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- 2018
- Battery energy storage systems
- techno-economic modeling
- photovoltaics
- net-metering
- solar power
- Electrical Engineering and Automation
- Aristotle University of Thessaloniki
- Western Macedonia University of Applied Sciences
- Technological Educational Institute of Thessaly
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Enhanced energy storage performance in Sn doped Sr0.6(Na0.5Bi0.5)0.4TiO3 lead-free relaxor ferroelectric ceramics
摘要： SnO2 doped Sr0.6(Na0.5Bi0.5)0.4TiO3 (NBT-ST) ceramics were prepared by a conventional solid-state reaction method. Their phase structures, microstructures and electrical properties were characterized in details. It is found that SnO2 doping could increase the lattice parameters, density and average grain size. A suitable amount of SnO2 can improve dielectric properties, and affect the relaxor behavior of the NBT-ST matrix, thereby it can effectively reduce the energy loss and optimize the energy storage performance. Furthermore, the energy storage properties are improved with SnO2 doping. Especially, the 1 at. % SnO2 doped NBT-ST achieves a high recoverable energy density of 2.35 J/cm3, which is mainly attributed to large maximum polarization of 43.2 μC/cm2, small remnant polarization of 5.83 μC/cm2 and high breakdown strength of 180 kV/cm. Also, relatively good temperature stability for dielectric performance and excellent fatigue resistance are observed in this composition. These properties are attractive for lead-free energy storage applications.
关键词： SnO2,Lead-free,Dielectric,Energy storage,NBT-ST
更新于2025-11-14 17:28:48
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Enhanced breakdown strength and energy storage density in a new BiFeO3-based ternary lead-free relaxor ferroelectric ceramic
摘要： A new ternary lead-free relaxor ferroelectric ceramic of (0.67-x)BiFeO3-0.33(Ba0.8Sr0.2)TiO3-xLa(Mg2/3Nb1/3)O3+y wt.% MnO2+z wt.% BaCu(B2O5) (BF-BST-xLMN+y wt.% MnO2+z wt.% BCB) was prepared by a solid-state reaction method. The substitution of LMN for BF was believed to induce a typical dielectric relaxation behavior owing to the increased random fields. After co-doping MnO2 and BCB, a significant decrease in the conductivity and grain size was simultaneously realized, resulting in obviously enhanced dielectric breakdown strength and energy-storage performances at room temperature. A high recoverable energy storage density W~3.38 J/cm3 and an acceptable energy storage efficiency η~59% were achieved in the composition with x=0.06, y=0.1 and z=2 under a measuring electric field of 23 kV/mm. In addition, the energy-storage performance is quite stable against both frequency (0.1 Hz-100 Hz) and temperature (30-170 oC), suggesting that BF-BST-xLMN+y wt.% MnO2+z wt.% BCB lead-free relaxor ferroelectric ceramics might be a promising dielectric material for high-power pulsed capacitors.
关键词： Lead-free ceramics,Relaxor ferroelectrics,Energy storage,BiFeO3,BDS
更新于2025-11-14 17:28:48
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Structure-design strategy of 0–3 type (Bi0.32Sr0.42Na0.20)TiO3/MgO composite to boost energy storage density, efficiency and charge-discharge performance
摘要： A novel 0–3 type (Bi0.32Sr0.42Na0.20)TiO3/MgO composite is investigated in this work, which possesses a high stored energy storage density ws?2.50 J/cm3, recoverable energy storage density WR?2.09 J/cm3 with high efficiency η?84% under low electric field (20 kV/mm). The excellent performance is owning to the increase of breakdown strength (BDS) value and the intrinsic mechanism for enhanced BDS value by MgO incorporation is disclosed by numerical simulations (COMSOL). Moreover, the studied composite exhibits excellent charge-discharge performance, the current density (CD) and power density (PD) are 1671 A/cm2 and 150 MW/cm3, respectively, which are much superior to that of other ceramics. Besides, most of the stored energy is discharged within ?0.15 μs via charge-discharge tests. This work not only provides a novel technique to designing bismuth-based ceramic capacitors with simultaneously high Wd, η and excellent charge-discharge performance, but also deepens the understandings of the role for the metallic oxide in the composite.
关键词： 0–3 Composite,Energy storage,Numerical simulations,Charge-discharge,Lead-free
更新于2025-11-14 17:28:48
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(Bi0.51 Na0.47)TiO3 based lead free ceramics with high energy density and efficiency
摘要： Dielectric ceramics with high energy storage density and energy efficiency play an important role in high power energy storage applications. In this work, lead free relaxor ferroelectric ceramics in (1-x)Bi0.51Na0.47TiO3-xBa(Zr0.3Ti0.7)O3 (BNT-BZT100x: x=0.20, 0.30, 0.40 and 0.50) system are fabricated by conventional solid-state sintering method. The BNT-BZT100x ceramics are sintered dense with minimal pores, exhibiting pseudocubic symmetry and strong relaxor characteristic. A very high energy storage density of 3.1 J/cm3 and high energy efficiency of 91% are simultaneously achieved in BNT-BZT40 ceramic with 0.1mm in thickness, at the applied electric field of 280 kV/cm. The temperature stability of the energy density is studied over temperature range of 20-160°C, showing minimal variation below 1.5%, together with the excellent cycling reliability (the variations of both energy density and efficiency are below 3% up to 106 cycles), making BNT-BZT40 ceramic promising as a candidate for high-temperature dielectric and energy storage applications.
