- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Preparation of hollow yttrium-doped TiO<sub>2</sub> microspheres with enhanced visible-light photocatalytic activity
摘要： Using melamine-formaldehyde polymer microspheres as templates, yttrium-doped TiO2 hollow spheres (Y-TiO2HS) were successfully prepared via a sol-gel method. The as-synthesized samples were characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-Vis diffuse reflectance spectrum, luminescence spectrum, specific surface area (BET) analysis and porosity analysis. The results indicate that Y doping could increase the thermal stability, reduce the band gap and enhance photocatalytic activity of the TiO2. When the Y doping molar ratio was 1.5%, the Y-TiO2HS presented high surface area (62.651 m2 /g) and photocatalytic degradation rate (about 70%). The corresponding BET value and photocatalytic degradation rate of Y-TiO2HS increased by 3 times and 50%, respectively, compared with those of un-doped TiO2HS.
关键词： synthesis,yttrium doping,hollow microspheres,photocatalytic activity,TiO2
更新于2025-09-23 15:22:29
-
Sensitization of TiO <sub/>2</sub> by the symmetric cationic polymethine dye for the photocatalytic reduction of methylene blue
摘要： Using the spectral, electrochemical and energy transformation characteristics of the cationic polymethine dye (D) 2-[(1E)-1,3-butadienyl-]-1-(phenylmethyl)-benindolium borfluoride, it has been found that the dye can be applied as a highly efficient sensitizer of TiO2. An intensity of the initially narrow light adsorption band becomes wider and embraces practically entire visible and near IR zones as a result of application of the dye to the surface of TiO2. Due to this effect, a wider array of light quanta can potentially be involved in the photocatalytic transformations. Some new heterostructures (HS) of the type D/TiO2 have been developed and their photocatalytic activities were determined in the test reaction of reduction of methylene blue by formaldehyde for different dye contents and under various modes of irradiation. The schemes of the energy transformation initiated by the light with different wavelengths are proposed and discussed.
关键词： photocatalytic activity.,heterostructure,Cationic polymethine dye,titania,methylene blue,sensitizing
更新于2025-09-23 15:22:29
-
Photocatalytic Activity of Monosized AuZnO Composite Nanoparticles
摘要： Photocatalytic activity of monosized AuZnO composite nanoparticles with different compositions were synthesized by the one-pot polyol procedure, using the triblock copolymer poly(ethylene glycol)-block-poly(propylene glycol)-blockpoly(ethylene glycol) (PEO-PPO-PEO) as the surfactant. The structure and morphology of the composite nanoparticles were analyzed by X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX), selected area electron diffraction (SAED), a transmission electron microscope (TEM) and high resolution transmission electron microscopy (HRTEM). The characterization showed that the AuZnO composite nanoparticles were spherical, with narrow particle size distribution and high crystallinity. The Fourier transform infrared spectroscopy (FTIR) study con?rms the PEO-PPO-PEO molecules on the surface of the composite nanoparticles. The investigations by ultraviolet-visible light absorbance spectrometer (UV-Vis) and photoluminescence spectrophotometer (PL) demonstrate well the dispersibility and excellent optical performance of the AuZnO composite nanoparticles. Photocatalytic activity and reusability of the AuZnO nanoparticles in UV and visible light regions was evaluated by the photocatalytic degradation of Rhodamine B (RhB). The experimental results show that the AuZnO composite nanoparticles with a suitable amount of Au loading have stability and improved photocatalytic activity. AuZnO composite nanoparticles are effective and stable for the degradation of organic pollutants in aqueous solution.
关键词： one-pot polyol synthesis,photocatalytic activity,AuZnO composite nanoparticles,optical performance
更新于2025-09-23 15:22:29
-
ZnO Tetrapods for Potential Photocatalytic Dye Degradation
摘要： In this study, a facile method was used to prepare ZnO tetrapods for potential dye degradation applications. Field emission scanning electron microscope (FESEM), energy-dispersive X-ray spectroscopy (EDX) and UV-Vis spectroscopy were employed to investigate the morphology, chemical composition, and photocatalytic properties of prepared ZnO tetrapods. A Rhodamine B (RB) dye was used as a model dye to study the photocatalytic activity of the prepared sample. It was shown that RB dye can be efficiently degraded in the presence of ZnO tetrapods under continuous UV-light illumination. Thus, prepared ZnO tetrapods with excellent photocatalytic properties can be potentially used in wastewater treatment.
