- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Expansion dynamics and chemistry evolution in ultrafast laser filament produced plasmas
摘要： Laser ablation in conjunction with optical emission spectroscopy is a potential non-contact, standoff detection method for all elements in the periodic table and certain isotopes such as radionuclides. Currently, significant development efforts are on-going to use ultrafast laser filaments for remote detection of materials. The application of filaments is of particular interest in extending the range of stand-off capability associated with elemental and isotopic detection via laser-induced breakdown spectroscopy. In this study, we characterize the expansion dynamics and chemical evolution of filament-produced uranium (U) plasmas. Laser filaments are generated in the laboratory by loosely focusing 35 femtosecond (fs), 6 milli Joule (mJ) pulses in air. Two-dimensional spectrally-integrated and time-resolved imaging was performed to study hydrodynamics and evolution of U atomic and UO molecular emission in filament-produced U plasmas. Our results highlight that filament ablation of U plasmas gives a cylindrical plasma plume morphology with an appearance of plume splitting into slow and fast moving components at later times of its evolution. Emission from the slow-moving region shows no distinct spectral features (i.e. broadband-like) and is contributed in part by nanoparticles generated during ultrafast laser ablation. Additionally, we find U atoms and U oxide molecules (i.e. UO, UxOy) co-exist in the filament produced plasma, which can be attributed to the generation of low-temperature plasma conditions during filament ablation.
关键词： optical emission spectroscopy,Laser ablation,plasma chemistry,ultrafast laser filaments,uranium plasmas
更新于2025-09-23 15:19:57
-
Strongly inhomogeneous distribution of spectral properties of silicon-vacancy color centers in nanodiamonds
摘要： The silicon-vacancy (SiV) color center in diamond is a solid-state single photon emitter and spin quantum bit suited as a component in quantum devices. Here, we show that SiV centers in nanodiamonds exhibit a strongly inhomogeneous distribution with regard to the center wavelengths and linewidths of the zero-phonon-line (ZPL) emission at room temperature. We find that the SiV centers separate in two clusters: one group exhibits ZPLs with center wavelengths within a narrow range ≈730–742 nm and broad linewidths between 5 and 17 nm, whereas the second group comprises a very broad distribution of center wavelengths between 715 and 835 nm, but narrow linewidths from below 1 up to 4 nm. Supported by ab initio Kohn–Sham density functional theory calculations we show that the ZPL shifts of the first group are consistently explained by strain in the diamond lattice. Further, we suggest, that the second group showing the strongly inhomogeneous distribution of center wavelengths might be comprised of a new class of silicon-related defects. Whereas single photon emission is demonstrated for defect centers of both clusters, we show that emitters from different clusters show different spectroscopic features such as variations of the phonon sideband spectra and different blinking dynamics.
关键词： diamond,single photons,density functional theory calculations,color centers,optical emission,nanodiamond
更新于2025-09-19 17:15:36
-
Atomization of arsenic hydride in a planar dielectric barrier discharge: Behavior of As atoms studied by temporally and spatially resolved optical emission spectrometry
摘要： The excitation mechanism of arsenic atoms in a planar shaped dielectric barrier discharge (DBD) atomizer with sputtered grid shaped electrodes was studied by optical emission spectrometry (OES) with resolution in time and space. Due to the shape of the electrodes, the DBD design provides optical access to the plasma not only in end-on position but also in side-on direction. By means of an iCCD camera with nanosecond time resolution coupled to a monochromator it was shown that the spatial and temporal development of the plasma emission depends on the discharge gas nature (Ar, He). Applying argon, a dense and constricted plasma filament is formed, whereas in helium a much more homogeneous plasma is ignited. The impact of both plasmas on the emission signal of arsenic atoms was studied employing analyte introduction via hydride generation. The excitation of arsenic temporally follows the emission signal of helium or argon and is spread across the whole discharge volume. The basic discharge propagation dynamics showed similarities to previously presented results obtained by OES in a capillary DBD.
