- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
In Situ Measurement of Phase Boundary Kinetics during Initial Lithiation of Crystalline Silicon through Picosecond Ultrasonics
摘要： Studying the kinetics of phase transformation and phase boundary propagation during initial lithiation of silicon electrodes in lithium ion batteries is relevant to understanding their performance. Such studies are usually challenging due to the difficulties in measuring the phase boundary velocity in the interior of the sample. Here we introduce a non-invasive, in situ method to measure the progression of the phase boundary in a planar specimen geometry while maintaining well-controlled lithium flux and potential. We developed an apparatus integrating an electrochemical cell with picosecond ultrasonics to probe the propagating phase boundary in real time. Phase propagation during initial lithiation of crystalline silicon, which is an example of a high capacity anode, is investigated. The primary objective of this manuscript is to report on the experimental technique development and some preliminary results. For lithiation normal to the (100) plane, we observe the phase boundary velocity to be approximately 12 pm/s and x to be 3.73 in LixSi under galvanostatic lithiation with a current density of 40 μA/cm2. The growth rate of the lithiated phase and the reaction rate coefficient are examined using a Deal-Grove type model.
关键词： Lithium ion battery,In situ,Phase boundary propagation,Crystalline silicon,Picosecond ultrasonics
更新于2025-09-23 15:23:52
-
[IEEE 2018 19th International Conference on Electronic Packaging Technology (ICEPT) - Shanghai (2018.8.8-2018.8.11)] 2018 19th International Conference on Electronic Packaging Technology (ICEPT) - A novel organic coating assisted laser drilling method for TSV fabrication
摘要： Through-silicon vias (TSVs) is a promising three-dimensional packaging solution in post-Moore's law era in the semiconductor industry. The fabrication of through silicon via plays an important role in three-dimensional packaging. Laser drilling is widely used in TSVs fabrication. However, the geometry quality of laser drilling is unsatisfied and heat affected zone (HAZ) is intrinsic. In this work, a novel organic coating assisted picosecond UV laser drilling method is proposed to obtain high-quality TSVs, the HAZ was noticeably eliminated and the TSVs quality was significantly improved. The effects of the organic thickness and laser power on the TSVs' quality were also studied in detail. It is found that the diameter of vias decreases with the increase of the organic thickness and decrease of the laser power. The minimum diameter of TSV obtained by this method is about 15 μm while the aspect ratio is beyond 30. Most importantly, by coating with the organic layer, the minimized via diameter can be decreased to about only 70% of the laser spot size which breaks the limit that the minimized via should be larger than or at least equal to the laser spot size. These findings will be helpful for TSV technology development in modern three-dimensional packaging.
关键词： ultraviolet picosecond laser drilling,through silicon via,heat affected zone elimination,organics coating method
更新于2025-09-23 15:22:29
-
Microstructure and Characteristic of Biomedical Titanium Alloy Based on Picosecond Laser Micromachining
摘要： Laser micromachining has become a hotspot in recent years due to its high precision, non-contact and adjustable parameter. In this paper, TC4 titanium alloy implant samples were conducted to obtain specific surface textures through picosecond laser. The laser parameters which directly influenced the microstructure and characteristic of surface textures were optimized within the context of laser power, scanning speed and scanning number via response surface methodology. The microstructure was evaluated using scanning electron microscope (SEM) while the feature size of the surface textures was measured through surface 3D profiler. In addition, endothelial cell culture was conducted to investigate the biofunctionalization of samples with specific surface textures. It demonstrated that well-structured textures played an important role in promoting cell adhesion and proliferation for titanium alloy implants.
关键词： Picosecond laser micromachining,Microstructure,Biofunctionalization,Titanium alloy
更新于2025-09-23 15:22:29
-
Single-shot frequency-resolved optical gating for retrieving the pulse shape of high energy picosecond pulses
摘要： Accurate characterization of laser pulses used in experiments is a crucial step to the analysis of their results. In this paper, a novel single-shot frequency-resolved optical gating (FROG) device is described, one that incorporates a dispersive element which allows it to fully characterize pulses up to 25 ps in duration with a 65 fs per pixel temporal resolution. A newly developed phase retrieval routine based on memetic algorithms is implemented and shown to circumvent the stagnation problem that often occurs with traditional FROG analysis programs when they encounter a local minimum.
