研究目的
Investigating the fabrication and characterization of a CH3NH3PbI3/BiFeO3 heterojunction photodetector operating at the near-infrared region.
研究成果
The fabricated CH3NH3PbI3/BiFeO3 heterojunction photodetector exhibits high responsivity and detectivity in the near-infrared region, with a reasonably good photoresponse time. The use of BiFeO3 as an optical filter layer enhances responsivity at the cost of response speed.
研究不足
The response time of the photodetector is higher than that of CH3NH3PbI3-only photodetectors, possibly due to the delay introduced by the BiFeO3 filter layer.
1:Experimental Design and Method Selection:
The study involves the synthesis of BiFeO3 nanoparticles via a solid-state route and CH3NH3PbI3 via a sol-gel chemical route. The heterojunction device is fabricated by depositing these materials on an ITO-coated glass substrate.
2:Sample Selection and Data Sources:
The samples include BiFeO3 and CH3NH3PbI3 thin films. Data is collected using XRD, HRSEM, UV-Vis spectroscopy, and electrical measurements.
3:List of Experimental Equipment and Materials:
Equipment includes a spin coater, thermal evaporator, semiconductor parameter analyzer, monochromator, and power meter. Materials include Bi2O3, Fe2O3, CH3NH3I, PbI2, DMF, and Ag.
4:Experimental Procedures and Operational Workflow:
The process involves cleaning the ITO substrate, depositing BiFeO3 and CH3NH3PbI3 layers, annealing, and depositing Ag electrodes. Photoresponse is measured under monochromatic light.
5:Data Analysis Methods:
Responsivity and detectivity are calculated using photocurrent density and optical power density measurements.
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Semiconductor parameter analyzer
B1500A
Keysight
Measuring electrical characteristics
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Power meter
PM100D
Thorlabs
Measuring optical power density
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UV-Vis spectroscopy
V-770
JASCO
Analyzing optical absorbance
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X-ray diffraction
RIGAKU
Japan
Characterizing the crystalline structure of materials
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HRSEM
Nova Nano SEM 450
USA
Surface morphology analysis
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Monochromator
SP2150i
Princeton Instruments
Providing monochromatic light
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