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Size and shape control of monoclinic vanadium dioxide thermochromic particles for smart window applications
摘要： Monoclinic vanadium dioxide (VO2 (M)) was synthesized by the thermolysis of vanadyl ethylene glycolate, which was obtained easily by the precipitation of a vanadium precursor in ethylene glycol solution under atmospheric conditions. The particle size and shape were easily controlled by altering the molar concentration of the vanadium precursor. Thereafter, VO2 (M) composite films were prepared by mixing with poly(vinylpyrrolidone). A high concentration of the vanadium precursor produced small spherical nanoparticles ≈30 nm in size, while lower concentrations afforded large rod-like particles. The composite films fabricated with the VO2 (M) nanoparticles exhibited high luminous transmittance (Tlum = 79%) and IR modulation ability (ΔTIR = 5.6%). This work demonstrates that these VO2 (M) composite films show promise for application in smart windows.
关键词： solar modulation ability,Energy efficiency,size and shape tuning,high luminous transmittance,VO2 (M) particle,thermochromic coating
更新于2025-09-23 15:21:21
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Optimized thermochromic properties of VO2/CoFe2O4 nanocomposite films via band gap engineering
摘要： VO2/CoFe2O4 nanoparticle composites were synthesized by hydrothermal method combined with annealing treatment. The nanocomposites consist of quasi-spherical nanoparticles with an average size of about 70 nm. The thermochromic properties of the nanocomposite films can be modulated by changing film thickness and the content of CoFe2O4 in the nanocomposites. The band gap of the VO2/CoFe2O4 nanocomposites increases with increasing CoFe2O4 additive content. The introduction of CoFe2O4 into VO2 matrix can not only lower the phase transition temperature, but also optimize the luminous transmittance and solar modulation ability of the VO2/CoFe2O4 nanocomposites as well. Our findings demonstrate a promising avenue in constructing VO2-based smart films with excellent thermochromic performance.
关键词： Solar modulation ability,VO2/CoFe2O4 nanocomposite,Luminous transmittance,Phase transition temperature
更新于2025-09-23 15:21:21
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Double-layer VO2 thin film patterned by SiO2 spheres with improved thermochromic properties for smart windows
摘要： The double-layer vanadium dioxide (VO2) thin film patterned by SiO2 spheres has been fabricated to enhance luminous transmittance (Tlum) without severely expense of solar modulation ability (ΔTsol) for the thermochromic smart windows. The first layer of vanadium thin film was deposited on the substrate with self-assembly SiO2 spheres and then the SiO2 spheres was removed by ultrasonic oscillation. The orderly perforated vanadium thin film with regular pores formed. Afterwards, the second layer of vanadium thin film was deposited on the perforated vanadium thin film. The semi-perforated double layer of vanadium thin film formed and was rapid thermal annealed forming the semi-perforated double VO2 thin films. Compared with continuous VO2 thin film(Tlum, 8.8%, ΔTsol, 5.9%), the semi-perforated double VO2 layer possesses orderly-patterned crater, which facilitate Tlum (42.6%) and only slightly attenuate the ΔTsol (5.5%). The phase transition temperatures for continuous VO2 thin film and the optimized semi-perforated VO2 double layer thin film were 58 °C and 52 °C, respectively, far below 68 °C of bulky VO2. This structure should be very meaningful for the real application of VO2-based smart window in the future.
关键词： luminous transmittance,thermochromic,solar modulation ability,VO2,smart windows
更新于2025-09-04 15:30:14