES OF GLIMPSE C01 AND GLIMPSE C02
摘要： We discuss images of the star clusters GLIMPSE C01 (GC01) and GLIMPSE C02 (GC02) that were recorded with the Subaru IRCS. Distortions in the wavefront were corrected with the RAVEN adaptive optics (AO) science demonstrator, allowing individual stars in the central regions of both clusters—where the fractional contamination from non-cluster objects is lowest—to be imaged. In addition to J, H, and K′ images, both clusters were observed through a narrow-band filter centered near 3.05 μm; GC01 was also observed through two other narrow-band filters that sample longer wavelengths. Stars in the narrow-band images have an FWHM that is close to the telescope diffraction limit, demonstrating that open-loop AO systems like RAVEN can deliver exceptional image quality. The near-infrared color–magnitude diagram of GC01 is smeared by non-uniform extinction with a 1σ dispersion ΔAK = ±0.13 mag. Spatial variations in AK are not related in a systematic way to location in the field. The Red Clump is identified in the K luminosity function (LF) of GC01, and a distance modulus of 13.6 is found. The K LF of GC01 is consistent with a system that is dominated by stars with an age >1 Gyr. As for GC02, the K LF is flat for K > 16, and the absence of a sub-giant branch argues against an old age if the cluster is at a distance of ～7 kpc. Archival SPITZER [3.6] and [4.5] images of the clusters are also examined, and the red giant branch-tip is identified. It is demonstrated in the Appendix that the [3.6] surface brightness profiles of both clusters can be traced out to radii of at least 100 arcsec.
关键词： Galaxy: stellar content,globular clusters: individual (GLIMPSE C01, GLIMPSE C02)
更新于2025-09-23 15:23:52
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Water-soluble titanium-oxides: Complexes, clusters and nanocrystals
摘要： The water-soluble titanium-oxide structures covered in this review span a continuum from molecular clusters to colloidal nanocrystals. Here, a deliberate distinction is made between titanium clusters and nanoparticles with organic ligands, soluble in organic solvents, and related structures prepared and soluble in water. This distinction is made in response to rapid developments in three areas covered in this article: small titanium-oxide clusters prepared at low pH values in water, heterpolytungstate macroanions with high-nuclearity titanium-oxide cores, and polyoxometalate complexes of anatase-phase TiO2. The latter nanostructures occupy a unique position between polyoxometalate macroanions and traditional colloidal TiO2. As such, the progressively larger water-soluble titanium-oxide structures covered in the three main sections of this review establish a continuum that begins to blur the longstanding divide between molecular and colloid science.
关键词： Polyoxometalates,Titanium oxide,Water soluble,Clusters,Nanocrystals
更新于2025-09-23 15:23:52
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Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence
摘要： 1,3-P,N-ligands provide the ideal spatial separation to facilitate homo and hetero metal-metal interactions to access multinuclear complexes. The rich chemistry of such complexes includes applications in coordination chemistry, metal-activation and (cooperative) catalysis. However, it has been especially the fruitful combination in photoluminescent P,N-coinage metal complexes which has renewed interest in these ligands. While the field classically focused on dinuclear species, now also coinage metal clusters have been studied for use in catalysis and photophysical applications. Reviewed are recent developments from 2009 to mid-2017.
关键词： P,N-ligands,Coinage metal clusters,Photoluminescence,Transition metal complexes,Homogeneous catalysis,Metal-metal bonds
更新于2025-09-23 15:23:52
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Using the multi-object adaptive optics demonstrator RAVEN to observe metal-poor stars in and towards the Galactic Centre
摘要： The chemical abundances for five metal-poor stars in and towards the Galactic bulge have been determined from the H-band infrared spectroscopy taken with the RAVEN multi-object adaptive optics science demonstrator and the Infrared Camera and Spectrograph at the Subaru 8.2-m telescope. Three of these stars are in the Galactic bulge and have metallicities between ?2.1 < [Fe/H] < ?1.5, and high [α/Fe] ～ +0.3, typical of Galactic disc and bulge stars in this metallicity range; [Al/Fe] and [N/Fe] are also high, whereas [C/Fe] < +0.3. An examination of their orbits suggests that two of these stars may be confined to the Galactic bulge and one is a halo trespasser, though proper motion values used to calculate orbits are quite uncertain. An additional two stars in the globular cluster M22 show [Fe/H] values consistent to within 1σ, although one of these two stars has [Fe/H] = ?2.01 ± 0.09, which is on the low end for this cluster. The [α/Fe] and [Ni/Fe] values differ by 2σ, with the most metal-poor star showing significantly higher values for these elements. M22 is known to show element abundance variations, consistent with a multipopulation scenario though our results cannot discriminate this clearly given our abundance uncertainties. This is the first science demonstration of multi-object adaptive optics with high-resolution infrared spectroscopy, and we also discuss the feasibility of this technique for use in the upcoming era of 30-m class telescope facilities.
