研究目的
Comparison of the physicochemical properties of TiO2 thin films obtained by magnetron sputtering with continuous and pulsed gas flow.
研究成果
The application of gas impulse in magnetron sputtering significantly improves the hardness and scratch resistance of TiO2 thin films, in addition to altering their structural properties from fibrous-like anatase to nanocrystalline rutile. This method also results in films with higher refractive index and packing density, making it beneficial for optical coatings.
研究不足
The study focuses on the comparison of TiO2 thin films prepared by two specific magnetron sputtering techniques (MF MS and GI MS) and does not explore other deposition methods or conditions. The research is limited to the analysis of structural, surface, optical, and mechanical properties, without delving into other potential characteristics or applications of the films.
1:Experimental Design and Method Selection:
TiO2 thin films were deposited by two various magnetron sputtering techniques: medium frequency (MF MS) and gas impulse (GI MS). The main difference between the two used sputtering techniques was the change of the pressure during the deposition process, which was a result of applied gas-supplying mode.
2:Sample Selection and Data Sources:
Thin films were deposited on various substrates, including silicon, fused silica, and Ti6Al4V metallic alloys due to different measurement methods used to determine the properties of TiO
3:List of Experimental Equipment and Materials:
The sputtering apparatus was equipped with diffusion and rotary pumps. High-purity metallic titanium targets were sputtered with the use of a DPS power supply working in a unipolar mode at the frequency of 165 kHz of sinusoidal pulses with the voltage amplitude of
4:8 kV. Experimental Procedures and Operational Workflow:
Both deposition processes were conducted for 240 min. Thickness was measured using the Taylor Hobson optical profiler.
5:Data Analysis Methods:
Structural properties were analyzed using X-ray diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM). Surface properties were determined by scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and wettability measurements. Optical properties were analyzed with the use of transmittance and reflectance measurements. Mechanical properties were analyzed by nanoindentation and scratch resistance measurements.
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Olympus BX51 optical microscope
BX51
Olympus
Examination of scratch resistance
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TalySurf CCI Lite Taylor Hobson optical profiler
CCI Lite
Taylor Hobson
Examination of scratch resistance
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PANalytical Empyrean PIXel3D powder diffractometer
Empyrean PIXel3D
PANalytical
X-ray diffraction measurements
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Thermo Fisher Scientific DXR? Raman Microscope
DXR?
Thermo Fisher Scientific
Raman spectroscopy measurements
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TECNAI G2 FEG Super-Twin transmission electron microscope
TECNAI G2 FEG Super-Twin
Thermo Fisher Scientific
Detailed analysis of the crystal structure of TiO2 coatings
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FEI Helios NanoLab 600i SEM
Helios NanoLab 600i
FEI
Surface and cross-sectional morphology estimation
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Ocean Optics QE65000 spectrophotometer
QE65000
Ocean Optics
Transmission spectra measurement
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Taylor Hobson optical profiler
Taylor Hobson
Measuring the thickness of thin films
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DPS power supply
Dora Power Systems
Powering the magnetron in a unipolar mode
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UHV VT AFM/STM Omicron AFM
UHV VT AFM/STM
Omicron
Surface roughness evaluation
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Specs Phoibos 100 MCD-5 hemispherical analyzer
Phoibos 100 MCD-5
Specs
Determining surface chemical states of TiO2 thin films
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Attension Theta Lite tensiometer
Theta Lite
Biolin Scientific
Wettability measurements
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Aquila nkd-8000 spectrophotometer
nkd-8000
Aquila Instruments Limited
Transmittance and reflectance spectra measurement
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CSM Instruments nanoindenter
CSM Instruments
Hardness and Young's elastic modulus analysis
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Taber Oscillating Abrasion Tester 6160
6160
Taber Industries
Scratch resistance measurement
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