研究目的
To synthesize sequential phosphorescent multi-block supramolecular copolymers using PtII and PdII complexes and to investigate their photophysical properties.
研究成果
The synthesis of 1D/2D block PtII and PdII supramolecular copolymers and the discovery of amplified phosphorescence efficiencies in the [Pt$Pd] co-assemblies will facilitate the exploration of potential applications for supramolecular polymeric materials.
研究不足
The study is limited to the synthesis and characterization of PtII and PdII supramolecular copolymers. The application of these materials in practical devices is not explored.
1：Experimental Design and Method Selection:
The study utilized a living supramolecular polymerization approach to synthesize sequential phosphorescent multi-block supramolecular copolymers.
2：Sample Selection and Data Sources:
Pincer PtII and PdII complexes were used as building blocks.
3：List of Experimental Equipment and Materials:
The synthesis involved the use of CH3CN solutions of PtII and PdII complexes, with water injected to induce co-assembly.
4：Experimental Procedures and Operational Workflow:
The process included the preparation of seed solutions and the addition of kinetic aggregates to form block copolymers.
5：Data Analysis Methods:
Time-dependent UV-vis absorption and emission spectra were measured to monitor the polymerization process.
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