关键词： Arsenic,Optical emission spectrometry,Dielectric barrier discharge
更新于2025-09-19 17:15:36
-
Determination of atomic oxygen state densities in a double inductively coupled plasma using optical emission and absorption spectroscopy and probe measurements
摘要： A collisional radiative model for fast estimation and monitoring of atomic oxygen ground and excited state densities and ?uxes in varying Ar:O2 mixtures is developed and applied in double inductively coupled plasma source at a pressure of 5 Pa and incident power of 500 W. The model takes into account measured line intensities of 130.4 nm, 135.6 nm, 557.7 nm, and 777.5 nm, the electron densities and electron energy distribution functions determined using a Langmuir probe and multipole resonance probe as well as the state densities of the ?rst four excited states of argon measured with the branching fraction method and compared to tunable diode laser absorption spectroscopy. The in?uence of cascading and self absorption is included and the validity of the used cross sections and reaction rates is discussed in detail. The determined atomic oxygen state densities are discussed for their plausibility, sources of error, and compared to other measurements. Furthermore, the results of the model are analyzed to identify the application regimes of much simpler models, which could be used more easily for process control, e.g. actinometry.
关键词： absorption spectroscopy,atomic oxygen,probe measurements,collisional radiative model,optical emission spectroscopy
更新于2025-09-19 17:13:59
-
Comparative study of electron temperature in cascaded arc Ar/N <sub/>2</sub> plasma using laser Thomson scattering combined optical emission spectroscopy approach
摘要： The expanding cascaded arc Ar/N2 plasma has been investigated by both the active and passive optical diagnostic technologies. In the investigation, the laser Thomson scattering (LTS) and optical emission spectroscopy (OES) have been adopted to measure electron temperature (Te) and electron excitation temperature (Texc), respectively. The LTS measurements show that a remarkable nonlinear behavior of Te as a function of the N2/(Ar + N2) ratio is found, which is caused by the collective interaction between the superelastic collision and the electron-impact excitation. The superelastic collisions by the highly excited vibrational nitrogen molecules can effectively heat the free electrons, while the electron kinetic energy can be transferred to N2 molecular internal energy via the electron impact with N2 in the ground state. The difference between Texc and Te demonstrates that the cascaded arc Ar/N2 plasma significantly deviates from the local thermodynamic equilibrium. This would be useful for improving our further understanding of nonequilibrium plasma and extending applications of the cascaded arc Ar/N2 plasma.
关键词： cascaded arc Ar/N2 plasma,local thermodynamic equilibrium,laser Thomson scattering,electron temperature,optical emission spectroscopy
更新于2025-09-19 17:13:59
-
Quantitative spatially resolved <i>post-mortem</i> analysis of lithium distribution and transition metal depositions on cycled electrodes <i>via</i> a laser ablation-inductively coupled plasma-optical emission spectrometry method
摘要： Diminishing the loss of performance of lithium ion batteries (LIBs) is a challenge that is yet to be ful?lled. Understanding of deterioration processes and mechanisms (i.e., so-called aging) requires analytically accurate examination of aged cells. Changes in the distribution of lithium or transition metals in the LIB cells can in?uence their cycle and calendar life signi?cantly. As electrochemically treated cells and especially their electrodes do not age homogeneously and the local electrochemistry (e.g. deposition patterns) is strongly dependent on surface properties, bulk analysis is not a satisfactory investigation method. Therefore, a surface sensitive method, namely laser ablation-inductively coupled plasma-optical emission spectrometry (LA-ICP-OES) is presented. LIB cells with lithium metal oxide LiNi1/3Co1/3Mn1/3O2 (NCM111) as cathode material and graphite as anode material are investigated using a 213 nm Nd:YAG laser.
关键词： graphite,aging,laser ablation-inductively coupled plasma-optical emission spectrometry,NCM111,LA-ICP-OES,LIBs,Nd:YAG laser,lithium ion batteries
更新于2025-09-19 17:13:59
-
In-situ optical emission spectroscopy of selective laser melting
摘要： The variances in local processing conditions during Selective Laser Melting (SLM), a powder bed Additive Manufacturing (AM) process, can cause defects that lead to part failure. The nature of SLM permits in-situ monitoring of radiometric signals emitted from the part surface during the process, including optical emission from excited alloying elements. Using Optical Emission Spectroscopy (OES) to measure the spectral content of light emitted gives insight into the chemistry and relative intensities of excited species vaporized during SLM processing. The contribution from investigating the use of in-situ OES to gain information about local processing conditions during SLM is reported in this paper. A spectrometer is split into the SLM system laser beam path to measure visible light emitted from the melt pool and plume during the processing of 304L stainless steel. The in-line configuration allows signal collection regardless of the laser scan location. The spectroscopic information is correlated to the melt pool size and features of SLM samples for various build conditions (i.e., process parameters, build chamber atmosphere type, and pressure).The limitations that exist in OES implementation for certain build chamber conditions are discussed. The results in this paper are initial progress towards the use of OES in SLM part qualification and controls applications.