关键词： relaxor characteristic,lead free ceramic,energy storage
更新于2025-11-14 17:28:48
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Photo-rechargeable Organic-Inorganic Dye Integrated Polymeric Power Cell with Superior Performances and Durability
摘要： In present work, we propose a simple and unique approach to design a light-weight, low-cost, self-charging power cell with considerable capacity to generate and store photo-charges named as self-charged photo-power cell (SCPPC). Initially, highly electroactive sodium dodecyl sulphate (SDS) incorporated poly (vinylidene fluoride) (PVDF) composite thin films with a large dielectric constant ~ 525 are synthesized via simplistic solution casting process. Then as-prepared high dielectric SDS/PVDF thin film has been used as a charge storage medium in combination with a inorganic-organic dye film i.e. ZnO NPs-Eosin Y- polyvinyl pyrrolidone film as photoelectrons generator in our SCPPC. An open circuit voltage ~ 1.2 V is attained after charging SCPPC under illumination light with intensity ~110 mW /cm2 and then discharge fully with a constant current density ~ 4.5 mA/cm2. Specific areal capacitance ~ 450 F/m2 is obtained with a large energy and power density of ~ 90 mWh/m2 and 54 W/m2. The improved overall efficiency ~3.78 % along with 89 % storage efficiency leads to promising application possibilities of our rechargeable photo-power cell. The recyclability i.e. recharge-ability and storage durability of the photo-power cell are also checked for 35 days without no such reduction in voltage generation and storage. Also multi-coloured light emitting diodes have been lighten up using the photo-power cell as power source.
关键词： storage,PVDF,dielectric,self-charging,SDS
更新于2025-11-14 17:28:48
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Phase-transition induced giant negative electrocaloric effect in a lead-free relaxor ferroelectric thin film
摘要： Ferroelectric/antiferroelectric thin/thick films with large positive or negative electrocaloric (EC) effects could be very useful in designing commercial refrigeration devices. Here, a giant negative EC effect (maximum ΔT ≈ ?42.5 K with ΔS ≈ ?29.3 J K?1 kg?1) comparable to the best positive EC effects reported so far is demonstrated for 0.5(Ba0.8Ca0.2)TiO3–0.5Bi(Mg0.5Ti0.5)O3 (BCT–BMT) lead-free relaxor ferroelectric thin films prepared on Pt(111)/TiOx/SiO2/Si substrates using a sol–gel method. An electric-field induced structural phase transition (nanoscale tetragonal and orthorhombic to rhombohedral) along the out-of-plane [111] direction plays a very key role in developing the giant negative EC effect. This breakthrough will pave the way for practical applications of next-generation refrigeration devices with high cooling efficiency in one cycle by ingeniously utilizing and combining both the giant negative and positive EC effects. Moreover, a large energy density of 51.7 J cm?3 with a high power density of 1.15 × 1010 W kg?1 at room temperature is also achieved in the thin film, indicating that it is also an attractive multifunctional material for energy storage.
关键词： lead-free,energy storage,electrocaloric effect,phase transition,thin film,relaxor ferroelectric
更新于2025-11-14 17:28:48
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A microfluidic all-vanadium photoelectrochemical cell with the N-doped TiO2 photoanode for enhancing the solar energy storage
摘要： In this work, the nitrogen-doped TiO2 photocatalyst is synthesized and applied in a microfluidic all-vanadium photoelectrochemical cell for enhancing the solar energy storage. The use of the nitrogen-doped TiO2 photoanode and the minimization design can ensure the visible-light response, increased specific surface area, vigorous pore structure and enhanced photon and mass transport as well as more uniform light distribution. Various characterizations are performed to evaluate the developed photocatalyst and microfluidic all-vanadium photoelectrochemical cell. The results confirm that the developed nitrogen-doped TiO2 photoanode can provide both the extended absorption spectrum and the small anatase crystal size as well as the obviously enlarged specific surface area with plentiful pore structure. Because of these merits, the microfluidic all-vanadium photoelectrochemical cell with the nitrogen-doped TiO2 photoanode yield the average photocurrent density of 0.103 mA/cm2 during the long-term operation, which is much higher than those with the un-doped TiO2 photoanode (0.086 mA/cm2) and commercial P25 TiO2 photoanode (0.073 mA/cm2), presenting 19.8% and 41% improvements, respectively. The results demonstrate not only the promotion of the vanadium reversible redox pairs conversion but also the inherently excellent stability by the nitrogen-doped TiO2 photoanode.
