研究目的
To demonstrate a unique method of investigating the carrier multiplication (CM) via photocurrent measurements using a PbS-QD-decorated tip of a conductive atomic force microscope (CAFM) system.
研究成果
The study demonstrates a nearly ideal CM efficiency with the lowest threshold energy of twice the bandgap energy in PbS QDs using tip-assisted photocurrent measurement. This approach is robust for evaluating the CM effect in low-dimensional materials.
研究不足
The technique is limited by the need for a vacuum environment and the specific setup of the CAFM system, which may not be readily available in all research settings.
1:Experimental Design and Method Selection:
The study employs a conductive atomic force microscope (CAFM) system equipped with a PbS-QD-decorated Au tip to measure local photocurrent.
2:Sample Selection and Data Sources:
PbS quantum dots (QDs) are anchored on a Au tip using a dielectrophoresis method, and photocurrent is measured between the QDs and a graphene layer on a SiO2/Si substrate.
3:List of Experimental Equipment and Materials:
CAFM system (NT-MDT, Russia), white light continuum source (Energetiq, USA), bandpass filter (Thorlab, 10 nm bandwidth), Au-coated tip (NT-MDT, VIT P/Au).
4:Experimental Procedures and Operational Workflow:
The photocurrent is measured under vacuum with incident light focused on the tip end, using bandpass filters to select wavelengths.
5:Data Analysis Methods:
The quantum yield is calculated from the normalized photocurrent data.
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