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Metal-Semiconductor-Metal ?μ-Ga2O3 Solar-Blind Photodetectors with a Record High Responsivity Rejection Ratio and Their Gain Mechanism

DOI:10.1021/acsphotonics.9b01727 期刊:ACS Photonics 出版年份:2020 更新时间:2025-09-19 17:13:59
摘要: In recent years, Ga2O3 solar-blind photodetector (SBPD) has been attached great attention for its potential application in solar-blind imaging, deep space exploration, and confidential space communication, etc. In this work, we demonstrated an ultrahigh performance ε-Ga2O3 metal-semiconductor-metal (MSM) SBPD. The fabricated photodetectors exhibited record-high responsivity and fast decay time of 230 A/W and 24 ms, respectively, compared with MSM-structured Ga2O3 photodetectors reported to date. Additionally, the ε-Ga2O3 MSM SBPD presents ultrahigh detectivity of 1.2×1015 Jones with low dark current of 23.5 pA under the operation voltage of 6 V, suggesting its strong capability of detecting an ultraweak signal. The high sensitivity and wavelength selectivity of the photodetector were further confirmed by the record high responsivity rejection ratio (R250nm/R400nm) of 1.2×105. From the temperature-dependent electrical characteristics in the dark, the thermionic field emission and Poole-Frenkel emission were found to be responsible for the current transport in the low and high electric field regimes, respectively. In addition, the gain mechanism was revealed by the Schottky barrier lowering effect due to the defect states at the interface of metal contact and Ga2O3 or in the bulk of Ga2O3 based on current transport mechanism and density functional theory (DFT) calculation. These results facilitate a better understanding of ε-Ga2O3 photoelectronic devices and provide possible guidance for promoting their performance in future solar-blind detection applications.
作者: Yuan Qin,Liheng Li,Xiaolong Zhao,Gary S. Tompa,Hang Dong,Guangzhong Jian,Qiming He,Pengju Tan,Xiaohu Hou,Zhongfang Zhang,Shunjie Yu,Haiding Sun,Guangwei Xu,Xiangshui Miao,Kanhao Xue,Shibing Long,Ming Liu
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To demonstrate an ultrahigh performance ε-Ga2O3 metal-semiconductor-metal (MSM) solar-blind photodetector (SBPD) and investigate its gain mechanism.

The fabricated MSM ε-Ga2O3 SBPD exhibits ultrahigh performance, including a record high responsivity of 230 A/W, ultrahigh detectivity of 1.2×1015 Jones, and a fast recovery speed of 24 ms. The gain mechanism is attributed to the Schottky barrier lowering effect due to defect states at the metal-semiconductor interface or in the bulk Ga2O3. These results suggest that ε-Ga2O3 has potential for future solar-blind photosensing and imaging applications.

The study focuses on the ε-Ga2O3 phase, and other phases of Ga2O3 are less explored. The performance of the photodetector may be influenced by the quality of the ε-Ga2O3 film and the fabrication process.

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