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Preparation of high-purity α-Si3N4 nano-powder by precursor-carbothermal reduction and nitridation
摘要： This work investigated the role of natural organic matter (NOM) in the environmental processes of silver nanoparticles (AgNP) and the uptake and accumulation of AgNP in wheat. Different NOMs (Suwannee River humic acids [SRHA], fulvic acid [FA]) and Ag elements (Ag(0) and Ag+) were incubated in a hydroponic media for 15 days. The results showed that the NOM (10 mg C L-1) altered the dissolution, stabilization, uptake and accumulation of AgNP. The dissolution of AgNP declined in the presence of NOM. Compared with FA, the dissolved Ag+ decreased much more from 0.30 mg L-1 to 0.10 mg L-1 in the presence of SRHA. The fluorescence quenching results indicated that SRHA exhibited stronger binding to Ag+ than that of FA, and the quenching constants Ksv were 0.1309 (SRHA) and 0.0074 (FA), respectively. CeO, CeH, CeOeC, and MeeOH were involved in the interaction between NOM and AgNP. The NOM decreased the accumulated content of Ag in wheat. Hence, NOM alleviated the inhibition of AgNP to wheat growth. SRHA reduced the Ag content of wheat roots approximately 3-fold. These results clearly indicated the importance of NOM on altering the behavior, fate and toxicity of AgNP in an environment.
关键词： Wheat,Nanoparticle fate,Accumulation,Natural organic matter,Silver nanoparticle
更新于2025-11-19 16:46:39
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Reproduction of surface-enhanced resonant Raman scattering and fluorescence spectra of a strong coupling system composed of a single silver nanoparticle dimer and a few dye molecules
摘要： The spectral changes in surface-enhanced resonant Raman scattering (SERRS) and surface enhanced fluorescence (SEF) of single silver nanoparticle dimers adsorbed by near-single dye molecules are reproduced under strong coupling regimes. For the reproduction, the enhancement and quenching factors in SERRS and SEF are derived from the Purcell factors including both radiative and nonradiative plasmon modes. The Purcell factors are estimated using the coupling energies obtained by analyzing the spectral changes in plasmon resonance during SERRS and SEF decay processes on the basis of a classical hybridization model. The model is composed of a plasmon and a molecular exciton with phonon replicas accurately representing the molecular multi-level system. The reproduced SERRS spectral changes are consistent with the experimental ones. Furthermore, the calculated SEF spectral changes can reproduce the experimental ones by phenomenologically assuming transitions from ultra-fast SEF to conventional SEF with decreasing coupling energies.
关键词： strong coupling,hybridization model,silver nanoparticle dimer,dye molecules,Purcell factors,surface enhanced fluorescence,surface-enhanced resonant Raman scattering
更新于2025-09-23 15:23:52
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Finite Element Analysis to the Constitutive Behavior of Sintered Silver Nanoparticles Under Nanoindentation
摘要： Finite element (FE) simulation is adopted as a fundamental tool to evaluate the mechanical reliability of packaging structures for electronic devices. Nevertheless, the determination of mechanical properties of sintered silver nanoparticles (AgNP) remains challenging as the traditional tensile test is difficult to be performed at a limited size. In the current study, spherical nanoindentation is utilized to measure the applied load-penetration depth responses of sintered AgNP reinforced by SiC microparticles at various weight ratios (0.0, 0.5, 1.0 and 1.5 wt.%). To describe the elasto-plastic behavior of this heterogeneous material, FE analysis is performed to simulate the indentation behavior and determine the parameters in the modified power-law model by fitting the average applied load-penetration depth responses. To overcome the uniqueness problem, the Young’s modulus is directly determined by continuous stiffness measurement technique and the proposed constitutive model can provide a reasonably accurate mechanical estimation of sintered AgNP. The effect of SiC content on sintered AgNP is discussed by correlating the morphology observed by scanning electron microscope (SEM) and the constitutive parameters obtained from the FE simulations.
关键词： nanoindentation,finite element analysis.,constitutive model,SiC microparticle,Sintered silver nanoparticle
更新于2025-09-23 15:23:52
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Fabrication of Stretchable Circuits on Polydimethylsiloxane (PDMS) Pre-Stretched Substrates by Inkjet Printing Silver Nanoparticles
摘要： Several research methodologies have recently been developed to allow for the patterning of conductive lines on elastomeric rubber substrates. Specifically, various conductive materials, substrates, and fabrication techniques were investigated to develop stretchable circuits. One promising technique recommends the application of axial strain on an elastomer substrate prior to patterning conductive lines on it. When the substrate is released, conductive lines buckle to form waves, making the circuit stretchable. However, the majority of applications of stretchable circuits require fitting them to two-dimensional surfaces, such as the human body. Hence, in this paper we propose the concept of radial pre-stretching of the substrates to enhance the stretchability of the fabricated circuits. In particular, straight silver conductive lines were deposited on a polydimethylsiloxane (PDMS) surface using inkjet printing technology, and subsequently tested under both axial and radial loads. Radial pre-stretching was compared to axial pre-stretching, resulting in an improved performance under radial loads. The optimal performance was achieved by pre-stretching the PDMS substrate with a radial strain of 27%. This resulted in stretchable circuits which could sustain radial loads with an average breakdown strain of approximately 19%. Additionally, horseshoe patterns were printed on radially pre-stretched PDMS substrates and their performance was compared to that of their straight line counterparts. Though these patterns are generally favorable for the fabrication of stretchable circuits, the optimal horseshoe pattern examined in this study could only sustain up to 16% radial strain on average when radially pre-stretched by 27%.