关键词： tetrapods,ZnO,photocatalytic activity,wastewater treatment
更新于2025-09-23 15:22:29
-
Photocatalytic Degradation of Estriol Using Iron-Doped TiO2 under High and Low UV Irradiation
摘要： Iron-doped TiO2 nanoparticles (Fe-TiO2) were synthesized and photocatalitically investigated under high and low ?uence values of UV radiation. The Fe-TiO2 physical characterization was performed using X-ray Powder Diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area analysis, Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), Diffuse Re?ectance Spectroscopy (DRS), and X-ray Photoelectron Spectroscopy (XPS). The XPS evidenced that the ferric ion (Fe3+) was in the TiO2 lattice and unintentionally added co-dopants were also present because of the precursors of the synthetic method. The Fe3+ concentration played a key role in the photocatalytic generation of hydroxyl radicals (?OH) and estriol (E3) degradation. Fe-TiO2 accomplished E3 degradation, and it was found that the catalyst with 0.3 at.% content of Fe (0.3 Fe-TiO2) enhanced the photocatalytic activity under low UV irradiation compared with TiO2 without intentionally added Fe (zero-iron TiO2) and Aeroxide? TiO2 P25. Furthermore, the enhanced photocatalytic activity of 0.3 Fe-TiO2 under low UV irradiation may have applications when radiation intensity must be controlled, as in medical applications, or when strong UV absorbing species are present in water.
关键词： hydroxyl radical,estriol,iron-doped TiO2,photocatalytic activity,low UV irradiation
更新于2025-09-23 15:22:29
-
Enhanced Photocatalytic Activity of Titania by Co-Doping with Mo and W
摘要： Various W and Mo co-doped titanium dioxide (TiO2) materials were obtained through the EISA (Evaporation-Induced Self-Assembly) method and then tested as photocatalysts in the degradation of 4-chlorophenol. The synthesized materials were characterized by thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), Raman spectroscopy (RS), N2 physisorption, UV-vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The results showed that the W-Mo-TiO2 catalysts have a high surface area of about 191 m2/g, and the presence of an anatase crystalline phase. The co-doped materials exhibited smaller crystallite sizes than those with one dopant, since the crystallinity is inhibited by the presence of both species. In addition, tungsten and molybdenum dopants are distributed and are incorporated into the anatase structure of TiO2, due to changes in red parameters and lattice expansion. Under our experimental conditions, the co-doped TiO2 catalyst presented 46% more 4-chlorophenol degradation than Degussa P25. The incorporation of two dopant cations in titania improved its photocatalytic performance, which was attributed to a cooperative effect by decreasing the recombination of photogenerated charges, high radiation absorption capacity, high surface areas, and low crystallinity. When TiO2 is co-doped with the same amount of both cations (1 wt.%), the highest degradation and mineralization (97% and 74%, respectively) is achieved. Quinones were the main intermediates in the 4-chlorophenol oxidation by W-Mo-TiO2 and 1,2,4-benzenetriol was incompletely degraded.
关键词： W-Mo dopants,photocatalytic activity,nanoparticles,titanium dioxide
更新于2025-09-23 15:22:29
-
Facile Synthesis and Characterization of CoS2–SiO2/Chitosan: The Photocatalysis in Real Samples, and Antimicrobial Evaluation
摘要： In the present work, The SiO2, and CoS2–SiO2 nanomaterials and incorporated on chitosan was developed as photocatalyst for photocatalytic degradation of toxic compound such as ethidium bromide as a hazard mutagenic pollutant. The SiO2, and CoS2–SiO2 nanomaterials were prepared using the sol–gel/sonochemical method. Therefore, the nano photocatalyst were characterized by various analytical devices such as scanning electron microscopy (SEM), X-ray diffraction and photoelectron (XRD and XPS) analysis, energy dispersive X-ray spectrometer (EDS), UV–Vis absorption spectroscopy and dynamic light scattering, in order to attain the structural properties. The average crystallite size values of SiO2, CoS2–SiO2, and CoS2–SiO2/Chitosan nanocomposites are 0.63, 40.28, and 69.75 nm, respectively. The band-gap values was obtained 8.9–2.7 eV for SiO2, CoS2–SiO2, and CoS2–SiO2/Chitosan nanocomposites, respectively. The photocatalytic performances of the three prepared nano-photocatalyst were examined by UV-light with help the photo-degradation of ethidium bromide. The CoS2–SiO2/Chitosan nanocomposites photocatalyst shows the high amount of photocatalytic degradation (96.00%) in comparison to SiO2, and CoS2–SiO2 nanomaterials. The results demonstrated that the all prepared nano-photocatalyst under UV irradiation was in pH 5 at 40 min. The antifungal and antibacterial of the SiO2, CoS2–SiO2, and CoS2–SiO2/Chitosan were examined. The CoS2–SiO2/Chitosan (high 11.00 mm inhibition zone) has appropriate antimicrobial activity compared with pure SiO2.
