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Device physics of back-contact perovskite solar cells

DOI:10.1039/C9EE04203B 期刊:Energy & Environmental Science 出版年份:2020 更新时间:2025-09-19 17:13:59
摘要: Back-contact perovskite solar cells (PSCs) are a promising candidate to further increase power conversion efficiency (PCE) and have been the subject of many investigations. However their full potential has not been achieved due a lack of a complete understanding of their operation from a device physics perspective. In this study, a detailed photoelectrical model for back-contact PSCs is developed by coupling a drift-diffusion description of free charge transport model with ion migration currents and emitted-carrier generation resulting from photon recycling. By studying the influence of relevant electrical parameters, the interplay between charge generation, transport and recombination, is revealed to further clarify the design principles based on devices with a back-contact structure. Although devices featuring the back-contact structure exhibit a sensitivity to electrical parameters, a high PCE exceeding 25% is predicted if the interface passivation and perovskite film quality can be well controlled. Different conduction band and valence band offsets offer various screening opportunities for functional materials with high efficiencies are introduced. Additionally, the simulated results revealed that mobile ions degrade the device performance if the average ion concentration exceeds 1016 cm?3. Furthermore, we point out that photon recycling can effectively compensate against radiative recombination, thereby resulting in an improved open circuit voltages. The results provide a new understanding of the carrier transport dynamics, ion migration, and photon recycling effects for the back-contact structure, which can be applied to a systematic improvement in the design of high efficiency PSCs.
作者: Zhenhai Yang,Weichuang Yang,Xi Yang,James Greer,Jiang Sheng,Baojie Yan,Jichun Ye
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Investigating the device physics and performance optimization of back-contact perovskite solar cells (PSCs) through a detailed photoelectrical model that includes ion migration and photon recycling effects.

The QIBC PSCs can achieve higher Jsc than traditional sandwich devices due to suppressed parasitic absorption, with a predicted PCE exceeding 25% under optimal conditions. Mobile ions significantly affect device performance if their concentration exceeds 1016 cm?3, and photon recycling can improve Voc by suppressing radiative recombination. The study provides guidelines for designing high-efficiency QIBC PSCs.

The study assumes parameters are independent of each other, which may not fully capture the complex interactions in real devices. Additionally, the relationship between mobile ion concentration and perovskite film quality degradation is not considered.

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