关键词： frequency-resolved optical gating,picosecond pulses,memetic algorithms,pulse shape retrieval,FROG
更新于2025-09-23 15:21:21
-
The First Commercial 730a??nm Picosecond-Domain Laser is Safe and Effective for Treating Multicolor Tattoos
摘要： Background and Objectives: Laser‐pumped lasers enable driving a secondary wavelength through pumping with a primary device. Here we investigate the first 730 nm laser‐pumped laser for efficacy in tattoo removal. Study Design/Materials and Methods: Fifteen subjects with 20 tattoos were enrolled to investigate the effect of a new 730 nm, titanium‐sapphire laser‐pumped laser at removing decorative tattoos. A total of four treatments were administered and photographic improvement of pre‐ and post‐treatment cross‐polarized digital images was evaluated by four blinded physician observers using an 11‐point scale. Results: Blinded assessment of pre‐ and post‐treatment images found 70%, 77%, 83%, 83%, 26%, and 8% clearance from baseline images for black, green, blue, purple, red and yellow pigments, respectively. Side effects were limited to pinpoint bleeding and erythema immediately after treatment and some crusting and scale up to 1–2 weeks following treatment, and a localized allergic reaction in a single subject. There was no scarring or pigmentary alteration visible in any follow‐up images. Conclusion: The new 730 nm, picosecond‐domain, titanium‐sapphire, laser‐pumped laser is safe and effective for removing multicolored tattoos. Green, blue, and purple pigments cleared the most as expected, but black ink cleared more completely than was predicted.
关键词： 730 nm,laser,ink,green,blue,removal,picosecond,tattoo
更新于2025-09-23 15:21:01
-
<i>In situ</i> structural kinetics of picosecond laser-induced heating and fragmentation of colloidal gold spheres
摘要： Fragmentation of colloidal 54 nm gold nanoparticles by picosecond laser pulses is recorded by time-resolved X-ray scattering, giving access to structural dynamics down to a 80 ps resolution. Lattice temperature and energy dissipation have been quantified to verify that the maximum applied fluence of 1800 J m?2 heats up the particles close to boiling. Already within 30 ns, particles with significantly lower particle sizes of 2 to 3 nm are detected, which hints towards an ultrafast process either by a thermal phase explosion or Coulomb instability. An arrested growth is observed on a microsecond time scale resulting in a final particle size of 3–4 nm with high yield. In this context, the fragmentation in a NaCl/NaOH solution seems to limit growth by electrostatic stabilization of fragments, whereas it does not modify the initial product sizes. The laser-induced fragmentation process is identified as a single-step, instantaneous reaction.
关键词： Coulomb instability,fragmentation,thermal phase explosion,time-resolved X-ray scattering,picosecond laser pulses,gold nanoparticles
更新于2025-09-23 15:21:01
-
Wettability Control of Copper Surface Using Picosecond Laser for Enhancing Condensation Heat Transfer
摘要： One of the most important and widely visualized process taking place in nature is condensation. Superhydrophobic surfaces, which facilitates dropwise condensation has been the principal area of research in the last decade or so. Fabrication of superhydrophobic surface can be achieved by either surface modification using mechanical process, surface treatment like coating or by the combination of both. But, the major drawback of coating is its durability and vulnerability. So, in this work we have fabricated a robust surface by means of picosecond laser machining. Apart from being a simple process, this method has an advantage of cutting down the surface fabrication time by several hours as compared to other methods like one-step immersion, electro-deposition, top-down fabrication method, etc. In our work three different work specimens irradiated with different laser power were studied for its surface morphologies by scanning electron microscope (SEM) images and its wettability was measured using contact angle meter. It is found that the wettability of surface changes with different laser power and hence it is possible to control the wettability by adjusting the laser parameters. Condensation experiment was carried out on these different surfaces and its performance was compared with plain surface.
