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oe1(光电查) - 科学论文

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出版时间
  • 2018
研究主题
  • thin-film transistors
  • N2O plasma treatment.
  • amorphous InGaZnO
  • gate-bias stress
  • stability
应用领域
  • Electronic Science and Technology
机构单位
  • Peking University
567 条数据
?? 中文(中国)
  • Improvement of Sensing Performance of Impedancemetric C2H2 Sensor Using SmFeO3 Thin-Films Prepared by a Polymer Precursor Method

    摘要: A sensitive an impedancemetric acetylene (C2H2) gas sensor device could be fabricated by using perovskite-type SmFeO3 thin-film as a sensor material. The uniform SmFeO3 thin-films were prepared by spin-coating and focusing on the effects of polymer precursor solutions. The prepared precursors and thin-films were characterized by means of thermal analysis, Fourier-transform infrared spectroscopy, ultraviolet–visible spectroscopy, X-ray diffraction analysis, scanning electron microscopy and X-ray photoelectron spectroscopy. It was found that particle growth and increase in homogeneity of the prepared thin-film could be accelerated by the addition of acetyl acetone (AcAc) as a coordination agent in the polymer precursor solution. Moreover, the highly crystallized thin-film-based sensor showed good response properties and stabilities to a low C2H2 concentration between 0.5 and 2.0 ppm.

    关键词: polymer precursor,acetyl acetone,thin-film,gas sensor,acetylene,perovskite-type oxide,AC impedance

    更新于2025-11-14 15:15:56

  • Stepped Annealed Inkjet-Printed InGaZnO Thin-Film Transistors

    摘要: The preparation of thin-film transistors (TFTs) using ink-jet printing technology can reduce the complexity and material wastage of traditional TFT fabrication technologies. We prepared channel inks suitable for printing with different molar ratios of their constituent elements. Through the spin-coated and etching method, two different types of TFTs designated as depletion and enhancement mode were obtained simply by controlling the molar ratios of the InGaZnO channel elements. To overcome the problem of patterned films being prone to fracture during high-temperature annealing, a stepped annealing method is proposed to remove organic molecules from the channel layer and to improve the properties of the patterned films. The different interfaces between the insulation layers, channel layers, and drain/source electrodes were processed by argon plasma. This was done to improve the printing accuracy of the patterned InGaZnO channel layers, drain, and source electrodes, as well as to optimize the printing thickness of channel layers, reduce the defect density, and, ultimately, enhance the electrical performance of printed TFT devices.

    关键词: thin-film transistor,annealing,plasma treatment,ink-jet printing

    更新于2025-10-24 16:37:46

  • Complexing agent triethanolamine mediated synthesis of nanocrystalline CuO thin films at room temperature via SILAR technique

    摘要: In the present work, nanostructured cupric oxide (CuO) thin films have been successfully deposited on glass substrates by successive ionic layer adsorption and reaction (SILAR) technique at room temperature. The influence of complexing agent as triethanolamine (TEA) on the structural, morphological, optical and electrical characteristics of nanocrystalline CuO thin films have been examined in detail. Structural studies confirm that all the films were polycrystalline nature having a monoclinic crystalline form and displayed (111) and (111) preferential orientations. The estimated crystallite values ranged from 17.47 to 19.95 nm. The surface morphology of CuO thin films was examined through scanning electron microscopy and materials microscope studies. Surface studies revealed that homogeneously distributed CuO nanostructures on the film surfaces. The optical studies showed that band gap energy values of the CuO thin films were increased from 1.33 to 2.00 eV as a function of increasing TEA concentration. Meanwhile, the average transmittance of all the films had increased from 2.5 to 42.5% with the increasing TEA concentration. FTIR studies identified the formation of single phase CuO and chemical bonding of the complexing agent. The resistivity value of CuO thin film synthesized without TEA was 3.74 × 10^5 Ω.cm and the resistivity consequently increased to 509 × 10^5 Ω.cm with TEA concentration of 1.0 M%. A high figure of merit (786×10^{-12} Ω^{-1}) was obtained for complexing agent concentration of 0.25 M%.

    关键词: SILAR,Surfactant,TEA,CuO thin film

    更新于2025-10-24 16:32:58

  • Growth and characterization of hybrid (HoGO/P3HT) graphene-based nanostructures for photovoltaic (PV) applications.

