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- 摘要
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- 实验方案
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Stable Sn/Pb-Based Perovskite Solar Cells with a Coherent 2D/3D Interface
摘要： Low-band-gap metal halide perovskite semiconductor based on mixed Sn/Pb is a key component to realize high-ef?ciency tandem perovskite solar cells. However, the mixed perovskites are unstable in air due to the oxidation of Sn2+. To overcome the stability problem, we introduced N-(3-aminopropyl)-2-pyrrolidinone into the CH3NH3Sn0.5Pb0.5IxCl3-x thin ?lm. The carbonyl group on the molecule interacts with Sn2+/Pb2+ by Lewis acid coordination, forming vertically oriented 2D layered perovskite. The 2D phase is seamlessly connected to the bulk perovskite crystal, with a lattice coherently extending across the two phases. Based on this 2D/3D hybrid structure, we assembled low-band-gap Sn-based perovskite solar cells with power conversion ef?ciency greater than 12%. The best device was among the most stable Sn-based organic-inorganic hybrid perovskite solar cells to date, keeping 90% of its initial performance at ambient condition without encapsulation, and more than 70% under continuous illumination in an N2-?lled glovebox for over 1 month.
关键词： power conversion efficiency,2D/3D interface,stability,Sn/Pb-based,perovskite solar cells
更新于2025-11-21 11:18:25
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High lying energy of charge-transfer states and small energetic offsets enabled by fluorinated quinoxaline-based alternating polymer and alkyl-thienyl side-chain modified non-fullerene acceptor
摘要： Significant driving forces are the prerequisite to achieve fast and efficient charge separation in fullerene derivatives-based polymer solar cells to achieve high power conversion efficiency (PCE). However, the large driving forces both in photo-induced hole transfer (PHT) and in photo-induced electron transfer (PET) processes lead to significant energy losses, resulting in low open-circuit voltage in the devices. Recent studies indicate the driving forces in non-fullerene acceptors-based devices can be reduced to very low values but still with high PCE and low energy losses. Herein, we report a new donor:acceptor system with high lying energy of charge-transfer excitons (ECT) of 1.50 eV and very small driving forces (PHT of 0.28 eV and PET of 0.11 eV), in which a fluorinated quinoxaline-based alternating polymer (FTQ) and an alkyl-thienyl side-chain modified small molecule (ITIC-Th) are taken as the donor material and non-fullerene acceptor material, respectively. A high power conversion efficiency (PCE) of 8.19% with maximal external quantum efficiency of 71% are achieved successfully in FTQ:ITIC-Th-based device after appropriate thermal annealing treatment, indicating FTQ can be further applied as donor materials with other highly efficient NF-acceptors to achieve enhanced performances and low energy losses.
关键词： Power conversion efficiency,Driving forces,Energy of charge-transfer states,Polymer solar cells
更新于2025-11-14 17:28:48
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Thinning ferroelectric films for high-efficiency photovoltaics based on the Schottky barrier effect
摘要： Achieving high power conversion efficiencies (PCEs) in ferroelectric photovoltaics (PVs) is a longstanding challenge. Although recently ferroelectric thick films, composite films, and bulk crystals have all been demonstrated to exhibit PCEs >1%, these systems still suffer from severe recombination because of the fundamentally low conductivities of ferroelectrics. Further improvement of PCEs may therefore rely on thickness reduction if the reduced recombination could overcompensate for the loss in light absorption. Here, a PCE of up to 2.49% (under 365-nm ultraviolet illumination) was demonstrated in a 12-nm Pb(Zr0.2Ti0.8)O3 (PZT) ultrathin film. The strategy to realize such a high PCE consists of reducing the film thickness to be comparable with the depletion width, which can simultaneously suppress recombination and lower the series resistance. The basis of our strategy lies in the fact that the PV effect originates from the interfacial Schottky barriers, which is revealed by measuring and modeling the thickness-dependent PV characteristics. In addition, the Schottky barrier parameters (particularly the depletion width) are evaluated by investigating the thickness-dependent ferroelectric, dielectric and conduction properties. Our study therefore provides an effective strategy to obtain high-efficiency ferroelectric PVs and demonstrates the great potential of ferroelectrics for use in ultrathin-film PV devices.
