研究目的
Investigating the broad-band emission and color tuning of Eu3+-doped LiCa2SrMgV3O12 phosphors for warm white light-emitting diodes.
研究成果
The Eu3+-doped LCSMV phosphors exhibit broad-band emission and color tunable properties, making them suitable for application in warm white light-emitting diodes. The energy transfer from (VO4)3- groups to Eu3+ ions is governed by electric dipole-dipole interaction. The fabricated LED lamp demonstrates potential for lighting and display applications with a CCT of 3655 K and Ra of 90.
研究不足
The thermal stability of the phosphors decreases with increasing temperature, with the emission intensity dropping to 50% at around 60-65 °C. The quantum efficiency values, while promising, could potentially be improved by optimizing synthetic conditions.
1:Experimental Design and Method Selection
Series of Eu3+-doped LiCa2SrMgV3O12 (LCSMV) phosphors were prepared via solid phase reaction. Their spectroscopic properties were investigated systematically by photoluminescence excitation (PLE) and emission (PL) spectra, temperature-dependent PL spectra and luminescence decay curves.
2:Sample Selection and Data Sources
LiCa2SrMgV3O12: xEu3+ (x = 0–0.05) compounds were prepared via solid phase reaction using Li2CO3, MgO, CaCO3, SrCO3, NH4VO3, and Eu2O3 as raw materials.
3:List of Experimental Equipment and Materials
X-ray diffractometer (DMAX2500, RIGAKU) with Cu Kα radiation, Edinburgh Instruments FS5 spectrofluorometer with 150 W xenon lamps, integrating sphere for QE measurement, Edinburgh Instruments (FLS 980) for temperature-dependent PL spectra.
4:Experimental Procedures and Operational Workflow
The raw materials were mixed homogeneously with ethanol and sintered at 850 °C for 5 h. The phase structure was checked by XRD, and spectroscopic properties were characterized by PLE and PL spectra, luminescence decay curves, and temperature-dependent PL spectra.
5:Data Analysis Methods
The decay curves were fitted to a bi-exponential function to analyze the luminescence lifetimes. The QE values were estimated using an integrating sphere.
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X-ray diffractometer
DMAX2500
RIGAKU
Checking the phase structure of the product
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Spectrofluorometer
FS5
Edinburgh Instruments
Characterizing spectroscopic properties including PLE and PL spectra, luminescence decay curves
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Dynamic-heating device
FLS 980
Edinburgh Instruments
Characterizing temperature-dependent PL spectra
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Integrating sphere
Not specified
Edinburgh Instruments
Recording the quantum efficiency of the sample
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