    摘要: Herein, we present a comparative study between nanostructures of poly(3-hexylthiophene) (P3HT), Holmium-Graphene Oxide (HoGO) nanocomposite and hybrid HoGO/P3HT thin-film nanostructures in terms of structural, morphological and spectroscopic properties. Specifically, the graphene based GO nanostructure was functionalized with rear earth ion Ho(III) to improve its mobility. Furthermore, semiconducting P3HT nanostructure was successfully grown with HoGO nanocomposite creating hybrid HoGO/P3HT nanostructure for energy materials. The nanostructures were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), (FTIR) and UV/VIS/NIR spectroscopy. The interaction between HoGO and HoGO/P3HT nanostructures is evidenced through substantial variations in nanoparticle morphologies. FTIR results provided the evidence of the presence of different types of carbon functionalities in the nanostructures. From the absorption spectra, growth of hybrid HoGO/P3HT nanostructure broadened the absorbance with a slight decrease in %. These nanostructures open a promising direction on growth of hybrids for photovoltaic applications because of their interesting optical properties.

    关键词: nanostructures,Hybrid,nanocomposite,thin-film,photovoltaics

    更新于2025-10-22 19:40:53

  • Evaluation of solar factor using spectral analysis for CdTe photovoltaic glazing

    摘要: Solar and luminous light transmission control using Cadmium Telluride (CdTe) based PV glazing systems (15cm × 15 cm × 0.6 cm) were evaluated in this work. Indoor spectral characterisation showed that average solar transmission for investigated three different CdTe glazing systems were 5.77% (CdTe1), 9.54% (CdTe2) and 12.34% (CdTe3). Spectral behaviour of reflections in the range of solar and visible wavelengths was similar for these three different transparent CdTe glazing. Near infrared (NIR) reflection was higher compared to luminous reflection after 1500 nm for all three glazing systems. Solar factor (SF) for CdTe1, CdTe2 and CdTe3 glazing were 0.23, 0.28, 0.26. CdTe3 is the best candidate for glazing application as it has 113% higher luminous transmission while SF only increases by 21% compared to CdTe1.

    关键词: transmission,reflection,solar factor,glazing,Cadmium Telluride (CdTe),thin film solar cell

    更新于2025-10-22 19:40:53

  • [IEEE 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC) - Waikoloa Village, HI, USA (2018.6.10-2018.6.15)] 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion (WCPEC) (A Joint Conference of 45th IEEE PVSC, 28th PVSEC & 34th EU PVSEC) - Mitigating optical losses in crystalline silicon thin-film solar cells on glass

    摘要: Liquid phase crystallized silicon thin-film solar cells on glass provide efficiencies up to 14.2 %. While open-circuit voltage and fill factor are already comparable to wafer-based devices, short-circuit current density is reduced due to incomplete light absorption. This paper analyzes the losses of current device designs in experiment and one-dimensional simulations, revealing the low absorber thickness of 15-20 μm as well as the planar glass-silicon interface as the main cause of non-absorption. Interface textures, in particular a sinusoidal texture and a smooth anti-reflective three-dimensional (SMART) texture, are discussed concerning their potential to mitigate these losses, allowing to reduce losses at the glass-silicon interface by at least 40% relative. Taking the electronic interface quality into account, the SMART texture is identified as the most promising texture for light management in liquid phase crystallized silicon thin-film solar cells on glass.

    关键词: light management,thin-film solar cells,absorption enhancement,silicon

    更新于2025-10-22 19:40:53

  • Photocatalytic performance of TiO2 thin film decorated with Cu2O nanoparticles by laser ablation

    摘要: Cu2O nanoparticles decorated TiO2 thin films were fabricated by laser ablation. The effects of Cu2O nanoparticles on the structure, optical properties and photocatalytic performance of TiO2 thin film were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), Raman spectrometer system, optical absorption and photocatalytic evaluation system, respectively. XRD patterns indicate that the decoration has the effect of lowering the grain orientation of Cu2O. The photocatalytic performance in hydrogen generation of Cu2O decorated TiO2 composite thin film was significantly improved compared with that of either Cu2O nanoparticles or TiO2 single layer thin film with 1.70 and 1.77 times, respectively. The oxidation of Cu2O was demonstrated to dominate the photocatalytic performances of Cu2O/TiO2 composite thin films by varying the laser ablation powers.