关键词： PDMS,inkjet printing,stretchable circuits,pre-stretching,sensors platform,silver nanoparticle ink
更新于2025-09-23 15:22:29
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Effects of low-temperature sintering on surface morphology and electrical performance of silver nanoparticle/carbon nanotube composite films
摘要： Silver nanoparticle (AgNP)/carbon nanotube (CNT) composites are drawing increasing attention for several applications, especially where transparency is required. However, interfacial interaction and stability of the AgNP/CNT composites have been scarcely investigated. In the present study, transparent coatings were prepared from dispersed AgNP-coated multiwalled CNTs and exposed to different annealing conditions. The changes in surface morphology and evolution of interfacial configuration of AgNP-decorated CNT transparent composite films were investigated. Under certain conditions, CNT ropes were glued to one another by the melted AgNP aggregates, resulting in the improvement of the measured electrical properties. The in situ measurements of the electrical properties allowed correlating the AgNPs sintering mechanism with the morphological observations. Notably, at a given temperature, increasing the initial film density increased the time necessary to complete the AgNPs sintering. The obtained results show that the electrical resistance can be used as a tool to indirectly monitor the network state of transparent AgNP-decorated CNT composite films, hence paving the way to tuning the composite film properties with a high precision for the desired application. These findings also explain the mechanism of reinforcement of polymer nanocomposites by the current nanofillers.
关键词： A. Silver nanoparticle,B. Carbon nanotube,E. In situ monitoring,D. Sintering,F. Electrical properties,C. Nanocomposite
更新于2025-09-23 15:22:29
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Molecular-Level Control over Plasmonic Properties in Silver Nanoparticle/Self-Assembling Peptide Hybrids
摘要： The plasmonic properties of silver nanoparticle (AgNP) arrays are directly controlled by AgNP size, shape, and spatial arrangement. Reported here is a strategy to prepare chiral AgNP arrays templated by two constitutionally isomeric aromatic peptide amphiphiles (APAs), KS C′EKS and C′EKSKS (KS = S-aroylthiooxime-modi?ed lysine, C′ = citrulline, and E = glutamic acid). In phosphate bu?er, both APAs initially self-assembled into nanoribbons with a similar geometry. However, in the presence of silver ions and poly(sodium 4-styrenesulfonate) (PSSS), one of the nanoribbons (KS C′EKS) turned into nanohelices with a regular twisting pitch, while the other (C′EKSKS) remained as nanoribbons. Both were used as templates for synthesis of arrays of ～8 nm AgNPs to understand how small changes in molecular structure a?ect the plasmonic properties of these chiral AgNP/APA hybrids. Both hybrids showed improved colloidal stability compared to pure AgNPs, and both showed enhanced sensitivity as surface-enhanced Raman spectroscopy (SERS) substrates for model analytes, with nanohelices showing better SERS performance compared to their nanoribbon counterparts and pure AgNPs.
关键词： self-assembling peptide,silver nanoparticle,plasmonic properties,chiral AgNP arrays,SERS
更新于2025-09-23 15:21:01
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Surface-plasmon-coupled chemiluminescence amplification of silver nanoparticles modified immunosensor for high-throughput ultrasensitive detection of multiple mycotoxins
摘要： A novel surface-plasmon-coupled chemiluminescent immunosensor was developed for the detection of multiplex mycotoxins with ultrahigh sensitivity, high throughput and simplicity. The immunosensor was constructed by immobilizing carboxyl modified silver nanoparticles (AgNPs) and bovine serum albumin combined antigens sequentially on the glass chip modified with amino groups. The optical properties of AgNPs could amplify the chemiluminescence (CL) generated on the chip through the surface plasmon resonance phenomenon. Using a competitive immunoassay, the CL signals from all the sensing sites on the chip were collected simultaneously by a charge-coupled device for ultrasensitive analysis of multiple mycotoxins. Citrinin, aflatoxin B1 and ochratoxins A were selected as model analytes. Under optimal conditions, the surface-plasmon-coupled chemiluminescent immunosensor-based method presented wide linear ranges over 4 orders of magnitude and much lower limits of detection than previous work. The assay results of mycotoxins in red yeast rice samples using the proposed method were in good agreement with that using the liquid chromatography-mass spectrometry method. Its high selectivity, high throughput, acceptable stability and accuracy showed broad prospects in mycotoxin monitoring and evaluation of safety on Traditional Chinese Medicine.
