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Wear and Corrosion Resistance of Al0.5CoCrCuFeNi High-Entropy Alloy Coating Deposited on AZ91D Magnesium Alloy by Laser Cladding
摘要： In order to improve the wear and corrosion resistance of an AZ91D magnesium alloy substrate, an Al0.5CoCrCuFeNi high-entropy alloy coating was successfully prepared on an AZ91D magnesium alloy surface by laser cladding using mixed elemental powders. Optical microscopy (OM), scanning electron microscopy (SEM), and X-ray diffraction were used to characterize the microstructure of the coating. The wear resistance and corrosion resistance of the coating were evaluated by dry sliding wear and potentiodynamic polarization curve test methods, respectively. The results show that the coating was composed of a simple FCC solid solution phase with a microhardness about 3.7 times higher than that of the AZ91D matrix and even higher than that of the same high-entropy alloy prepared by an arc melting method. The coating had better wear resistance than the AZ91D matrix, and the wear rate was about 2.5 times lower than that of the AZ91D matrix. Moreover, the main wear mechanisms of the coating and the AZ91D matrix were different. The former was abrasive wear and the latter was adhesive wear. The corrosion resistance of the coating was also better than that of the AZ91D matrix because the corrosion potential of the former was more positive and the corrosion current was smaller.
关键词： laser cladding,wear,AZ91D magnesium alloy,high-entropy alloy coating,corrosion
更新于2025-11-21 11:24:58
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A study of metallurgy and erosion in laser surface alloying of AlxCu0.5FeNiTi high entropy alloy
摘要： AlxCu0.5FeNiTi high entropy alloy coating is synthesized by premixed high purity Cu, Fe, Ni and Ti powders on AA1050 aluminium substrate by laser surface alloying, with the aim to improve microhardness and erosion rate. Phase constituents, microstructure and microhardness were investigated using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Vickers Microhardness tester, respectively. The erosion behavior of AlxCu0.5FeNiTi coating is checked using an air jet erosion setup. SEM images show presence of three regions. Percentage compositions of these regions are evaluated using Energy Dispersive Spectroscopy. XRD analysis of AlxCu0.5FeNiTi coating confirmed that these regions are a mixture of disordered BCC and two FCC solid solution phases. The microhardness of the AlxCu0.5FeNiTi HEA is 18 times that of the AA1050 aluminium substrate. Results show that AlxCu0.5FeNiTi HEA coating has improved erosion resistance.
关键词： Laser Surface Alloying,Microhardness,Microstructure,High Entropy Alloy,Erosion rate
更新于2025-11-21 11:18:25
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Rapid Alloy Development of Extremely High-Alloyed Metals Using Powder Blends in Laser Powder Bed Fusion
摘要： The design of new alloys by and for metal additive manufacturing (AM) is an emerging field of research. Currently, pre-alloyed powders are used in metal AM, which are expensive and inflexible in terms of varying chemical composition. The present study describes the adaption of rapid alloy development in laser powder bed fusion (LPBF) by using elemental powder blends. This enables an agile and resource-efficient approach to designing and screening new alloys through fast generation of alloys with varying chemical compositions. This method was evaluated on the new and chemically complex materials group of multi-principal element alloys (MPEAs), also known as high-entropy alloys (HEAs). MPEAs constitute ideal candidates for the introduced methodology due to the large space for possible alloys. First, process parameters for LPBF with powder blends containing at least five different elemental powders were developed. Secondly, the influence of processing parameters and the resulting energy density input on the homogeneity of the manufactured parts were investigated. Microstructural characterization was carried out by optical microscopy, electron backscatter diffraction (EBSD), and energy-dispersive X-ray spectroscopy (EDS), while mechanical properties were evaluated using tensile testing. Finally, the applicability of powder blends in LPBF was demonstrated through the manufacture of geometrically complex lattice structures with energy absorption functionality.
关键词： multi-principal element alloys,high-entropy alloys,additive manufacturing,rapid alloy development,powder blends,laser powder bed fusion
更新于2025-11-21 11:01:37
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Precipitation behavior of selective laser melted FeCoCrNiC0.05 high entropy alloy
摘要： Interstitial elements are e?ective to strengthen high entropy alloys (HEAs). In this work, FeCoCrNiC0.05 was prepared by selective laser melting (SLM) followed by annealing. The e?ects of annealing on the microstructures and mechanical properties of the SLMed FeCoCrNiC0.05 were investigated. Results show that, nano-scale Cr23C6-type carbides can precipitate under annealing conditions, leading to higher yielding strength. The SLMed FeCoCrNiC0.05 annealed at 1073 K for 0.5 h has a yielding strength of 787 MPa and an elongation of 10.3%. Precipitation kinetics in SLMed FeCoCrNiC0.05 has been established according to Avrami formula. The high strength can be attributed to solid solution hardening, precipitation hardening and cell-like structures.
关键词： Precipitation kinetics,Hardening mechanism,Selective laser melting,Mechanical properties,High entropy alloy
更新于2025-11-14 17:04:02
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In situ TiN-reinforced CoCr2FeNiTi0.5 high-entropy alloy composite coating fabricated by laser cladding
摘要： The fcc structural CoCr2FeNiTi0.5 high-entropy alloy (HEA) composite coating with TiN particles reinforced was acquired by laser cladding on the commercial 904L stainless steels. The results show that phase structure is mainly composed of fcc solid solution and TiN phases. The coating exhibits excellent structural stability below 850 °C. The microstructure consists of irregular dendrite and TiN particles. Transmission electron microscopy (TEM) results reveal that the close-packed plane of fcc phase is (111) with interplanar spacing of * 0.208 nm. The interface between TiN and fcc matrix is semi-coherent. And the angle of boundary between dendrite and matrix is * 65°. The hardness and corrosion resistance of coating have much improvement compared with those of substrate.
