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Rapid analysis of marble treatments by laser induced fluorescence
摘要： Nowadays scientific study of Cultural Heritage accompanies most of the time historical artistic evaluation and an assessment of the conservation state by humanistic experts and restorers. Several laboratory methods with high sensitivity are well established (ICP-MS, FTIR,…), and many methods for in situ rough characterization of large surface are widely diffused (thermovision, UV photography,…), in addition to instrumentation for punctual analysis to be applied also in field (XRF, colorimetry,…). However, the request for systems that can provide rapid detailed characterization on large surface in any storage conditions is still a hot topic. This is combined with the ever-increasing demand for digital material for documentation, fruition and study. Laser-based systems, and in particular Laser Induced Fluorescence (LIF), Laser Induced Breakdown Spectroscopy and Raman spectroscopy, due to the characteristics of these sources and the detectors to which they can be coupled, respond well to these needs. The TECFIS-DIM (Diagnostic and Metrology) Laboratory of the ENEA center of Frascati (Rome, Italy) in the last decade has put an effort to develop more and more compact and efficient laser systems for in situ material characterization on cultural heritage surfaces. Here two prototypal LIF systems have been used to characterize marble surfaces treated with ancient and modern materials and a rapid recognition and mapping method has been developed and tested thanks to the individuation of discriminant spectral features. Results are reported on test samples created in lab with known substances and in situ on real artworks.
关键词： Patinas,Marble,Polymers,Laser spectroscopies,Laser induced fluorescence (LIF)
更新于2025-09-23 15:19:57
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All-carbon THz components based on laser-treated diamond
摘要： We report on fs laser structuring and graphitization of diamond and experimental characterization of its THz response. A full characterization of graphitized, conductive layer generated by laser irradiation is carried out by performing scanning-electron microscopy, Raman spectroscopy and electrical measurements. The transmittance of the laser textured diamond samples, both with the graphitic overlayer and after selective oxidizing etching, is analyzed in the (0.25 ÷ 6.0) THz spectral range. A significant selective absorption of the graphitized overlayer towards polarized THz radiation is demonstrated, which is associated to the formation of graphitic laser induced periodic surface structures. This anisotropy allows conceiving compact passive metasurfaces based on conductive/dielectric patterns on the diamond plate surface for the development of robust, lightweight and broadband THz optical components.
关键词： graphitic laser induced periodic surface structures,graphitization,electrical measurements,fs laser structuring,THz response,transmittance,THz optical components,polarized THz radiation,conductive layer,diamond,Raman spectroscopy,metasurfaces
更新于2025-09-23 15:19:57
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Optical control of layered nanomaterial generation by pulsed-laser ablation in liquids
摘要： Pulsed-laser ablation in liquids capitalizes on combining chemical and optical control to rapidly generate size, composition, and phase-controlled nanostructures, without the need for surfactants. Very high temperatures, which we determined to be ca. (8,400 ± 1,300) K, pressures, and ion densities exist in the laser-induced liquid-confined plasma. These unique conditions, coupled with the rapid cooling during which nanoparticles are formed, permitted access to new extreme regions of materials’ phase diagrams. This way, we produced metastable layered copper and zinc hydroxide-based nanocrystals with interesting physical properties that can serve as precursors for two-dimensional inorganic semiconductor nanomaterials.
关键词： LTE spectra,optical control,electron temperature,layered nanocrystals,Pulsed-laser ablation in liquids,laser-induced plasma
更新于2025-09-23 15:19:57
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Correlation between plume fluctuation and keyhole dynamics during fiber laser keyhole welding
摘要： In order to reveal the fluctuation mechanism of the plume induced during fiber laser keyhole welding, dynamic behaviors of both the plume and the keyhole were simultaneously observed by using the multiple-imaging method. The results show that the fluctuation period of the plume was the same as that of the laser-induced vapor moving down on the keyhole front wall (KFW). The tilt angle of the plume was the largest when the laser-induced vapor was close to the orifice. As the laser-induced vapor moved toward the bottom of the KFW, the tilt angle of the plume decreased gradually. The correlation between the plume fluctuation and the dynamics of the laser-induced vapor on the KFW was not affected by parameters such as welding speed, laser power, and focal length. Further analysis shows that the periodic drilling behavior of the laser spot on the KFW is the main reason for the periodic fluctuation of the plume.
