研究目的
To improve performances of inverted perovskite solar cells (IPSCs) by enhancing carrier collection ability and increasing more exciton in active layer using nanorod array and mesoporous structure.
研究成果
The incorporation of TiO2 nanorod arrays and mesoporous layers significantly improves the power conversion efficiency of inverted perovskite solar cells. The optimal configurations were found to be a 1.5-μm-periodic TiO2 nanorod array and a 500 °C-annealed TiO2 mesoporous layer, achieving a power conversion efficiency of 14.47%.
研究不足
The study focuses on the structural improvements of the electron transport layer and does not explore the potential of using higher quality perovskite materials, which could further enhance the performance of the IPSCs.
1:Experimental Design and Method Selection:
The study involved the fabrication of IPSCs with TiO2 nanorod arrays and mesoporous layers to enhance carrier collection and light absorption.
2:Sample Selection and Data Sources:
Fluorine-doped tin oxide (FTO)-coated glass substrates were used as the base for the solar cells.
3:List of Experimental Equipment and Materials:
Equipment included an electron beam evaporator, spin coater, two-beam He-Cd laser interference photolithography system, and a radio frequency magnetron sputtering system. Materials included TiO2 powder, ethyl cellulose, terpineol anhydrous, ethanol, methylammonium iodide, lead iodide, γ-butyrolactone, dimethyl sulfoxide, spiro-OMeTAD, chlorobenzene solvent, 4-tert-butylphyridine, and bis(trifluoromethane) sulfonamide lithium salt.
4:Experimental Procedures and Operational Workflow:
The process involved cleaning the FTO substrates, depositing TiO2 films, creating nanorod arrays via interference lithography, depositing perovskite active layers, and finally, adding hole transport layers and silver electrodes.
5:Data Analysis Methods:
The performance of the solar cells was evaluated through current density-voltage characteristics, external quantum efficiency measurements, and dark current density analysis.
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