研究目的
Investigating the control of CdS and Mn2+-doped-CdS Q-dots in a silicate glass for magneto-optical applications.
研究成果
The research successfully demonstrated the growth of CdS and Mn2+ doped CdS Q dots in a glass matrix, showing a variation in band gap due to Mn2+-ion doping. The highest Verdet constant observed in such a glassy host might be useful for engineering waveguide based Faraday rotation devices.
研究不足
The study is limited by the annealing temperature's effect on the size distribution of Q-dots and the consequent impact on the Verdet constant. The research also highlights the need for optimizing Q-dot size to reduce scattering loss in the medium for engineering M-O light waveguide devices.
1:Experimental Design and Method Selection:
The study involved the synthesis of CdS and Mn2+-doped CdS quantum dots in a silicate glass matrix using conventional glass fusion and annealing methods. The microstructural and optical properties were characterized using XRD, FETEM, UV-Visible-NIR, and PL spectroscopic techniques.
2:Sample Selection and Data Sources:
Glass samples with DMS-QD were prepared using synthetic precursors. The host glass matrix was melted and homogenized at 1150oC for 4 hours in nitrogen atmosphere.
3:List of Experimental Equipment and Materials:
Equipment used includes X-Ray Diffractometer (Bruker D8), Field-emission transmission electron microscopy (FE-TEM) (Philips CM20), Perkin Elmer Lambda 950 spectrophotometer, and Horiba Flurolog 3 Fluorimeter.
4:Experimental Procedures and Operational Workflow:
After doping the melts with CdS and Cd
5:844Mn166S, they were quenched in air in a stainless steel mould and then annealed. Data Analysis Methods:
The size distribution of Q-dots was calculated using the Brus equation, and the Verdet constant was calculated from the Faraday rotation angle.
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