研究目的
Investigating the control of emission spectrum in monolithic blue-cyan dichromatic light-emitting diodes through thickness variation of the GaN barrier and optimization of the barrier doping with n- or p-type impurities.
研究成果
The study demonstrates that the blue-to-cyan ratio in the emission spectra of dichromatic LEDs can be effectively controlled by varying the thickness and doping of the GaN barrier between quantum wells, without substantial decrease in emission efficiency. A novel mechanism involving enhanced Shockley-Read-Hall recombination in the barrier is suggested for spectral control.
研究不足
The study focuses on blue-cyan dichromatic LEDs and may not directly apply to LEDs emitting in other spectral ranges. The impact of the GaN barrier width and doping on characteristics of white light produced by combination with phosphors is not discussed.
1:Experimental Design and Method Selection:
The study involves the growth of LED samples by metal-organic chemical vapor deposition on sapphire substrates, with variations in the GaN barrier thickness and doping type and level between blue and cyan quantum wells.
2:Sample Selection and Data Sources:
A set of LED samples with different barrier thicknesses and doping levels were grown and characterized.
3:List of Experimental Equipment and Materials:
An AIX2000HT planetary reactor system was used for growth, with specific precursors and dopants.
4:Experimental Procedures and Operational Workflow:
The structures were characterized by electroluminescence spectroscopy at room temperature, with operation currents varied from 1 to 150 mA.
5:Data Analysis Methods:
Numerical simulations were carried out using a drift-diffusion model to understand the mechanisms controlling the emission spectra and efficiency.
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AIX2000HT planetary reactor system
AIX2000HT
AIXTRON
Used for the growth of LED samples by metal-organic chemical vapor deposition.
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Trimethylgallium
Precursor used in the growth process.
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Trimethylindium
Precursor used in the growth process.
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Trimethylaluminum
Precursor used in the growth process.
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Ammonia
Precursor used in the growth process.
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Silicon
Used for n-type doping.
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Magnesium
Used for p-type doping.
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Hydrogen
Carrier gas used in the growth process.
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Nitrogen
Carrier gas used in the growth process.
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Calibrated silicon photodiode
Used to determine the external quantum efficiency (EQE) of the LEDs.
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