关键词： stars: abundances,Galaxy: centre,instrumentation: adaptive optics,globular clusters: individual: M22,techniques: spectroscopic
更新于2025-09-23 15:23:52
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Effect of Hydration Procedure of Fumed Silica Precursor on the Formation of Luminescent Carbon Centers in SiO <sub/>2</sub> :C Nanocomposites
摘要： The effect of hydration procedure of fumed silica precursor on photoluminescent properties of carbonized silica (SiO2:C) nanocomposite after chemo/thermal treatments is studied. Main structural effect is the formation of chemical bonding of phenyl groups to silica surface via multiple C─Si─O bonding bridges. Synthesized samples demonstrate very broad photoluminescence (PL) bands in near ultraviolet and visible ranges with maximum intensity dependent on temperature of thermal annealing. Two main trends in luminescence properties are: 1) hydration-induced blue shift of PL in comparison with PL of unhydrated series; 2) red shift of PL bands with increasing synthesis temperature regardless hydration procedure. Temperature dependent evolution of light emission bands is discussed in terms of surface carbon nanoclusters formation and aggregation processes. It is assumed that blue shift of PL bands in the hydrated series is associated with the decreased surface mobility of carbon atoms and clusters as a result of increased chemical bonding with silica surface that slows down carbon thermally stimulated clusterization/aggregation processes.
关键词： carbonized nanocomposite material,carbonized fumed silica,phenyltrimethoxysilane,wide-band visible photoluminescence,carbon clusters
更新于2025-09-23 15:23:52
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<i>Spitzer Planck Herschel</i> Infrared Cluster (SPHerIC) survey: Candidate galaxy clusters at 1.3 < <i>z</i> < 3 selected by high star-formation rate
摘要： There is a lack of large samples of spectroscopically confirmed clusters and protoclusters at high redshifts, z > 1.5. Discovering and characterizing distant (proto-)clusters is important for yielding insights into the formation of large-scale structure and on the physical processes responsible for regulating star-formation in galaxies in dense environments. The Spitzer Planck Herschel Infrared Cluster (SPHerIC) survey was initiated to identify these characteristically faint and dust-reddened sources during the epoch of their early assembly. We present Spitzer/IRAC observations of 82 galaxy (proto-)cluster candidates at 1.3 < zp < 3.0 that were vetted in a two step process: (1) using Planck to select by color those sources with the highest star-formation rates, and (2) using Herschel at higher resolution to separate out the individual red sources. The addition of the Spitzer data enables efficient detection of the central and massive brightest red cluster galaxies (BRCGs). We find that BRCGs are associated with highly significant, extended and crowded regions of IRAC sources which are more overdense than the field. This result corroborates our hypothesis that BRCGs within the Planck–Herschel sources trace some of the densest and actively star-forming proto-clusters in the early Universe. On the basis of a richness-mass proxy relation, we obtain an estimate of their mean masses which suggests our sample consists of some of the most massive clusters at z ≈ 2 and are the likely progenitors of the most massive clusters observed today.
关键词： galaxies: star formation,submillimeter: galaxies,infrared: galaxies,galaxies: evolution,galaxies: clusters: general,galaxies: high-redshift
更新于2025-09-23 15:23:52
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Photometric and astrometric study of open cluster FSR 814 (Koposov 36) using SDSS/2MASS/PPMXL/Gaia DR2
摘要： We present multi photometric and astrometric study of open cluster FSR 814 (Koposov 36) selected from the FSR catalog in different bands of Sloan Digital Sky Survey (SDSS), 2MASS, PPMXL and Gaia DR2. This study contains new results with a very high accuracy for the first time and generates the multi decontaminated color-magnitude diagrams to estimate the main astrophysical properties (such as: diameter, age, distance, reddening, geometrical projected distances, luminosity and mass functions) of FSR 814. Our results have been compared with other literatures.
