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Bright Blue Light Emission of Ni2+ ions doped CsPbClxBr3-x Perovskite Quantum Dots Enabling Efficient Light-Emitting Devices

DOI:10.1021/acsami.0c01074 期刊:ACS Applied Materials & Interfaces 出版年份:2020 更新时间:2025-09-23 15:21:01
摘要: In recent years, significant advances have been achieved in the red and green perovskite quantum dots(PQDs)based light-emitting diodes (LEDs). However, the performances of the blue perovskite LEDs are still seriously lagging behind that of the green and red counterparts. Herein, we successfully developed Ni2+ ions doped CsPbClxBr3-x PQDs through the room-temperature supersaturated recrystallization synthetic approach. We simultaneously realized the doping of various concentrations of Ni2+ cations, and modulated the Cl/Br element ratios through introducing different amount of NiCl2 solution in the reaction medium. By the synthetic method, not only the emission wavelength from 508 to 432 nm of Ni2+ ions doped CsPbClxBr3-x QDs was facially adjusted, but also the photoluminescence quantum yield (PLQY) of PQDs was greatly improved due to efficiently removing the defects of the PQDs. Thus, the blue emission at 470 nm with PLQY of 89% was achieved in 2.5% Ni2+ ions doped CsPbCl0.99Br2.01 QDs, which increased nearly three times over that of undoped CsPbClBr2 QDs, and was the highest for the CsPbX3 PQDs with blue emission that fulfilling the NTSC standards. Benefiting from the high luminous Ni2+ ions doped PQDs, the blue emitting LED at 470 nm was obtained, exhibiting an external quantum efficiency (EQE) of 2.4% and a maximum luminance of 612 cd/m2, which surpassed the best performance reported previously for the corresponding blue-emitting PQDs based LED.
作者: Gencai Pan,Xue Bai,Wen Xu,Xu Chen,Yue Zhai,Jinyang Zhu,He Shao,Nan Ding,Lin Xu,Biao Dong,Yanli Mao,Hongwei Song
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In conclusion, we reported the successful synthesis of the Ni2+ ions doped CsPbClxBr3-x PQDs at room temperature by the modified supersaturated reprecipitation method, in which the different amount of NiCl2 solution was introduced in the reaction medium. The advantage of this synthesis method lies in the fact that it not only efficiently tuned the bandgap of the CsPbClxBr3-x PQDs, from green (508 nm) to blue (432 nm) spectral region is realized, but also the halide vacancy associated to the non-radiative transition of extiton in the PQDs can be efficiently modified. Therefore, the high efficient photoluminescence with PLQY of 89% for the blue emission at 470 nm is achieved in the 2.5% Ni2+ ions doped CsPbCl0.99Br2.01 PQDs, which is the highest result for the CsPbX3 PQDs with blue emission that fulfilling the NTSC standards. Furthermore, the valence band is modulated in the Ni2+ ions doped CsPbClxBr3-x PQDs, leading the elimination of the carrier injection in the LED device, which result in the device with a high luminance of 612 Cd/m2 and a peak EQE of 2.4%. Both of these factors are higher than the current reported best-performing LED based on the blue emitting PQDs, and demonstrate a promising prospect in the LED display applications.

The technical and application constraints of the experiments, as well as potential areas for optimization.

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