研究目的
Investigating the possibility of detecting changes in structural bonds and the impurity composition under conditions of laser-induced graphitization of the surface in sectoral nitrogen-containing HPHT diamonds.
研究成果
Analyzing the diamond’s plasma spectra after the end of laser-induced surface graphitization, including analyzing the plasma spectra at surface transition states, can be an effective indicator of changes in the structural bonds of carbon atoms and the level of doping with other impurities, both within one multisectoral plate, and for plates with different levels of doping.
研究不足
The reasons for the sharp drop in the intensities of O and H bands in the (111) sector during the transient part of the laser-induced graphitization stage are not completely clear, indicating a limitation in understanding all aspects of the graphitization process.
1:Experimental Design and Method Selection:
The study utilized laser-induced breakdown spectroscopy (LIBS) to analyze synthetic diamonds, focusing on the process of laser-induced graphitization.
2:Sample Selection and Data Sources:
Different multisectoral plates of synthetic single-crystal diamonds grown by HPHT technique were investigated.
3:List of Experimental Equipment and Materials:
A pulsed Nd3+: YAG laser at 1064 nm, an AvaSpec-ULS2048L fiber-output spectrometer, and an inVia confocal Raman microscope were used.
4:Experimental Procedures and Operational Workflow:
The surface ablation of samples was carried out by focused laser radiation, with plasma spectra processing performed using proprietary software.
5:Data Analysis Methods:
The plasma emission spectra were normalized and combined into series for each stationary ablation mode, approximated by a normal distribution.
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