关键词： Antibacterial,Chitosan,CoS2,SiO2,Photocatalytic activity
更新于2025-09-23 15:22:29
-
Morphological expedient flower like nanostructures WO3–TiO2 nanocomposite material and its multi applications
摘要： The prepare WO3 -TiO2 nanocomposite material has been successfully achieved precipitation route and sonication technique. The experimental results expose that 400 °C of WO3–TiO2 nanocomposite material exhibited the higher photoatalytic activity for the degradation of azo dye Acid block 1(AB 1) under UV-Light. This nanocomposite material was characterized by High-resolution scanning electron microscopy (HR-SEM) with elementary dispersive X-ray (EDX), High-resolution transmission electron microscopy (HR-TEM), XRD analysis, photoluminescence spectroscopy (PL), UV–Vis DRS and BET. The HR-SEM images reveal that most nanoflower are linked together by an edge-to-flat-surface combination. EDX studies that Ti, O and W are in higher mediation. The HR-TEM images indicate nanorod structure. As a reaction of this nanoparticle was found to be stable and reusable. This nanoparticle was antibacterial activity and electrochemical activity showed highest activity by WO3–TiO2 compared that of TiO2 nanocomposite material was reported.
关键词： UV-Light,HR-TEM,Antibacterial activity,Nanoflower,Photocatalytic activity,Electrochemical activity
更新于2025-09-23 15:21:21
-
Visible Light Driven Mesoporous Mn and S Co-doped TiO2 Nano material: characterization and Applications in Photocatalytic Degradation of Indigocarmine dye and Antibacterial Activity
摘要： The present study explored the Photocatalytic & antibacterial activity of Mesoporous Mn and S co-doped TiO2 nano material synthesized by sol-gel method. As prepared samples were characterized by X-ray diffraction (XRD), X-ray photo electron spectroscopy(XPS), Scanning electron microscopy (SEM), Energy dispersive X-ray Spectroscopy(EDX), Fourier transform infrared spectroscopy(FT-IR), UV-Visible Diffused Reflectance Spectroscopy(UV-Vis-DRS),Transmission electron Microscopy(TEM), Brunauer-Emmett-Teller (BET) and Photoluminescence (PL).The Characterization results revealed that all the co-doped and undoped samples shows anatase phase. The Frequency shift of Ti-O-Ti in the catalyst samples was observed in FT-IR due to substitutional doping of Mn and S by replacing Ti and O, Further the catalyst shows smooth spherically shaped small particle size (7.6 nm) with high surface area (155.87 m2/g) and having less band gap energy (2.58 eV). The most reactive ?OH are produced during the progress of reaction was determined by using Photo luminescence (PL) technique. The photocatalytic efficiency and antibacterial activity was evaluated by degradation of Indigo carmine(IC), Bacillus coagulans and klebsiella pneumonia respectively. The complete degradation of IC was achieved at optimum reaction parameters such as 0.150g of the catalyst dosage, solution pH=4 and initial dye concentration 20ppm with the catalyst of 1.0Wt% of Mn-0.25Wt% of S co-doped Titania with in 90 min. The zone of inhibition bacterial growth was observed (24mm and 23mm) compared to control value (Chloramphenicol) 25mm and 24mm.
关键词： antibacterial activity,Mn-S,TiO2,Indigo carmine,Photocatalytic activity,Sol-gel method
更新于2025-09-23 15:21:21
-
Theory-Driven Heterojunction Photocatalyst Design with Continuously Adjustable Band Gap Materials
摘要： The utilization efficiency of hot carriers in photocatalyst is limited at present by their fast recombination. Heterojunction interface would reduce the recombination rate by effectively facilitating spatial separation of the hot electron and hole. Here, we establish a heterojunction photocatalyst design principle by using continuously adjustable band gap materials. This is demonstrated using first-principles calculations, and is subsequently validated by direct measurements of photocatalytic activity of ZnxCd1-xS-reduced graphene oxide (RGO) heterojunction as a proof-of-concept photocatalyst. Tuning the Zn/Cd ratio and/or the reduction degree of RGO can result into three types of heterojunction, and different conduction and valence band offsets by varying their band gap and positions of band edges. The modulation of efficient electron-hole separation at the interface is manifested by the consistency of calculated and experimental optical absorbance, and enhanced photocatalytical activity of ZnxCd1-xS-RGO heterojunction. This results can also rationalize the available experimental results of RGO-based composites. This design principle is broadly applicable to the development of other heterojunction materials ranging from photocatalysts and solar cells to functional electronic devices through interfacial band alignment engineering.
关键词： band gap,photocatalytic activity,RGO,heterojunction,ZnxCd1-xS,photocatalyst,first-principles calculations
更新于2025-09-23 15:21:21