研究目的
Investigating the scalable spray coating of colloidal CdSeTe quantum dots (QDs) for photovoltaics and photodetector applications.
研究成果
The spray coating process is a promising technology for the industrial-scale production of optoelectronic devices, demonstrating high performance in photodetectors with broadband response, high responsivity, and detectivity.
研究不足
The study focuses on the spray coating process for QD film fabrication and its application in photodetectors. Limitations include the specific conditions required for optimal performance (40 spray coating cycles) and the need for further optimization for industrial-scale production.
1:Experimental Design and Method Selection:
The study involved the design of a spray coating platform for preparing colloidal ternary CdSeTe QD film for photodetectors. A mixture solvent with water and ethanol was used to enhance the adhesive force between QDs and the substrate interface.
2:Sample Selection and Data Sources:
Colloidal CdSeTe QDs were synthesized and used as the active material. The substrates were FTO covered glasses treated with UV-ozone.
3:List of Experimental Equipment and Materials:
Chemicals included selenium powder, cadmium oxide, tellurium powder, and others. Equipment included a scanning electron microscope (SU8020, Hitachi Co.), UV-vis spectrophotometer (Puxi-T10, PERSEE), and others.
4:Experimental Procedures and Operational Workflow:
The QDs were synthesized, ligands were exchanged, and the QDs were dissolved in a mixture of deionized water and ethanol. The QDs were then spray-coated onto the substrate under controlled conditions.
5:Data Analysis Methods:
The performance of the photodetectors was evaluated based on current density-voltage curves, responsivity, detectivity, and rise time.
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scanning electron microscope
SU8020
Hitachi Co.
Measuring the SEM images of QDs films
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TEM instrument
JEM-2010
Hitachi Co.
Measuring the TEM images of QDs
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X-ray diffractometer
PANalytical B.V.
PANalytical B.V.
Measuring the structure of the materials
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ultraviolet near-infrared spectrophotometer
Puxi-T10
PERSEE
Measuring the UV-vis absorption of QDs and films
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luminescence spectrometer
FL-380
GANGDONG
Measuring the PL of QDs
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multimeter
Keithley 2400
TE Connectivity
Measuring the current density-voltage curves
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xenon lamp
150 W
SOFN
Used in responsivity measurement
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monochromator
DK240
Spectral Products
Used in responsivity measurement
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electrochemical workstation
Chenhua
Measuring the current-time response
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