研究目的
Investigating a simple laser-based process for the direct writing of thin TMDC layers, specifically MoS2 and WS2, under ambient conditions.
研究成果
The study demonstrates a simple, cost-effective laser-based method for the direct writing of thin TMDC layers, specifically MoS2 and WS2, under ambient conditions. The method allows for the fabrication of patterns with designed layer numbers and is versatile for other TMDCs. Future work will focus on process optimization and understanding the formation mechanism.
研究不足
The crystalline quality of the laser-irradiated MoS2 is inferior to exfoliated samples, as indicated by broader Raman spectral features. The process's mechanism, whether heat or photo-induced, is not fully understood.
1:Experimental Design and Method Selection:
The study employs a laser-based process for the direct writing of thin TMDC layers, utilizing a dip-coated MoS2 precursor exposed to laser irradiation.
2:Sample Selection and Data Sources:
The substrates used were 200 nm of SiO2/Si, cleaned and treated to enhance wettability. The precursor solution was prepared with ammonium tetrathiomolybdate (ATTM) in n-methyl-2-pyrrolidone (NMP).
3:List of Experimental Equipment and Materials:
A Horiba T6400 spectrometer for Raman spectroscopy, a Bruker Dimension Edge AFM, and a 532 nm Nd:YAG laser for irradiation.
4:Experimental Procedures and Operational Workflow:
The precursor was dip-coated onto the substrate, baked, and then irradiated with the laser. The resulting MoS2 layers were characterized by AFM and Raman spectroscopy.
5:Data Analysis Methods:
The thickness and quality of the MoS2 layers were assessed by the spectral distance between E1 2g and A1g Raman bands and by AFM measurements.
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