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Development of Thick Superhydrophilic TiO <sub/>2</sub> –ZrO <sub/>2</sub> Transparent Coatings Realized through the Inclusion of Poly(methyl methacrylate) and Pluronic-F127
摘要： A thick coating of hierarchically porous double-templated TiO2?ZrO2?PMMA?PF127 with excellent self-cleaning properties and high transmittance has been developed for the first time on glass substrates using a simple dip-coating technique. Comparative studies of this sample with a thick and transparent coating of single-templated TiO2?ZrO2?PMMA have been performed to probe the origin of its exceptional properties. The formation of the composites, successful incorporation of the polymer into the matrix, and the porous nature of the films have been studied. The presence of Ti2+ in the double-templated samples has been confirmed, which suggest the chemisorption of water on the surface of the film. The variation in the self-cleaning properties of the samples on UV-illumination has also been studied. The double-templated film is found to possess the capability of good hydrophilic retention even 2 days after UV-irradiation.
关键词： PF127,self-cleaning,PMMA,transparent coatings,dip-coating,UV-irradiation,TiO2?ZrO2,superhydrophilic
更新于2025-09-23 15:21:01
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Dip coated TiO2 based metal-semiconductor-metal ultraviolet photodetector for UV A monitoring
摘要： Metal-Semiconductor-Metal ultraviolet photodetector was fabricated by painting silver contacts on dip coated TiO2 thin films. The number of deposition cycles have influence on physiochemical properties and UV sensing properties. The UV photodetector properties were studied by illuminating devices with light intensity of 1.8 μW/cm2 and 5 V bias. The fabricated devices show ohmic I–V characteristics. The maximum photocurrent of 0.64 μA is obtained at 365 nm for film deposited at 8 cycles. The highest photoresponsivity obtained for C8 sample under UV illumination of 365 nm is 2.15 A/W at 5 V bias. The fast rise and fall times obtained for fabricated device are 17 s and 19 s. The optical switching characteristics show good reproducibility and stability.
关键词： Photoresponsivity,Dip coating,MSM UV photodetector,Titanium dioxide
更新于2025-09-23 15:19:57
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Highly efficient planar heterojunction perovskite solar cells with sequentially dip-coated deposited perovskite layers from a non-halide aqueous lead precursor
摘要： High-performance planar heterojunction (PHJ) perovskite solar cells (PrSCs) with MAPbI3 perovskite films were fabricated using a facile, environmentally benign, efficient and low-cost dip-coating deposition approach on a bilayered ZnO/TiO2 electron transport system from aqueous non-halide Pb(NO3)2. Outstanding performance of PrSCs was achieved due to the PHJ configuration of FTO/TiO2/ZnO/MAPbI3/spiro-OMeTAD/MoO3/Ag. These PHJ PrSCs exhibited better performance and stability with thinner ZnO layers in contrast to those with mesoporous TiO2 scaffolds, indicating that the thickness of the ZnO layer in the PHJ architecture significantly affected the surface coverage, morphology, crystallinity, and stability of the MAPbI3 perovskite films processed by dip-coating deposition.
关键词： ZnO/TiO2 electron transport system,perovskite solar cells,planar heterojunction,dip-coating deposition,aqueous non-halide Pb(NO3)2
更新于2025-09-19 17:13:59
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Ultrafast, sensitive and visual sensing of copper ions by a dual-fluorescent film based on quantum dots
摘要： The use of fluorescent sensors is one of the most promising approaches for meeting the growing demand for a sensitive, convenient and cost-effective detection method of metal ions. However, visual sensing based on fluorescent materials remains a challenge due to the hard-to-see changes in fluorescence intensity, long response time and poor stability. Here, a simple and effective film sensor was developed for the visual detection of Cu2+ using quantum dots (QDs) modified by polyethylenimine (PEI) and poly(vinylidene fluoride) (PVDF) by electrospinning and dip-coating methods. QDsr-PEI on the surface of nanofibers could be used as a responsive red fluorescence signal, while the QDsg dispersed in the nanofibers were used as a green background signal. Due to the high Cu2+ binding capacity of PEI and the contrast-color sensitivity of the two kinds of QDs, it realized an obvious fluorescence change from red to green toward Cu2+ in the liquid phase with a short response time of 30 s and a low detection limit of 2 mM by observation. Furthermore, the film exhibited excellent fluorescence stability to a high temperature and UV light, which is beneficial for satisfying much more possible applications. These results demonstrate that the dual fluorescent film sensor has a great potential for the real-time and visual detection of Cu2+.
