研究目的
To demonstrate a flexible and haze-controllable QD-GFRH film for improving photoluminescence extraction in surface light sources for display and lighting applications.
研究成果
The flexible and haze-controllable QD-GFRH film demonstrated improved photoluminescence extraction, robust mechanical properties, and superior thermal and chemical stability. It showed potential for large-scale and flexible white surface light sources, covering a wide color gamut.
研究不足
The study focuses on the fabrication and characterization of QD-GFRH films but does not extensively explore the scalability of the manufacturing process or the cost-effectiveness compared to existing technologies.
1:Experimental Design and Method Selection:
The study involved the synthesis of a QD-GFRH film through sol-gel condensation and vacuum bag pressing method, utilizing refractive index mismatch for haze control.
2:Sample Selection and Data Sources:
Core/shell structured CdSe/CdZnS QDs were used, with glass fiber as the light scattering material.
3:List of Experimental Equipment and Materials:
Materials included MPMDMS, toluene, barium hydroxide monohydrate, BDK, MPTMS, DPSD, and oleic acid-capped CdSe/CdZnS quantum dots. Equipment included SEM, AFM, UV–vis–NIR spectrometer, TMA, DMA, and PL spectrometer.
4:Experimental Procedures and Operational Workflow:
The process involved ligand exchange, sol-gel condensation, vacuum bag pressing, and UV radiation for polymerization.
5:Data Analysis Methods:
Data were analyzed using FT-IR spectroscopy, 29Si NMR, TGA, and PL decay dynamics analysis.
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FT-IR spectroscopy
FT-IR 4600
JASCO
Confirmation of silica encapsulated QDs and MerQD/oligosiloxane resin
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Nuclear magnetic resonance spectroscopy
400 MHz NMR
Bruker
Measurement of 29Si NMR spectrum
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UV–vis–NIR spectrometer
Solidspec-3700
Shimadzu
Measurement of transmittance
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Universal testing machine
AGS-X STD
Shimadzu
Measurement of stress–strain curves
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Absolute PL quantum yield spectrometer
Quantaurus-QY C11347
Hamamatsu Photovics K.K.
Measurement of PL QY values
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Fluorescence lifetime spectrometer
FL920
Edinburgh Instruments
Measurement of PL decay curves
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CdSe/CdZnS quantum dots
Nanodot-HE-series
Powerlogics
Color conversion in the film
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Glass fiber
Nittobo
Light scattering material
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Thermomechanical analyzer
TMA/SS6100
Seiko Instrument
Measurement of thermomechanical properties
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Dynamic mechanical analyzer
Measurement of storage modulus and tan δ
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Dispersive Raman spectrometer
ARAMIS
Horiba Jobin Yvon
2D image of emission peak position
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Thermos gravimetric analyzer
Q50
TA Instruments
Measurement of TGA profiles
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