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High-speed colour-converting photodetector with all-inorganic CsPbBr3 perovskite nanocrystals for ultraviolet light communication

DOI:10.1038/s41377-019-0204-4 期刊:Light: Science & Applications 出版年份:2019 更新时间:2025-09-19 17:13:59
摘要: Optical wireless communication (OWC) using the ultra-broad spectrum of the visible-to-ultraviolet (UV) wavelength region remains a vital field of research for mitigating the saturated bandwidth of radio-frequency (RF) communication. However, the lack of an efficient UV photodetection methodology hinders the development of UV-based communication. The key technological impediment is related to the low UV-photon absorption in existing silicon photodetectors, which offer low-cost and mature platforms. To address this technology gap, we report a hybrid Si-based photodetection scheme by incorporating CsPbBr3 perovskite nanocrystals (NCs) with a high photoluminescence quantum yield (PLQY) and a fast photoluminescence (PL) decay time as a UV-to-visible colour-converting layer for high-speed solar-blind UV communication. The facile formation of drop-cast CsPbBr3 perovskite NCs leads to a high PLQY of up to ~73% and strong absorption in the UV region. With the addition of the NC layer, a nearly threefold improvement in the responsivity and an increase of ~25% in the external quantum efficiency (EQE) of the solar-blind region compared to a commercial silicon-based photodetector were observed. Moreover, time-resolved photoluminescence measurements demonstrated a decay time of 4.5 ns under a 372-nm UV excitation source, thus elucidating the potential of this layer as a fast colour-converting layer. A high data rate of up to 34 Mbps in solar-blind communication was achieved using the hybrid CsPbBr3–silicon photodetection scheme in conjunction with a 278-nm UVC light-emitting diode (LED). These findings demonstrate the feasibility of an integrated high-speed photoreceiver design of a composition-tuneable perovskite-based phosphor and a low-cost silicon-based photodetector for UV communication.
作者: Chun Hong Kang,Ibrahim Dursun,Guangyu Liu,Lutfan Sinatra,Xiaobin Sun,Meiwei Kong,Jun Pan,Partha Maity,Ee-Ning Ooi,Tien Khee Ng,Omar F. Mohammed,Osman M. Bakr,Boon S. Ooi
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To address the technology gap in UV photodetection by developing a hybrid Si-based photodetection scheme incorporating CsPbBr3 perovskite nanocrystals for high-speed solar-blind UV communication.

The study successfully demonstrated a hybrid CsPbBr3–silicon photodetection scheme with enhanced responsivity and EQE in the UV region. The high PLQY and fast PL decay time of CsPbBr3 NCs make them suitable for high-speed UV communication. The findings pave the way for the development of low-cost, high-performance UV photodetectors.

The study is limited by the photostability of the CsPbBr3 perovskite NC layer under intense UV illumination, which degrades over time due to thermal degradation and photooxidation. Future work could explore encapsulation or surface passivation techniques to improve stability.

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