研究目的
Investigating the mechanisms of Al incorporation into 4H-SiC during epitaxial growth and proposing a model based on surface vacancy induced incorporation to explain the experimental trends.
研究成果
The proposed model, involving transient formation of surface vacancies, explains the experimental trends of Al incorporation into 4H-SiC during epitaxial growth. Al incorporation is limited by its high desorption rate, and increasing its incorporation requires improving its stability upon adsorption on Si vacancies or reducing its desorption time. The transient formation of C vacancies also plays a role in destabilizing incorporated Al atoms.
研究不足
The model is qualitative and phenomenological, lacking quantitative simulation or DFT-based calculations to validate the assumptions. The discussion is based on literature data, which may not fully represent the physical-chemical parameters at the layer surface during the process.