研究目的
To develop a novel fluorescent probe based on a diarylethene derivative with a benzothiazide unit for selective detection of Cd2+ ions.
研究成果
The diarylethene derivative demonstrated excellent photochromic properties and high selectivity and sensitivity toward Cd2+. It could serve as a fluorescent probe for Cd2+ detection in methanol and was applied in constructing a molecular logic circuit.
研究不足
The fluorescence response of the derivative to Cd2+ was not observed in aqueous solution due to poor water solubility. The interference of Cu2+ in the fluorescence response to Cd2+ was noted.
1:Experimental Design and Method Selection:
The study involved the synthesis of a diarylethene derivative and investigation of its photochromism and fluorescent properties in methanol solution.
2:Sample Selection and Data Sources:
The derivative was synthesized and its interaction with various metal ions was studied.
3:List of Experimental Equipment and Materials:
Materials were purchased commercially and used without further purification. Instruments included a Bruker AV400 spectrometer, Agilent 1100 ion trap MSD spectrometer, WRS-1B melting point apparatus, Agilent 8453 UV-visible spectrophotometer, MUA-165 UV lamp, MVL-210 visible lamp, Hitachi F-4600 fluorescence spectrophotometer, and Absolute PL Quantum Yield Spectrometer QYC11347-
4:Experimental Procedures and Operational Workflow:
The derivative's photochromism and fluorescent properties were measured under UV/vis light irradiation and in the presence of various metal ions.
5:Data Analysis Methods:
The quantum yields of cyclization and cycloreversion were determined, and the binding constant (Ka) of the derivative with Cd2+ was calculated.
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Agilent 1100 ion trap MSD spectrometer
1100
Agilent
Obtaining HRMS
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Agilent 8453 UV-visible spectrophotometer
8453
Agilent
Collecting absorption spectrum
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Hitachi F-4600 fluorescence spectrophotometer
F-4600
Hitachi
Recording fluorescent spectra
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Bruker AV400 spectrometer
AV400
Bruker
Recording NMR spectra
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WRS-1B melting point apparatus
WRS-1B
Measuring melting point
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MUA-165 UV lamp
MUA-165
Photoirradiation
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MVL-210 visible lamp
MVL-210
Photoirradiation
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Absolute PL Quantum Yield Spectrometer QYC11347-11
QYC11347-11
Measuring quantum yield
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