关键词： Color-Magnitude Diagram (CMD),Open clusters and associations: individual (FSR 814),Astrometry
更新于2025-09-23 15:23:52
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[IEEE 2018 IEEE International Conference on Electrical Engineering and Photonics (EExPolytech) - Saint Petersburg, Russia (2018.10.22-2018.10.23)] 2018 IEEE International Conference on Electrical Engineering and Photonics (EExPolytech) - Study of Oxyfluoride Glasses with Silver Molecular Clusters for Application in Sensoric and Optoelectronics
摘要： Temperature sensitivity of Oxyfluoride glasses with molecular silver clusters and samarium ions were studied. The experimental procedure for obtaining luminescence spectra at various temperatures is described. The perspective of using oxyfluoride glasses in fiber-optic temperature sensors is considered.
关键词： sensitive element,luminescence,Fiber-optical temperature sensor,oxyfluoride glass,spectrum,molecular clusters of silver
更新于2025-09-23 15:23:52
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Deep, multiband photometry of low-mass stars to reveal young clusters: A blind study of the NGC2264 region
摘要： Context. Thanks to their extensive and homogeneous sky coverage, deep, large-scale, multiwavelength surveys are uniquely suited to statistically identify and map young star clusters in our Galaxy. Such studies are crucial to address issues like the initial mass function, or the modes and dynamics of star cluster formation and evolution. Aims. We aim to test a purely photometric approach to statistically identify a young clustered population embedded in a large population of field stars, with no prior knowledge of the nature of stars in the field. We conducted our blind test study on the NGC 2264 region, which hosts a well-known, richly populated young cluster (～3 Myr-old) and several active star-forming sites. Methods. We selected a large (4 deg2) area around the NGC 2264 cluster, and assembled an extensive r, i, J catalog of the field from pre-existing large-scale surveys, notably Pan-STARRS1 and UKIDSS. We then mapped the stellar color locus on the (i ? J, r ? i) diagram to select M-type stars, which offer the following observational advantages with respect to more massive stars: (i) they comprise a significant fraction of the Galactic stellar population; (ii) their pre-main sequence phase lasts significantly longer than for higher mass stars; (iii) they exhibit the strongest luminosity evolution from the pre-main sequence to the main sequence; (iv) their observed r, i, J colors provide a direct and empirical estimate of AV . A comparative analysis of the photometric and spatial properties of M-type stars as a function of AV enabled us to probe the structure and stellar content of our field. Results. Using only r, i, J photometry, we could identify two distinct populations in our field: a diffuse field population and a clustered population in the center of the field. The presence of a concentration of occulting material, spatially associated with the clustered population, allowed us to derive an estimate of its distance (800–900 pc) and age (～0.5–5 Myr); these values are overall consistent with the literature parameters for the NGC 2264 star-forming region. The extracted clustered population exhibits a hierarchical structure, with two main clumps and peaks in number density of objects around the most reddened locations within the field. An excellent agreement is found between the observed substructures for the clustered population and a map of the NGC 2264 subregions reported in the literature. Our selection of clustered members is coherent with the literature census of the NGC 2264 cluster for about 95% of the objects located in the inner regions of the field, where the estimated contamination rate by field stars in our sample is only 2%. In addition, the availability of a uniform dataset for a large area around the NGC 2264 region enabled us to discover a population of about a hundred stars with indications of statistical membership to the cluster, therefore extending the low-mass population census of NGC 2264 to distances of 10–15 pc from the cluster cores. Conclusions. By making use solely of deep, multiband (r, i, J) photometry, without assuming any further knowledge of the stellar population of our field, we were able to statistically identify and reconstruct the structure of a very young cluster that has been a prime target for star formation studies over several decades. The method tested here can be readily applied to surveys such as Pan-STARRS and the future LSST to undertake a first complete census of low-mass, young stellar populations down to distances of several kiloparsecs across the Galactic plane.
关键词： techniques: photometric,stars: low-mass,methods: statistical,surveys,open clusters and associations: individual: NGC 2264,methods: observational
更新于2025-09-23 15:22:29