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Titanium Dioxide Hole-Blocking Layer in Ultra-Thin-Film Crystalline Silicon Solar Cells
摘要： One of the remaining obstacles to achieving the theoretical ef?ciency limit of crystalline silicon (c-Si) solar cells is high interface recombination loss for minority carriers at the Ohmic contacts. The contact recombination loss of the ultra-thin-?lm c-Si solar cells is more severe than that of the state-of-art thick cells due to the smaller volume and higher minority carrier concentration. This paper presents a design of an electron passing (Ohmic) contact for n-type Si that is hole-blocking with signi?cantly reduced hole recombination. By depositing a thin titanium dioxide (TiO2) layer, we form a metal-insulator-semiconductor (MIS) contact for a 2 μm-thick Si cell to achieve an open circuit voltage (Voc) of 645 mV, which is 10 mV higher than that of an ultra-thin cell with a traditional metal contact. This TiO2 MIS contact constitutes a step towards high-ef?ciency ultra-thin-?lm c-Si solar cells.
关键词： titanium dioxide,Silicon photovoltaic,ultra-thin-?lm,selective contact
更新于2025-09-11 14:15:04
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Development of Germanium-Based Wafer-Bonded Four-Junction Solar Cells
摘要： Multijunction solar cells with four junctions are expected to be the next-generation technology for both space and concentrator photovoltaic applications. Most commercial triple-junction solar cells are today grown on germanium, which also forms the bottom subcell. Extending this concept to four junctions with an additional ～1-eV subcell was proven to be challenging. We investigate a new cell concept, which uses direct wafer bonding to combine a metamorphic GaInAs/Ge bottom tandem solar cell with a GaInP/AlGaAs top tandem on GaAs resulting in a monolithic four-junction cell on germanium. This article summarizes results of the cell developments, which have been resulting in a four-junction concentrator cell with 42% ef?ciency. We implemented a new passivated Ge backside technology to enhance the current generation in the Ge junction, and we propose realistic steps to realize solar cells with 45% ef?ciency using this cell architecture.
关键词： photovoltaics,concentrator,photovoltaic cells,germanium,III-V semiconductor materials
更新于2025-09-11 14:15:04
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Reflective Back Contacts for Ultrathin Cu(In,Ga)Se2-Based Solar Cells
摘要： We report on the development of highly reflective back contacts (RBCs) made of multilayer stacks for ultrathin CIGS solar cells. Two architectures are compared: they are made of a silver mirror coated either with a single layer of In2O3:Sn (ITO) or with a bilayer of ZnO:Al/ITO. Due to the improvement of CIGS rear reflectance, both back contacts result in a significant external quantum efficiency enhancement, in agreement with optical simulations. However, solar cells fabricated with Ag/ITO back contacts exhibit a strong shunting behavior. The key role of the ZnO:Al layer to control the morphology of the top ITO layer and to avoid silver diffusion through the back contact is highlighted. For a 500-nm-thick CIGS layer, this optimized RBC leads to a best cell with a short-circuit current of 27.8 mA/cm2 (+2.2 mA/cm2 as compared to a Mo back contact) and a 12.2%-efficiency (+2.5% absolute).
关键词： photovoltaic cells,reflective back contacts,ultrathin Cu(In,Ga)Se2,In2O3:Sn
更新于2025-09-11 14:15:04
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[IEEE 2019 IEEE Milan PowerTech - Milan, Italy (2019.6.23-2019.6.27)] 2019 IEEE Milan PowerTech - Optimal Scheduling of Generators and BESS using Forecasting in Power System with Extremely Large Photovoltaic Generation
摘要： Large scale integration of renewable energy sources (RES) can cause supply demand uncertainty. In Japanese power systems the photovoltaic (PV) generation is growing rapidly. PV forecasting with energy storage systems can be used in Unit Commitment (UC) to reduce these imbalances. In this study Battery Energy Storage systems (BESS) and day-ahead PV forecasting with prediction intervals have been used to examine the imbalances. The day-ahead UC of thermal generators and day-ahead optimal BESS charging and discharging is calculated with different BESS inverter capacities and BESS energy capacities. Then the power shortfall and surplus of PV power in the target day are calculated. The simulation is run for 3 months from April to June 2010 for Kanto area power system of Japan.
关键词： Photovoltaic (PV) forecasting,Unit Commitment (UC),Optimal Power dispatch,Battery Energy Storage Systems (BESS),Prediction Intervals,Mixed Integer Linear Programming (MILP)
更新于2025-09-11 14:15:04
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Study on Shunt Active Power Filter Control Strategies of Three-phase Grid-connected Photovoltaic Systems
摘要： This paper deals with the improvement of the energy quality using shunt active power filter. The three-phase grid-connected photovoltaic generator consists in solar panels, a three-phase voltage inverter connected to the grid and a nonlinear load constituted by a diode rectifier bridge supplying a resistive load in series with an inductor. In so doing, three main challenges arise from the application context. First, the harmonic currents and the reactive power must be compensated. The second challenge is the injection of active solar energy into the grid. Third, Maximum Power Point Tracking (MPPT) must be found. This paper proposes a method addressing those challenges. For the first and the second one, direct current and power controls is used. For the third challenge, an algorithm is proposed which take in account the electrical variables and the variation of the solar irradiation. Simulation results of the proposed method are shown. The method is illustrated with two different strategies: Hysteresis Control and Direct Power Control (DPC) for a variable load. Obtained results are presented and compared in this paper to confirm the robustness and the superiority of DPC strategy compared to Hysteresis Control strategy. In the same context, the simulation carried out in this article shows promising results with THD approximates 1.33 %.