关键词： dip-coating,fluorescent sensors,visual detection,Cu2+,quantum dots,electrospinning
更新于2025-09-16 10:30:52
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Investigation of Well-Defined Pinholes in TiO2 Electron Selective Layers Used in Planar Heterojunction Perovskite Solar Cells
摘要： The recently introduced perovskite solar cell (PSC) technology is a promising candidate for providing low-cost energy for future demands. However, one major concern with the technology can be traced back to morphological defects in the electron selective layer (ESL), which deteriorates the solar cell performance. Pinholes in the ESL may lead to an increased surface recombination rate for holes, if the perovskite absorber layer is in contact with the fluorine-doped tin oxide (FTO) substrate via the pinholes. In this work, we used sol-gel-derived mesoporous TiO2 thin films prepared by block co-polymer templating in combination with dip coating as a model system for investigating the effect of ESL pinholes on the photovoltaic performance of planar heterojunction PSCs. We studied TiO2 films with different porosities and film thicknesses, and observed that the induced pinholes only had a minor impact on the device performance. This suggests that having narrow pinholes with a diameter of about 10 nm in the ESL is in fact not detrimental for the device performance and can even, to some extent improve their performance. A probable reason for this is that the narrow pores in the ordered structure do not allow the perovskite crystals to form interconnected pathways to the underlying FTO substrate. However, for ultrathin (~20 nm) porous layers, an incomplete ESL surface coverage of the FTO layer will further deteriorate the device performance.
关键词： electron selective layer,pinhole,perovskite solar cell,dip coating,evaporation-induced self-assembly,mesoporous TiO2
更新于2025-09-16 10:30:52
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Study of Electrophotophysical Characteristics of IR Photodetectors Based on PbS Colloidal Quantum Dots
摘要： The electrophotophysical characteristics of laboratory samples of IR photodetectors obtained by dip coating of PbS colloidal quantum dots with the subsequent exchange of oleic acid molecules that compose their ligand shell by S2? ions have been studied.
关键词： thin layers,electrophysical characteristics of layers,spectral and luminescent properties,dip-coating method,near infrared region,PbS colloidal quantum dots,ligand exchange,IR photodetectors
更新于2025-09-16 10:30:52
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A feasible strategy to prepare quantum dot-incorporated carbon nanofibers as free-standing platforms
摘要： Recently, quantum dots (QDs) have often garnered significant attention and have been employed for various applications. Nevertheless, most conventional devices utilize a glass substrate and/or brittle substrate, which is not compatible with next-generation wearable electronics. A suitable method for devising conductive and flexible free-standing platforms that can be combined with various kinds of QDs is thus in great need for next-generation wearable electronics. In this work, we introduce a universal and simple method to coat QDs on carbon nanofibers (CNFs) by a dip-coating process, where many kinds of QDs can be well decorated on the surface of CNFs. As one potential application among many, QD-coated CNFs were examined for their photocatalytic applications and characterization. As a result, it was found that the best performance of CdSe QD-coated CNFs for hydrogen production was 3.8 times higher than that of only QDs with the same 1 mg of QDs. This is an early report on fabricating various kinds of QD-coated CNFs, which can be extended to a myriad set of applications.