关键词： power conversion efficiency,Schottky barrier effect,ferroelectric photovoltaics,PZT ultrathin film,depletion width
更新于2025-11-14 17:28:48
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Au@Ag@Ag2S heterogeneous plasmonic nanorods for enhanced dye-sensitized solar cell performance
摘要： Au@Ag@Ag2S heterogeneous nanorods (NRs) with two strong plasmonic absorptive bands were developed for boosting the performance of dye-sensitized solar cells, and the remarkably enhanced plasmonic devices were achieved. By doping different concentrations of the Au@Ag@Ag2S NRs within the TiO2 photoanode layers, various enhanced effects of the plasmonic devices were obtained. With the incorporation of the typical Au@Ag@Ag2S NRs (their aspect ratios: 2.7) into the TiO2 photoanodes, the top efficiency of 6.51% of the fabricated plasmonic photovoltaic devices at their doped concentrations of the 2.31% was observed, exhibiting dramatic 40% enhancement than that of the conventional dye-sensitized solar cells (bare device: 4.65%). Benefiting from effective surface plasmon effects of the Au@Ag@Ag2S NRs, the light-harvesting abilities of photoanodes and dyes in devices are dramatically enhanced, which in return boost the whole performance of photovoltaic devices significantly.
关键词： Dye-sensitized solar cell,Nanorod,Power conversion efficiency,Plasmonic effect
更新于2025-11-14 15:27:09
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Enabling low voltage losses and high photocurrent in fullerene-free organic photovoltaics
摘要： Despite significant development recently, improving the power conversion efficiency of organic photovoltaics (OPVs) is still an ongoing challenge to overcome. One of the prerequisites to achieving this goal is to enable efficient charge separation and small voltage losses at the same time. In this work, a facile synthetic strategy is reported, where optoelectronic properties are delicately tuned by the introduction of electron-deficient-core-based fused structure into non-fullerene acceptors. Both devices exhibited a low voltage loss of 0.57 V and high short-circuit current density of 22.0 mA cm?2, resulting in high power conversion efficiencies of over 13.4%. These unconventional electron-deficient-core-based non-fullerene acceptors with near-infrared absorption lead to low non-radiative recombination losses in the resulting organic photovoltaics, contributing to a certified high power conversion efficiency of 12.6%.
关键词： non-fullerene acceptors,power conversion efficiency,voltage losses,charge separation,organic photovoltaics
更新于2025-11-14 15:18:02
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Effect of Thionation on the Performance of PNDIT2-Based Polymer Solar Cells
摘要： All-polymer solar cells have gained traction in recent years with solar cell performance of over 11% power conversion efficiency (PCE) recently demonstrated. The n-type polymer PNDIT2, also known as N2200 or P(NDI2OD-T2), has been extensively used for both photovoltaic as well as field-effect transistor applications. When paired with donor materials that have appropriately aligned energy-levels, PNDIT2 has exhibited device efficiencies over 10% PCE, and organic field effect transistors fabricated with PNDIT2 exhibit mobilities over 1 cm2/Vs. Thionation of the NDI moiety, which is the substitution of imide oxygen with sulfur atoms, has been shown to improve the field-effect transistor performance of NDI-based small molecules. Applying this strategy to PNDIT2, we explored the effect that thionation, in a 2S-trans configuration, has on the performance of all-polymer solar cells fabricated with the donor polymer PTB7-Th. Solar cells were fabricated with the original polymer, PNDIT2, as a reference, and an optimized efficiency of 4.85% was achieved. As samples with 100% conversion to 2S-trans configuration could not be produced due to synthetic limitations, batches with increasing ratios of 1S to 2S-trans thionation (15:85, 7:93, and 5:95) were studied. Devices with thionated PNDIT2 exhibited a systematic lowering of photovoltaic parameters with increasing thionation, resulting in device efficiencies of just 0.84%, 0.62%, and 0.42% PCE. The lower performance of the thionated blends is attributed to poor π-π stacking order in the thionated PNDIT2 phase, resulting in lower electron mobilities and finer phase separation. Evidence in support of this conclusion is provided by grazing incidence wide-angle X-ray scattering, transmission electron microscopy, photoluminescence quenching, transient photocurrent analysis, and SCLC measurements.
