研究目的
Investigating the rapid fabrication of efficient perovskite solar cells (PSCs) through intense pulsed light (IPL) annealing of SnO2 electron transport layer (ETL) and mixed triple cation perovskite thin films, and the role of di-iodomethane (CH2I2) additive in enhancing PSC efficiency.
研究成果
The study demonstrated the feasibility of using IPL for rapid fabrication of efficient PSCs on both rigid and flexible substrates. The addition of CH2I2 improved film morphology and crystallinity, leading to enhanced device performance. Sequential step IPL annealing presents a promising approach for scalable roll-to-roll manufacturing of PSCs.
研究不足
The study was limited by the IPL machine's capability to provide pulse energies higher than 2.1 kJ. Additionally, the flexible PSCs showed lower performance compared to rigid cells, attributed to higher resistance of ITO coated sheets and handling issues.
1:Experimental Design and Method Selection
The study utilized intense pulsed light (IPL) for rapid thermal processing of SnO2 ETL and perovskite thin films. The methodology included spin-coating for film deposition and IPL for annealing.
2:Sample Selection and Data Sources
Samples included rigid glass-FTO and flexible PET-ITO substrates. Data was collected through SEM, UV-vis, PL, XRD, XPS, IS, and current-voltage measurements.
3:List of Experimental Equipment and Materials
Materials included PbI2, N,N-Dimethylformamide, di-iodomethane, SnO2 solution, Methylammonium iodide, Formamidinium iodide, Spiro-MeOTAD, FTO glass substrates, and ITO coated PET sheets. Equipment included SEM (FEI Nova NanoSEM 600), XRD (Bruker AXS D8 X-ray Diffractometer), IPL machine (Xenon S-2000 rack-mounted sintering system), and others.
4:Experimental Procedures and Operational Workflow
The process involved substrate cleaning, SnO2 ETL spin-coating and IPL annealing, perovskite ink preparation and spin-coating, IPL annealing of perovskite films, and deposition of Spiro-MeOTAD and gold electrodes.
5:Data Analysis Methods
Data analysis involved characterization techniques (SEM, UV-vis, PL, XRD, XPS) and performance evaluation (IS, current-voltage measurements).
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