关键词： KFW,plume,fiber laser welding,laser-induced vapor,fluctuation
更新于2025-09-23 15:19:57
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Collinear dual-pulse laser optical breakdown and energy deposition
摘要： A non-equilibrium model for laser-generated plasmas is used to represent collinear dual nano-second-pulse interactions. In the specific case considered, the breakdown is initiated with an ultraviolet (UV) laser pulse at 266 nm, which pre-ionizes the gas, and it is followed by a near-infrared (NIR) pulse at 1064 nm, which deposits significant energy into the ionized mixture. The model is validated against corresponding experiments, and simulation results are interrogated to understand key features of the plasma-kernel dynamics in the breakdown phase, and the initial post-breakdown vorticity and plasma-core decay.
关键词： energy deposition,laser-induced breakdown,non-equilibrium plasma,plasma dynamics,dual-pulse laser
更新于2025-09-23 15:19:57
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Features of fused silica ablation by laser induced carbon microplasma
摘要： The features of surface structuring on the transparent material by laser-induced microplasma were studied and the intensity of its microplasma was measured. The formation of micro-relief by a series of nanosecond pulsed laser induced carbon microplasma in confinement mode on the surface of fused silica were investigated and the measured intensity was compared with the features of micro-relief. The dependence of depth of formed relief and track on the laser regime was determined. It is shown that the mechanism of microstructure formation is dependent on multifactor and associated with the ablation on the surface of fused silica by the microplasma, which exists quite long time after the pulses.
关键词： Ablation,Surface structuring,Laser-induced microplasma,Nanosecond pulses,Fiber laser,Fused silica
更新于2025-09-23 15:19:57
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Interactive tissue reactions of 1064a??nm focused picoseconda??domain laser and dermal cohesive polydensified matrix hyaluronic acid treatment in in vivo rat skin
摘要： Background: Picosecond-domain laser treatment using a microlens array (MLA) or a diffractive optical element (DOE) generates micro-injury zones in the epidermis and upper dermis. Objective: To investigate interactive tissue reactions between MLA-type picosecond laser pulses and cohesive polydensified matrix hyaluronic acid (CPMHA) filler in the dermis. Methods: In vivo rats with or without CPMHA pretreatment were treated with a 1064-nm picosecond-domain neodymium:yttrium-aluminum-garnet (Nd:YAG) laser using an MLA or DOE. Skin samples were obtained at post-treatment days 1, 10, and 21 and histologically and immunohistochemically analyzed. Results: Picosecond-domain Nd:YAG laser treatment with an MLA-type or a DOE-type handpiece generated fractionated zones of pseudo-cystic cavitation along the lower epidermis and/or upper papillary dermis at Day 1. At Day 21, epidermal thickness, dermal fibroblasts, and collagen fibers had increased. Compared to CPMHA-untreated rats, rats pretreated with CPMHA showed marked increases in fibroblasts and collagen fibers in the papillary dermis. Immunohistochemical staining for the hyaluronic acid receptor CD44 revealed that MLA-type picosecond laser treatment upregulated CD44 expression in the basilar epidermis and dermal fibroblasts. Conclusions: We suggest that the hyaluronic acid-rich environment associated with CPMHA treatment may enhance MLA-type picosecond-domain laser-induced tissue reactions in the epidermis and upper dermis.
