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Characterisation of spectroscopic and magneto-optical faraday rotation in Mn2+- doped CdS quantum dots in a silicate glass

DOI:10.1016/j.jallcom.2019.152696 期刊:Journal of Alloys and Compounds 出版年份:2019 更新时间:2025-09-19 17:13:59
摘要: We demonstrate the control of CdS and Mn2+-doped-CdS Q-dots in a silicate glass for magneto-optical applications. The microstructural properties of Q-dot glasses were investigated by X-Ray diffraction (XRD), Field Emission Transmission Electron Microscopy (FETEM) and the optical properties by UV-Visible-NIR and Photoluminescence (PL) spectroscopic techniques, respectively. The FETEM of the CdS QD–glass heat treated at 600oC reveals that the size of CdS and Mn2+-doped CdS Q-dots are in the range of 4-5 nm and 5-6nm, respectively. The observed size distributions of Q-dots were in reasonable agreement with the data, derived from X-ray line broadening and estimated average Bohr radii using the UV-visible absorption data. Photoluminescence characteristics were investigated at room temperature by exciting the CdS and Mn2+-doped-CdS Q-dot glasses with a 420 nm excitation source, which yielded broad emission spectra in the visible and near-IR range (450-800nm). We observed a red shift in the emission peak with increase in the Q-dot size, controlled by heat treatment temperature range (550-600oC). The room-temperature magneto-optical Faraday rotation measurements on Q-dots glasses were carried out using magnetic field strength up to 360 mT, and observed an increase in the value of Verdet constant, from 6.2 to 12.0 degree/T-cm, when comparing undoped CdS-Q-dot glass with Mn2+-doped CdS glass. The demonstration of enhanced Verdet constant in Q-dot silicate glasses with sub-Tesla field paves the path for engineering range magneto-optical devices for photonics, spintronics and sensors applications, in which the polarisation of photons may be controlled with low-intensity magnetic field in optical waveguides.
作者: Rajendra P. Panmand,Shashikant P. Tekale,Krishna D. Daware,Suresh W. Gosavi,Animesh Jha,Bharat B. Kale
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Investigating the control of CdS and Mn2+-doped-CdS Q-dots in a silicate glass for magneto-optical applications.

The research successfully demonstrated the growth of CdS and Mn2+ doped CdS Q dots in a glass matrix, showing a variation in band gap due to Mn2+-ion doping. The highest Verdet constant observed in such a glassy host might be useful for engineering waveguide based Faraday rotation devices.

The study is limited by the annealing temperature's effect on the size distribution of Q-dots and the consequent impact on the Verdet constant. The research also highlights the need for optimizing Q-dot size to reduce scattering loss in the medium for engineering M-O light waveguide devices.

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