关键词： photovoltaic system,MPPT,Direct Power Control,energy quality,Hysteresis Control
更新于2025-09-11 14:15:04
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Effective minority carrier lifetime as an indicator for potential-induced degradation in p-type single-crystalline silicon photovoltaic modules
摘要： In this paper, we report the effective minority carrier lifetime (τeff) in fresh and potential-induced degradation (PID) acceleration tested p-type single-crystalline Si modules. τeff in different regions of solar cells was measured using the microwave photoconductance decay (μPCD) method. Electroluminescence (EL), lock-in-thermography, and dark and light current–voltage (I–V ) measurements were carried out as a complementary analysis of μPCD. In addition, τeff in every stage of Si solar cell fabrication (wafer to solar cell) was measured to investigate the change of carrier dynamics. From the obtained results, a great decrease in τeff was observed in the PID-affected regions, confirming the excess non-radiative recombination centers in that region, suggesting that τeff from the μ-PCD method can be an effective indicator to judge whether PID phenomenon has occurred.
关键词： microwave photoconductance decay,p-type single-crystalline silicon,potential-induced degradation,effective minority carrier lifetime,photovoltaic modules
更新于2025-09-11 14:15:04
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Universal explanation for degradation by charge accumulation in crystalline Si photovoltaic modules with application of high voltage
摘要： It was experimentally found that surface recombination due to charge accumulation, called polarization-type potential-induced degradation (PID), occurs by applying high voltage in n-type crystalline Si photovoltaic (PV) modules. By contrast, polarization-type PID has not been observed yet in p-type crystalline Si PV modules. We investigated the effect of differences in anti-reflection coating (ARC) and the conduction type of the substrate used as a base for PV cells on PID. PID was examined for PV modules using p-type and n-type crystalline Si PV cells with a SiNx or SiNx/SiO2 stacked ARC layer. The results indicate that PID owing to charge accumulation occurs even for p-type crystalline Si PV modules by applying high positive voltage. Furthermore, we found that polarization-type PID due to charge accumulation in ARC, leading to surface recombination, is due not to the conduction type of the substrate but to the ARC structure.
关键词： potential-induced degradation,anti-reflection coating,surface recombination,charge accumulation,photovoltaic modules
更新于2025-09-11 14:15:04
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An Electrode Design Rule for Organic Photovoltaics Elucidated Using a Low Surface Area Electrode
摘要： It is widely considered that charge carrier extraction in bulk-heterojunction organic photovoltaics (BHJ OPVs) is most efficient when the area of contact between the semiconductor layers and the electrodes is maximized and the electrodes are electrically homogeneous. Herein, it is shown that ≈99% of the electrode surface can in fact be insulating without degrading the efficiency of charge carrier extraction, provided the spacing of the conducting areas is less than or equal to twice the optimal thickness of the BHJ layer. This striking result is demonstrated for BHJ OPVs with both conventional and inverted device architectures using two different types of BHJ OPVs, namely, PCDTBT:PC70BM and the ternary blend PBDB-T:ITIC-m:PC70BM. This finding opens the door to the use of a large pallet of materials for optical spacers and charge transport layers, based on a low density of conducting particles embedded in a wide bandgap insulating matrix.
关键词： nanoparticle electrode,organic photovoltaic,gold nanoparticle,transparent electrode,polymer solar cell,organic solar cell
更新于2025-09-11 14:15:04
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1 cm <sup>2</sup> Organic Photovoltaic Cells for Indoor Application with over 20% Efficiency
摘要： Organic photovoltaic (OPV) technologies have the advantages of fabricating larger-area and light-weight solar panels on flexible substrates by low-cost roll-to-toll production. Recently, OPV cells have achieved many significant advances with power conversion efficiency (PCE) increasing rapidly. However, large-scale solar farms using OPV modules still face great challenges, such as device stability. Herein, the applications of OPV cells in indoor light environments are studied. Via optimizing the active layers to have a good match with the indoor light source, 1 cm2 OPV cells are fabricated and a top PCE of 22% under 1000 lux light-emitting diode (2700 K) illumination is demonstrated. In this work, the light intensities are measured carefully. Incorporated with the external quantum efficiency and photon flux spectrum, the integral current densities of the cells are calculated to confirm the reliability of the photovoltaic measurement. In addition, the devices show much better stability under continuous indoor light illumination. The results suggest that designing wide-bandgap active materials to meet the requirements for the indoor OPV cells has a great potential in achieving higher photovoltaic performance.
关键词： indoor application,power conversion efficiency,organic photovoltaic cells,photostability
更新于2025-09-11 14:15:04
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1D Pyrrolidinium Lead Iodide for Efficient and Stable Perovskite Solar Cells
摘要： Due to the superior environmental stability, the utilization of low-dimensional perovskites in organometal halide solar cells (OMHSCs) has been on the sharp increase. Herein, we report a method to in situ form one-dimensional pyrrolidinium lead iodide (1D PyPbI3) atop the photoactive three-dimensional methylammonium lead iodide (3D MAPbI3) using pyrrolidine post-treatment. As compared to the 3D MAPbI3, the 1D PyPbI3 has a wider bandgap and is more environmentally stable, which serves as a tunnelling contact to mitigate charge carrier recombination and robust barrier against environmental degradation when incorporated into OMHSCs. Accordingly, power conversion efficiencies of the resulting MAPbI3 devices were enhanced from an average of 14.86 ± 0.65% to 15.9 ± 0.58% while shelf-life stability was significantly prolonged.
关键词： perovskite solar cell,one-dimensional perovskite,environmental stability,pyrrolidine,photovoltaic performance,pyrrolidinium lead iodide,charge recombination
更新于2025-09-11 14:15:04