关键词： Wettability control,micro grooves,Condensation heat transfer,Contact angle,Picosecond laser
更新于2025-09-23 15:21:01
-
Investigation on the effects of laser parameters on the plasma profile of copper using picosecond laser induced plasma spectroscopy
摘要： Laser induced plasma generation and characterization, affected by laser parameters and sample physical properties, represent important phenomena in many fields of applications. In this work, we present new studies on the effects of an appropriate combination of laser wavelengths and pulse energies on the generated plasma characterization using a single shot picosecond Nd:YAG laser. The plasma plume of a pure copper sample has been generated by laser induced plasma spectroscopy (LIPS) using a single shot 170 ps laser pulse with wavelengths (266, 355, 532 and 1064 nm) and varying laser fluence (10–41 J/cm2). The spectral intensities of Cu I 324.75, 327.39, 515.32 and 521.82 nm have been observed. The plasma electron temperature and density have been determined from the Boltzmann plots and Stark-broadening profiles of the plasma spectral lines, respectively, assuming the local thermodynamic equilibrium (LTE) condition. It has been found that the electron temperature and electron density values increase from around 10,000 to 20,000 K and around 2 × 1017 to 1.5 × 1018 cm?3, respectively, with the increase in the laser wavelength and pulse fluence gradually. These observations can be understood due to the variations of mass-ablation rates, inverse-Bremsstrahlung, and photo-ionization with the studied pulse wavelength and pulse energy. The obtained results explore the opportunity to control specific generated plasma parameters by applying proper picosecond pulse parameters which can be considered in many fields of material science spectroscopic analysis and control the plasma interaction dynamics.
关键词： Stark-broadening,Picosecond,Boltzmann plot,Electron temperature,LTE,Laser induced plasma spectroscopy,Copper,Electron density,Plasma plume,LIPS
更新于2025-09-23 15:21:01
-
Experimental study on direct fabrication of micro channel on fused silica by picosecond laser
摘要： Ultrafast laser ablation, known for its high precision and the depressed thermal influence during processing, is fevered in micro channel fabrication on the glass bulk. In present work, a micro channel structure fabricated on fused silica bulk by a picosecond pulsed laser is parametrically investigated with different processing environments, scanning velocities, pulse energies, hatch distances and repetitive scans. The best processing parameters are determined through the material remove rate and the bottom surface roughness of the channel. Moreover, the fabrication defect attributed to the heat accumulation effect is analyzed by Raman spectrum. A scanning strategy is put forward to compensate the asymmetry in the cross section of the micro channels.
关键词： Heat accumulation,Surface roughness,Scanning strategy,Micro channel,Picosecond laser
更新于2025-09-23 15:21:01
-
Phase Change Behavior of Sn <sub/>20</sub> Sb <sub/>80</sub> /Si?Nano-Composite Multilayer?Thin?Films
摘要： Nano-composite multilayer Sn20Sb80/Si thin films were studied by thermal, electrical and optical methods. Compared with Sn20Sb80, Sn20Sb80/Si film was proved to be a more promising candidate for phase change memory device applications because of its higher crystallization temperature (246?C) and larger crystallization activation energy (2.6 eV). The bandgap was broadened with the increase of Si layer thickness. The crystallization of Sn20Sb80 was restrained after the adding of more Si film layers confirmed by X-ray diffraction patterns. A smoother surface was obtained with the root-mean-square surface roughness of 0.753 nm for [Sn20Sb80(3nm)/Si(7nm)]5 thin film. The measurement using the picosecond laser technique showed that [Sn20Sb80(3nm)/Si(7nm)]5 thin film could achieve the crystalline-to-amorphous phase transform within 2.8 ns irradiated by the laser pulse.
关键词： bandgap,nano-composite multilayer thin films,picosecond laser technique,crystallization activation energy,Phase change memory,surface roughness,Sn20Sb80/Si,crystallization temperature
更新于2025-09-23 15:21:01