    关键词: Heterojunction,Cu2O nanoparticles,Laser ablation,Photocatalytic performance,TiO2 thin film

    更新于2025-10-22 19:40:53

  • Light management in crystalline silicon thin-film solar cells with imprint-textured glass superstrate

    摘要: The implementation of light management textures in thin-film solar cells often simultaneously causes an undesired deterioration of electronic performance. Here, we introduce a simple yet effective technique for improved light management in liquid phase crystallized silicon thin-film solar cells on glass. By imprinting pyramidal textures on the sun-facing side of the glass superstrate, absorber and functional layers of the device remain unaffected while light in-coupling is significantly increased. An increase of short-circuit current density by 2.5 mA cm2 was observed by texturing the glass in this way, corresponding to an enhanced power conversion efficiency from 12.9% to 13.8%. Optical simulations allow to attribute the increase in equal shares to an anti-reflective effect at the air-glass interface as well as light scattering and multiple passes through the glass. The technology allows for independent optimization of optical performance without compromising on electronic material issues and is therefore useable for any other solar cell technology using a glass superstrate.

    关键词: Light management,Nano-imprint lithography,Liquid phase crystallization,Thin-film solar cells,Silicon

    更新于2025-10-22 19:40:53

  • Enhanced electrical conductivity of transparent electrode using metal microfiber networks for gridless thin-film solar cells

    摘要: Improving the optical transmittance and electrical conductivity in transparent conductors (TC) has been a critical issue for decades due to their numerous applications. In this paper, we suggest an approach to produce extremely conductive TC material from electroplated Ni microfiber networks (NiMFs) in order to achieve highly efficient and aesthetically superior thin-film solar cells and modules. The high cross-sectional aspect ratio of NiMFs significantly enhanced their electrical conductivity and optical transmittance simultaneously. The TC structure employing NiMFs was a successful substitute for conventional patterned grids in Cu(In,Ga)Se2 thin-film solar cells because it reduced the series resistance, which is especially advantageous for large-area cells. The NiMF-induced transmittance loss was compensated for by the formation of a light diffusion layer on the NiMF. We propose that the excellent performance of NiMF TC materials enables the elimination or significant reduction of the grids in thin-film solar cells and modules.

    关键词: Ni fibers,Gridless,Thin-film solar cells,Transparent electrodes

    更新于2025-10-22 19:40:53

  • Percolation Effects in Electrolytically-Gated WS <sub/>2</sub> /Graphene Nano:Nano Composites

    摘要: Mixed networks of conducting and non-conducting nanoparticles show promise in a range of applications where fast charge transport is important. While the dependence of network conductivity on the conductive mass fraction (Mf) is well understood, little is known about the Mf-dependence of mobility and carrier density. This is particularly important as the addition of graphene might lead to increases in the mobility of semiconducting nanosheet-network transistors. Here, we use electrolytic gating to investigate the transport properties of spray-coated composite networks of graphene and WS2 nanosheets. As the graphene Mf is increased, we find both conductivity and carrier density to increase in line with percolation theory with percolation thresholds (~8 vol%) and exponents (~2.5) consistent with previous reporting. Perhaps surprisingly, we find the mobility increases modestly from ~0.1 cm2/Vs (for a WS2 network) to ~0.3 cm2/Vs (for a graphene network) which we attribute to the similarity between WS2-WS2 and graphene-graphene junction resistances. In addition, we find both the transistor on- and off-currents to scale with Mf according to percolation theory, changing sharply at the percolation threshold. Through fitting, we show that only the current in the WS2 network changes significantly upon gating. As a result, the on-off ratio falls sharply at the percolation threshold from ~104 to ~2 at higher Mf. Reflecting on these results, we conclude that the addition of graphene to a semiconducting network is not a viable strategy to improve transistor performance as it reduces the on:off ratio far more than it improves the mobility.

    关键词: graphene,ionic liquid,thin film transistor,WS2,carrier density,composite,mobility,Printed electronics

    更新于2025-10-22 19:40:53