关键词： Metal additive manufacturing,Optical emission spectroscopy,In-situ monitoring,Powder bed fusion
更新于2025-09-19 17:13:59
-
Time-resolved imaging of atoms and molecules in laser-produced uranium plasmas
摘要： Gas-phase oxidation of uranium (U), plume chemistry, and the corresponding impact on optical emission features of the U plasma are investigated. Plasmas were produced via nanosecond laser ablation of a natural U target in a chamber where U oxidation was controlled by varying the oxygen partial pressure in an argon cover gas. Monochromatic imaging of U atoms and monoxide (UO) molecules was performed using narrow bandpass optical filters. Results reveal the spatio-temporal evolution of atomic and molecular species in the plasma. U oxides are found to be formed further from the target (in comparison to U atoms), where lower temperatures favor molecular recombination. Segregation between the distribution of U atoms and UO species is observed at later times of plasma evolution, and is more apparent at lower oxygen partial pressures. At higher oxygen partial pressures, significant variation in plume morphology is noticed for UO species, which can be attributed to the higher oxide (UxOy) formation further from the target. The monochromatic images of U atoms and UO molecules and corresponding spectral features at various oxygen partial pressures presented here provide unique insight into gas-phase, high-temperature U oxidation and chemistry, with implications for a wide range of nuclear applications, from stand-off detection of radioisotopes to forensics and safeguards.
关键词： optical emission spectroscopy,plasma,uranium,laser ablation,monochromatic imaging
更新于2025-09-16 10:30:52
-
Particle distribution in transient plasmas generated by ns-laser ablation on ternary metallic alloys
摘要： Understanding the fundamental mechanisms behind industrial laser-based technologies represents one the cornerstones of the development and tailoring of new materials. With the thin-film deposition using laser ablation being one of the most important techniques for obtaining complex materials with controllable stoichiometry, there is a high request for both experimental and theoretical studies towards understanding the behavior of multi-component alloys under high-power laser irradiation. Here we investigate the laser ablation process on two ternary metallic alloys (Cu–Mn–Al and Fe–Mn–Si) by means of space-and time-resolved optical emission spectroscopy and fast camera imaging with the focus being on the spatial distribution of each composing element. Information regarding the kinetic and thermal energy of the ejected particles is extracted and discussed in the framework of an inner structuring of the laser-produced plasmas based on a mass and energy distribution. The hypothesis is then verified by implementing a fractal analysis to the multi-component plasmas. The theoretical fractal approach offers results in good agreement with the experimental data gives important insight in the inner dynamics of complex laser-produced plasmas.
关键词： Ternary metallic alloys,Optical emission spectroscopy,Fractal analysis,Fast camera imaging,Laser ablation
更新于2025-09-12 10:27:22
-
Characterization of the fast ionization wave induced by a CO <sub/>2</sub> laser pulse in argon
摘要： Fast ionization wave (FIW), a postbreakdown phenomenon of laser-induced plasma, is observed for a laser intensity of 1011–1013 W/m2 using the CO2 laser pulse in the atmospheric pressure condition. FIW is distinguishable as “overdriven detonation” according to Raizer’s Chapmann-Jouguet detonation theory because FIW is known as the type of laser-absorption wave that has a higher propagation velocity than the laser-supported detonation wave (LSDW). Some reports have described the expansion of FIW using a solid-state laser. Nevertheless, the threshold phenomena between FIW and LSDW are not fundamentally understood. This study used the high-speed visualization and optical emission spectroscopy to investigate the transition of the laser-absorption wave in argon gaseous form. To elucidate the physics of the transition threshold, a 5 J CO2 pulse laser, an Echelle spectrometer, and an intensi?ed CCD camera are used for the quantitative investigation of the plasma temperature and density. Results demonstrate that the FIW front had an electron temperature of 0.7 eV and an electron number density of 2.5 × 1023 m?3. At the FIW–LSDW transition, the electron temperature increased by 1 eV, and the density decreased by 2.2 × 1023 m?3. Besides, the transition threshold and the existence of local-thermodynamic equilibrium were evaluated based on the electron temperature, and the density was obtained from the spectroscopic experiments.
关键词： plasma temperature,optical emission spectroscopy,fast ionization wave,plasma density,CO2 laser,laser-induced plasma
更新于2025-09-12 10:27:22