关键词： Semi-coherent interface,High-entropy alloy,Laser cladding,TiN particle reinforced
更新于2025-09-23 15:22:29
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Microstructure and properties of CeO2-doped CoCrFeMnNi high entropy alloy fabricated by laser metal deposition
摘要： Rare earth elements are usually regarded as e?cient additives for property enhancement of many types of alloys. In the present study, the CoCrFeMnNi high entropy alloy (HEA) was doped with CeO2, and such composites were for the ?rst time obtained by the laser metal deposition (LMD) process. The microstructure, phase compositions, microhardness and crystallographic texture of the HEA/CeO2 composites were investigated. It was demonstrated that CoCrFeMnNi HEA/CeO2 samples were successfully obtained by the LMD process. Meanwhile, small irregular shape oxides rich in Mn and Cr were observed in the HEA/ CeO2 composite. Rare earth element Ce was found to be evenly distributed throughout the sample. Heterogeneous dendritic microstructure with a long columnar grains oriented along the build direction was observed. The measured average microhardness is 181.72 ± 9.72 HV0.1.
关键词： Composite,CeO2,High entropy alloy,Laser metal deposition,Additive manufacturing,CoCrFeMnNi
更新于2025-09-23 15:21:01
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Laser processing as a high-throughput method to investigate microstructure-processing-property relationships in multiprincipal element alloys
摘要： A direct laser deposition processing method was applied to construct compositional and microstructural libraries of AlxCoCrFeNi in an efficient and high-throughput manner. Among the compositions (x ? 0.51 e1.25) and quench rates (26e6400 K/s) studied, most of the laser deposited alloys exhibit a cellular microstructure, similar to the cast materials. The microstructural feature sizes were found to follow a power law relationship with the quench rate. The dependence of the microhardness on microstructural length scale was also investigated and observed to follow a Hall-Petch relationship. This study indicates that laser processing is an effective method for rapidly and efficiently evaluating multiprincipal element alloys and their microstructures.
关键词： Direct laser deposition,High-entropy alloys,Mechanical property,Microstructure
更新于2025-09-19 17:13:59
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Fatigue behaviour of a laser beam welded CoCrFeNiMn-type high entropy alloy
摘要： Laser beam welding was used to produce butt joints from the CoCrFeNiMn-type high entropy alloy. The alloy in the initial condition had an fcc single-phase coarse-grained structure. Laser welding resulted in the M7C3-type carbides precipitation in the fcc matrix. The carbide particles precipitation resulted in a considerable increase in microhardness from 150 HV 0.5 for the as-sintered condition to 205 HV 0.5 in the fusion zone. Laser beam welding had a negligible effect on both static mechanical properties and fatigue behaviour of the alloy. The endurance limit of either type of specimens (i.e. with and without welding seam) was 200 MPa. Fracture of all specimens with the laser beam welded seams occurred in the base material area during both tensile and fatigue testing. Weak effect of welding on static/fatigue behaviour of the alloy can be attributed to the higher hardness of the fusion zone, resulting in strain localization in the base material area. An increase in load resulted in activation of secondary slip systems and formation of deformation twins in fatigue specimens.
关键词： Fatigue,Tensile strength,Microstructure,Laser beam welding,High entropy alloy
更新于2025-09-16 10:30:52
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Laser Beam Welding of a Low Density Refractory High Entropy Alloy
摘要： The effect of laser beam welding on the structure and properties of a Ti1.89NbCrV0.56 refractory high entropy alloy was studied. In particular, the effect of different pre-heating temperatures was examined. Due to the low ductility of the material, laser beam welding at room temperature resulted in the formations of hot cracks. Sound butt joints without cracks were produced using pre-heating to T ≥ 600 °C. In the initial as-cast condition, the alloy consisted of coarse bcc grains with a small amount of lens-shaped C15 Laves phase particles. A columnar microstructure was formed in the welds; the thickness of the grains increased with the temperature of pre-heating before welding. The Laves phase particles were formed in the seams after welding at 600 °C or 800 °C, however, these particles were not observed after welding at room temperature or at 400 °C. Soaking at elevated temperatures did not change the microstructure of the base material considerably, however, “additional” small Laves particles formed at 600 °C. Tensile test of welded specimens performed at 750 °C resulted in the fracture of the base material because of the higher hardness of the welds. The latter can be associated with the bcc grains refinement in the seams.
关键词： microstructure,mechanical properties,laser beam welding,high entropy alloys
更新于2025-09-12 10:27:22
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High‐entropy transparent fluoride laser ceramics
摘要： For the first time, a transparent high‐entropy fluoride laser ceramic has been prepared and characterized. X‐ray diffraction (XRD) analysis of a CeNdCaSrBaF12 (CNCSBF) transparent ceramic consolidated by vacuum hot pressing (VHP) reveals that Ce3+, Nd3+, Ca2+, Sr2+, and Ba2+ have formed a single‐phased fluorite solid solution, with a lattice constant of 5.826??. Bulk density measurements produced a value of 6.15?g/cm3. Scanning electron microscopy (SEM) analysis of the ceramic revealed a uniform distribution of grain sizes in the material, with the average grain size being approximately 20?μm. The material exhibits a maximum in‐line transmittance of approximately 60% at 1000?nm. A near‐infrared range photoluminescence (PL) emission band was observed at 1057?nm, with a visible‐range PL emission band being located at 440?nm.
关键词： high entropy,transparent ceramics,optical properties,fluoride
更新于2025-09-11 14:15:04