关键词： laser,neodymium-doped yttrium aluminum garnet,cohesive polydensified matrix hyaluronic acid,laser-induced tissue breakdown,CD44,picosecond
更新于2025-09-23 15:19:57
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Coal Discrimination Analysis Using Tandem Laser-Induced Breakdown Spectroscopy and Laser Ablation Inductively Coupled Plasma Time-of-Flight Mass Spectrometry
摘要： The contribution and impact of combined laser ablation inductively coupled plasma time of flight mass spectrometry (LA-ICP-TOF-MS) and laser induced breakdown spectroscopy (LIBS) were evaluated for the discrimination analysis of different coal samples. This Tandem approach allows simultaneous determination of major and minor elements (C, H, Si, Ca, Al, Mg, etc), and trace elements (V, Ba, Pb, U, etc.) in the coal. The research focused on coal classification strategies based on principle component analysis (PCA) combined with K-means clustering, partial least squares discrimination analysis (PLS-DA), and support vector machine (SVM) for analytical performance. Correlation analyses performed from TOF mass and LIBS emission spectra from the coal samples showed that most major, minor, and trace elements emissions had negative correlation with the volatile content. Suitable variables for the classification models were determined from these data. The individual TOF data, LIBS data, and the combined data of TOF and LIBS, respectively, as the input for different models were analyzed and compared. In all cases, the results obtained with the combined TOF and LIBS data were found to be superior to those obtained with the individual TOF or LIBS data. The nonlinear SVM model combined with TOF and LIBS data provided the best coal classification performance, with a classification accuracy of up to 98%.
关键词： Principal component analysis,Support vector machine,Partial least squares discrimination analysis,Laser-induced breakdown spectroscopy,K-means clustering,Coal discrimination,Laser ablation inductively coupled plasma time of flight mass spectrometry
更新于2025-09-23 15:19:57
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Study of Thermal Effect in the Interaction of Nanosecond Capillary Discharge Extreme Ultraviolet Laser with Copper
摘要： Interaction of Extreme Ultraviolet (EUV) laser with matters is an attractive subject since novel phenomena always occur under the e?ect of high energy photons. In this paper, the thermal e?ect involved in the interaction of a capillary discharge 46.9 nm laser with copper was studied theoretically and experimentally. The temperature variation of the laser-irradiated region of copper was calculated. According to the results, the copper surface was ablated obviously and presented the trace of melting, evaporation, and resolidi?cation, which suggested the thermal e?ect occurred on the surface during the laser irradiation.
关键词： laser-induced damage,thermal e?ect,copper,46.9 nm laser
更新于2025-09-23 15:19:57
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Enhancement of photocatalytic activity by femtosecond-laser induced periodic surface structures of Si
摘要： Laser induced periodic surface structures (LIPSS) represent a kind of top down approach to produce highly reproducible nano/microstructures without going for any sophisticated process of lithography. This method is much simpler and cost effective. In this work, LIPSS on Si surfaces were generated using femtosecond laser pulses of 800 nm wavelength. Photocatalytic substrates were prepared by depositing TiO2 thin films on top of the structured and unstructured Si wafer. The coatings were produced by sputtering from a Ti target in two different types of oxygen atmospheres. In first case, the oxygen pressure within the sputtering chamber was chosen to be high (3 × 10–2 mbar) whereas it was one order of magnitude lower in second case (2.1 × 10–3 mbar). In photocatalytic dye decomposition study of Methylene blue dye it was found that in the presence of LIPSS the activity can be enhanced by 2.1 and 3.3 times with high pressure and low pressure grown TiO2 thin films, respectively. The increase in photocatalytic activity is attributed to the enlargement of effective surface area. In comparative study, the dye decomposition rates of TiO2 thin films grown on LIPSS are found to be much higher than the value for standard reference thin film material Pilkington ActivTM.
关键词： photocatalytic dye decomposition,silicon,femtosecond laser pulses,TiO2 thin film,laser induced periodic surface structures,nanoripples
更新于2025-09-23 15:19:57