研究目的
Investigating the manufacturability-aware process of p-n junction formation for photovoltaic cells involving with Si nanoparticle layer.
研究成果
The proposed infrared laser treatment technique is promising for the formation of p-n junctions with Si ink-based photovoltaic cells. High pulse overlap and a long exposure time are preferable for achieving lower sheet resistance in PN junctions.
研究不足
The research did not explore the optimization of laser power density to minimize crystallographic defects on Si substrates.
1:Experimental Design and Method Selection:
The research used a fiber laser at a wavelength of 1064 nm for the local heating dopant diffusion process.
2:Sample Selection and Data Sources:
Mono-crystalline p-type Si CZ wafers with an orientation of <100>, a thickness of 275 μm, and a resistivity of 1–10 ohm/cm were used.
3:List of Experimental Equipment and Materials:
A Yb-doped fiber laser (SPI IF20LRM110), n-type spin-on-dopant P509 from Filmtronics, Si nanoparticles from Meliorum Technologies, and carbon NP dispersion from Tokai Carbon.
4:Experimental Procedures and Operational Workflow:
The samples were cleaned, spin-coated with n-type SOD or n-type SOD + Si NPs, and then with carbon NP dispersion. The laser beam was scanned over the samples to diffuse the n-type dopant into the p-type substrate.
5:Data Analysis Methods:
Sheet resistance was measured using the four-point probe method, and dopant concentration profiles were analyzed using secondary ion mass spectroscopy (SIMS).
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