关键词： π-π stacking,PNDIT2,Thionation,All-polymer solar cells,Power conversion efficiency
更新于2025-10-22 19:40:53
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Single-Phase Transformer based HF-Isolated Z- Source Inverters with Voltage Clamping Techniques for Solar PV Applications
摘要： In this research article, a new family of impedance source inverters is presented. It employs high frequency electrical isolation between the inverter bridge switches and the load along with voltage clamping across the DC-link voltage. Conventional Z-source inverters (ZSIs) employs an impedance network that consists of inductors and capacitors. It has unique features which realize both step-up/step-down functions and eliminates the need of dead/overlap times. This paper extends this novel concept by using electrical isolation in impedance source inverters. High frequency isolation has many advantages in terms of immunity and reliability; when applied with impedance source inverters this makes ZSIs a preferable choice for industrial applications. In PV systems, the addition of the high frequency transformer provides safety by avoiding the injection of DC circulating current into the grid, without the need of an external bulky line frequency transformer. The gain of the proposed inverter design can be accurately selected by choosing the turns ratio of the HFT or by adjusting the shoot-through duty cycle (STDC) to the inverter. This allows for greater freedom especially when utilizing a higher modulation index, with the STDC allowing dynamic gain adjusts to be done speedily during operation of the inverter. Additionally, a DC-rail voltage clamping technique for the proposed class of isolated ZSIs is also discussed. This technique provides benefits not only in improving the output voltage quality, but also in reducing voltage stress of the active and passive components by minimizing the voltage spikes across the switching devices. In this paper, several high frequency isolated ZSIs are presented, and an example isolated improved ΓZSI design is shown and discussed in detail. Simulations are provided for the proposed class of isolated inverters to verify their working. Further experimental investigation has been done for which results for the isolated improved ΓZSI are reported. These empirical results have largely confirmed the expected benefits that were determined through simulation and accurate model-based testing.
关键词： Single stage power conversion,Higher voltage gain,Impedance source,frequency isolation,High frequency transformers
更新于2025-09-23 15:23:52
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Contribution to the System Design of Contactless Energy Transfer Systems
摘要： In this contribution, a design procedure that is applicable to many kinds of wireless or contactless energy transfer systems is proposed. The design procedure is limited to near field wireless energy transfer systems in resonant operation. For this purpose, the input impedance and voltage transfer function of different natural frequencies are calculated analytically, and moreover, the behavior of the system is described. Following three issues lead to a readily applicable design procedure. First, the knowledge of the transfer functions. Secondly, the knowledge of basic magnetic properties and lastly, the known influence of harmonics according to rectifier and inverter. This design procedure is demonstrated with two hardware setups.
关键词： Inductive power transmission,power conversion harmonics,transfer functions,resonant inverters,inductive,charging
更新于2025-09-23 15:22:29
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A Dual-Discrete Model Predictive Control-based MPPT for PV systems
摘要： This paper presents a method that overcomes the problem of the confusion during fast irradiance change in the classical MPPTs as well as in model predictive control (MPC)-based MPPTs available in the literature. The previously introduced MPC-based MPPTs take into account the model of the converter only, which make them prone to the drift during fast environmental conditions. Therefore, the model of the PV array is also considered in the proposed algorithm, which allows it to be prompt during rapid environmental condition changes. It takes into account multiple previous samples of power, and based on that is able to take the correct tracking decision when the predicted and measured power differ (in case of drift issue). After the tracking decision is taken, it will be sent to a second part of the algorithm as a reference. The second part is used for following the reference provided by the first part, where the pulses are sent directly to the converter, without a modulator or a linear controller. The proposed technique is validated experimentally by using a buck converter, fed by a PV simulator. The tracking efficiency is evaluated according to EN50530 standard in static and dynamic conditions. The experimental results show that the proposed MPC-MPPT is a quick and accurate tracker under very fast changing irradiance, while maintaining high tracking efficiency even under very low irradiance.
关键词： Buck converter,dc-dc power conversion,Photovoltaic systems,Double cost function,Maximum power point tracking,Drift,EN50530 standard,MPC
更新于2025-09-23 15:22:29
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High Bandwidth Non-Resonant High Voltage Generator for X-Ray Systems
摘要： High-voltage supplies for medical X-ray systems require up to 150 kV DC at up to 100 kW to supply the tube. The challenge for the power supply however is not only to deal with the high voltage and high power demand, but also to provide short voltage rise- and fall times in the range of 100μs. A coupled interleaved circuit variant of a single active bridge concept, the coupled interleaved single active bridge converter, is demonstrated in this work providing very fast output voltage control due to its non-resonant structure. The conduction modes of the circuit are analysed in detail and compared to the uncoupled interleaved single active bridge approach, demonstrating the advantages of low inverter RMS current, zero voltage switching (or at least zero current switching) over the full operating range with constant switching frequency. Analytic expressions for the output current-duty cycle relationship are provided. Experiments on a 60 kW (low voltage equivalent) prototype show that rise times as low as five switching cycles are possible, allowing to reach the target of 100μs rise time using a switching frequency of only 50 kHz.
关键词： DC-DC power conversion,high bandwidth,high voltage generator,X-ray generator
更新于2025-09-23 15:22:29