关键词： Immunosensor array,Signal amplification,Silver nanoparticle,Multiplex immunoassay,Mycotoxins,Surface-plasmon-coupled chemiluminescence
更新于2025-09-23 15:21:01
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Using adaptive neuro-fuzzy and genetic algorithm for simultaneously estimating the dye and AgNP concentrations of treated silk fabrics with nanosilver
摘要： Purpose – Arti?cial intelligence (AI) methods, such as genetic algorithm (GA) and adaptive neuro-fuzzy inference system (ANFIS), are capable of providing superior solutions for the simulation and the modeling of complex problems. The purpose of this study is to estimate the dye and the silver nanoparticle (AgNP) concentrations of silver nanoparticle-treated silk fabrics by the aforementioned methods. Design/methodology/approach – In this study, the color and the antimicrobial properties of silver nanoparticle-treated silk fabrics were matched by using the GA technique based on spectrophotometric color matching. The ANFIS method was also used; this method is based on the grid partitioning algorithm across four different methods. The ?rst and second methods are provided for dye concentration prediction, and the third and the fourth methods are given for AgNP concentration prediction. Findings – The mean of absolute error and root mean square (RMS) of the best dye concentration prediction by the ANFIS method based on the second method are 0.087 and 0.103, respectively. In addition, the mean of the absolute error and the RMS of the best results for AgNP concentration prediction by the ANFIS method by using the third method is 0.002 and 0.003, respectively. The obtained results indicate that the performance of the ANFIS method is better than the GA method. Originality value – The simultaneous prediction of the color and the antimicrobial properties of silver nanoparticle-treated silk fabrics was performed by using the GA and the ANFIS. The suggested method led to acceptable accuracy for color and antibacterial matching.
关键词： Prediction,Silver nanoparticle,Genetic algorithm,Neuro-fuzzy,Dye
更新于2025-09-23 15:21:01
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Modulation of localized surface plasmon resonances of a silver nanoparticle array upon the presence of MoS2 coatings or underlying thin films
摘要： There has been recently a growing interest in studying light-matter coupling using supported metallic nanostructures arranged into periodic arrays. The influence on the layer thickness of two-dimensional materials such as molybdenum disulfide MoS2 on the plasmonic behaviour of these arrays has become of great relevance due to the favorable bonding between S (sulfide atom) and metal atoms such as gold and silver as well as the variation of optical transition of MoS2 depending on the atomic thickness of the film. In this work, we have numerically studied the change in absorption spectra of an ordered array of silver nanoparticles AgNPs when attached to glass as well as to glass coated with different layers of MoS2. This arrangement was compared to an AgNPs attached to glass and post coated with MoS2 films of increasing thickness. It was shown that an overcoating of four MoS2 layers results in an increased plasmonic sensitivity compared to uncoated glass/AgNPs interface. Replacing the glass substrate by glass coated with MoS2 of different thickness and with added AgNPs shows a significant to the red shift with increasing MoS2 layers. This band is due to strong excitation-plasmon coupling of the silver lattice with MoS2 layers. Important is the fact that the electrical field is strongly enhanced beneath the MoS2/AgNPs barrier. One also observes a significant enhancement of the sensitivity. Hence, the design of more sensitive AgNPs/MoS2 based-plasmonic biosensors could be reached. Indeed, we show that AgNPs coating with few layers of MoS2 leads to approximately a 210.26% higher sensitivity.
关键词： Sensitivity,MoS2,Silver nanoparticle array,BioSensors,Localized surface plasmon resonance
更新于2025-09-23 15:21:01
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Enhanced photoelectrochemical performance of plasmonic Ag nanoparticles grafted ternary Ag/PaNi/NaNbO3 nanocomposite photoanode for photoelectrochemical water splitting
摘要： In this work, we have successfully synthesized silver nanoparticles (Ag-NPs) decorated binary PaNi/NBO nanocomposite by facile chemisorption route and demonstrated enhanced photoelectrochemical (PEC) water splitting activity. The ternary Ag/PaNi/NBO nanocomposite photoanode exhibits ~5 fold higher current density than pristine NaNbO3 nanofibers (NBO-NFs). The ternary Ag/PaNi/NBO photoanode exhibits a current density of 5.93 mA/cm2 at 0.9 V with respect to Ag/AgCl, whereas the pristine NBO-NFs photoanode exhibits only 0.85 mA/cm2 at 0.9 V. The improved performance is correlated to the high surface area, formation of the type-II heterojunction among PaNi and NBO-NFs and the introduction of the plasmonic behaviour of Ag-NPs as it expands the absorption of the visible part of the solar spectrum, which together decreases the recombination of charges with strong redox capability. Furthermore, the ternary Ag/PaNi/NBO photoanode showed lower charge transfer resistance (Rct) in the EIS measurements and improved incident photon to current efficiency (IPCE) of ~31.3% which is ~23% higher to the IPCE of bare NBO-NFs photoanode. Thus, these results suggest that the ternary Ag/PaNi/NBO nanocomposite is a promising material for PEC activity and wide practical applications.
关键词： Water Splitting,Silver nanoparticle,PaNi,NaNbO3,Ag/PaNi/NBO
更新于2025-09-23 15:19:57