关键词： photocatalytic applications,wearable electronics,quantum dots,carbon nanofibers,dip-coating
更新于2025-09-11 14:15:04
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Sol-Gel Derived Dip Coated ZnO – La <sub/>2</sub> O <sub/>3</sub> Thin Film Transistors
摘要： ZnO thin ?lms are fabricated utilizing a cost effective sol-gel dip coating technique and potentially applied as active material in thin ?lm transistors (TFT). The channel length of the TFT is maintained at 40 μm. Thermally deposited high –k La2O3 is used as dielectric material. The fabricated ZnO ?lms are annealed in oxygen atmosphere at 500?C for 1 hour and characterized by XRD, EDX and SEM analysis. The TFTs are fabricated in top gate coplanar electrodes structure on glass substrates. The electrical characteristics of the TFTs are investigated and some important electrical parameters are evaluated. The TFTs exhibit ?eld effect mobility of 1.9 cm2/VS, low threshold voltage of 2.5 Volt, high ON/OFF current ratio of 107, sub-threshold swing of 0.8V/decade, transconductace of 1.2 × 10?3 mho and gain band-width product of 20 kHz.
关键词： ZnO,sol-gel dip coating,thin film transistors,electrical characteristics,La2O3
更新于2025-09-11 14:15:04
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Photoelectrochemical water splitting properties of CdS/TiO2 nanofibers-based photoanode
摘要： CdS-sensitized TiO2 nanofibers (CdS/TiO2 NFs) structures were fabricated on the indium tin oxide (ITO) conducting substrate that acts as a working electrode in photoelectrochemical (PEC) cell for the generation of hydrogen by water splitting. TiO2 NFs on ITO conducting substrate were synthesized by electrospinning technique using Titanium tetraisopropoxide as the precursor, followed by a calcination process in air at 500 °C for 2 h. CdS deposition on TiO2 NFs structures was carried out by the dip coating method with different dipping times to optimize the water splitting efficiency. The morphologies and crystalline structures of fabricated samples were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The PEC properties of the electrodes were measured using a potentiostat instrument in a mixture of 0.25 M Na2S and 0.35 M Na2SO3 aqueous solutions for CdS/TiO2 photoanodes and in 0.5 M Na2SO4 electrolyte for uncoated TiO2 photoanode under the illumination of simulated sunlight (100 mW/cm2 from 150 W xenon lamp). It was found that an optimized TiO2 NFs structure sensitized by CdS layer yields a photoconversion efficiency of 3.2% at 0.0 V (vs. Ag/AgCl). The value of photocurrent density for CdS/TiO2 NFs samples were more than 20 times higher than that of the uncoated TiO2 NFs sample at 0.0 V (vs. Ag/AgCl) under a simulated sunlight irradiation.
关键词： photoelectrochemical water splitting,electrospinning,dip coating,hydrogen generation,CdS/TiO2 nanofibers
更新于2025-09-10 09:29:36
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Impact of Overlapping Fe/TiO <sub/>2</sub> Prepared by Sol-Gel and Dip-Coating Process on CO <sub/>2</sub> Reduction
摘要： Fe-doped TiO2 (Fe/TiO2) film photocatalyst was prepared by sol-gel and dip-coating process to extend its photoresponsivity to the visible spectrum. To promote the CO2 reduction performance with the photocatalyst, some types of base materials used for coating Fe/TiO2, which were netlike glass fiber and Cu disc, were investigated. The characterization of prepared Fe/TiO2 film coated on netlike glass fiber and Cu disc was analyzed by SEM and EPMA. In addition, the CO2 reduction performance of Fe/TiO2 film coated on netlike glass disc, Cu disc, and their overlap was tested under a Xe lamp with or without ultraviolet (UV) light, respectively. The results show that the concentration of produced CO increases by Fe doping irrespective of base material used under the illumination condition with UV light as well as that without UV light. Since the electron transfer between two overlapped photocatalysts is promoted, the peak concentration of CO for the Fe/TiO2 double overlapping is approximately 1.5 times as large as the Fe/TiO2 single overlapping under the illumination condition with UV light, while the promotion ratio is approximately 1.1 times under that without UV light.
关键词： UV light,Fe-doped TiO2,visible spectrum,photocatalyst,dip-coating,sol-gel,CO2 reduction
更新于2025-09-09 09:28:46