1：Experimental Design and Method Selection:

The study involves the fabrication of a ZIF-8@H:ZnO core-shell nanorods arrays/Si heterojunction self-powered photodetector using a combination of hydrogenation and ZIF-8 passivation. The methodology includes hydrothermal growth of ZnO nanorods, hydrogenation treatment, and ZIF-8 passivation.

2：Sample Selection and Data Sources:

p-type (100) silicon substrate was used as the base material. ZnO nanorods were grown on the silicon substrate via a hydrothermal method.

3：List of Experimental Equipment and Materials:

Equipment includes a field emission scanning electron microscope (FESEM, JEOL JSM-6500), transmission electron microscope (TEM, FEI Tecnai G2 F20/F30), X-ray diffraction (XRD, X’Pert PRO MPD), Raman spectroscopy (HORIBA JOBIN YVON, LabRAMHR800), X-ray photoelectron spectroscopy (XPS, ESCALAB 250Xi), UV-VIS-NIR spectrometer (HITACHI, U-4100), electron paramagnetic resonance (EPR, Bruker A300 spectrometer), and time-resolved photoluminescence (TRPL, FLS920 fluorescence lifetime spectrophotometer). Materials include ZnO target (99.9%), p-type (100) silicon substrate, and chemicals for hydrothermal synthesis.

4：9%), p-type (100) silicon substrate, and chemicals for hydrothermal synthesis. Experimental Procedures and Operational Workflow:

4. Experimental Procedures and Operational Workflow: The process involves deposition of a ZnO seed layer on silicon substrate, hydrothermal growth of ZnO nanorods, hydrogenation treatment, ZIF-8 passivation, and device fabrication with palladium top electrode and indium bottom electrode.

5：Data Analysis Methods:

Performance parameters such as detectivity, responsivity, and sensitivity were calculated from photocurrent measurements under various light illuminations. Structural and compositional analyses were performed using XRD, XPS, Raman spectroscopy, and EPR.