关键词： Photoanode,N-doped TiO2 photocatalyst,Conversion rate,Microfluidic all-vanadium photoelectrochemical cell,Solar energy storage
更新于2025-11-14 17:03:37
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Excellent catalysis of TiO2 nanosheets with high-surface-energy {001} facets on hydrogen storage properties of MgH2
摘要： Transition metal compound is one of the highly efficient catalysts in improving the reaction kinetics of hydrogen storage materials. Among all the transition metal, titanium and its compounds show great catalytic effect on magnesium hydride. In this paper, TiO2 nanosheets with exposed {001} facets were synthesized and doped into MgH2 for the first time. The TiO2 nanosheets (NS) doped MgH2 shows superior kinetic performance and lowest desorption temperature. The onset temperature of MgH2 + 5 wt% TiO2 NS to release hydrogen is 180.5 °C and the corresponding peak temperature is 220.4 °C, which are greatly lower than those of pure MgH2 and also distinctly lower than those of MgH2 + 5 wt% TiO2 nanoparticles (NP). For isothermal dehydrogenation analysis, the MgH2 + 5 wt% TiO2 NS can release 6.0 wt% hydrogen within 3.2 min at 260 °C and desorb 5.8 wt % hydrogen within 6 min at 240 °C. It is worth noting that the MgH2 + 5 wt% TiO2 NS can even release 1.2 wt% hydrogen at a temperature as low as 180 °C within 300 min. The hydrogenation kinetics of MgH2 + 5 wt% TiO2 NS is also greatly improved, which could absorb hydrogen within only a few seconds at the mild temperature. It can uptake 3.3 wt% hydrogen at 50 °C and 5.4 wt% at 100 °C within 10 s. It is demonstrated that the tremendous enhancement in reaction kinetics of MgH2 can be ascribed to the nanometer size and highly active {001} facets of anatase TiO2. The higher average surface energy can significantly reduce the hydrogen desorption activation energy of MgH2 to 67.6 kJ/mol, thus easily improves the hydrogen desorption properties.
关键词： Magnesium hydride,Hydrogen storage,Catalytic effects,crystal facets,TiO2
更新于2025-11-14 17:03:37
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Analogous Anti-Ferroelectricity in Y2O3-Coated (Pb0.92Sr0.05La0.02)(Zr0.7Sn0.25Ti0.05)O3 Ceramics and Their Energy-Storage Performance
摘要： Antiferroelectric analogous (Pb0.92Sr0.05La0.02)(Zr0.7Sn0.25Ti0.05)O3 (PSLZSnT) ceramics were prepared by the solid-state sintering method by introducing a Y2O3-coating via the self-combustion method. The synthesized Y2O3-doped PSLZSnT ceramics present pseudo-cubic structure and rather uniform microstructural morphology accompanied by relatively small grain size. Excellent energy-storage performance is obtained in the Y2O3-doped PSLZSnT ceramics, in which the value of the energy-storage density presents a linearly increasing trend within the electric field measurement range. Such excellent performance is considered as relating to the rather pure perovskite structure, high relative density accompanied by relatively small grain size, and the antiferroelectric-like polarization-electric field behavior.
关键词： oxide doping,self-combustion method,energy-storage density,perovskite structure,PSLZSnT antiferroelectric-like ceramics
更新于2025-09-23 15:23:52
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Battery lifetime enhancement via smart hybrid energy storage plug-in module in standalone photovoltaic power system
摘要： Standalone photovoltaic power system is one of the feasible solutions in rural electri?cation. However, due to the intermittent nature of solar energy and signi?cant demand variations due to small load size, energy storage devices are needed to ensure power quality and reliability. Lead-acid battery bank has been widely used in such systems to act as the intermediate bu?er to compensate the power mismatch between generation and demand, despite the poor lifetime characteristics and relatively short service life compared to other energy storage devices. Most charge controllers only provide basic battery charging functionality and prevent the battery bank from overcharging and deep-discharging. While other notable aging factors such as frequent charge-discharge transition, high C-rate and surge power are often neglected. This paper presents a smart hybrid energy storage plug-in module that aims to enhance the service life of Lead-acid battery in standalone photovoltaic-battery power systems by mitigating life-limiting factors such as current ?uctuations and surge current. This module is designed as a plug-in module that can be adopted directly in existing infrastructure in installed standalone PV-battery power system. The e?ectiveness of the proposed plug-in module in mitigating battery stresses is simulated in Matlab Simulink with actual solar irradiance data and estimated load pro?le for a rural community in Sarawak Malaysia. The simulation results are validated experimentally with the scaled-down photovoltaic-battery power system. The e?ectiveness in mitigating battery stress is quantitatively evaluated with battery health cost function, while the reduction in overall battery cost is analyzed and discussed.
关键词： Renewable energy,Hybrid energy storage system,Photovoltaic,Supercapacitor,Lead-acid battery,Li-ion battery
更新于2025-09-23 15:23:52