研究目的
Investigating the effect of synthesis methods (photo-deposition and chemical reduction) on the valence state of Pt and its influence on hydrogen production and dye degradation using Pt/TiO2 nanotube photocatalysts.
研究成果
Pt/TiO2 nanotube photocatalysts prepared by both photo-deposition and chemical reduction methods showed high hydrogen production activity, with the chemical reduction method being more effective for dye degradation due to the presence of multiple oxidation states of Pt. The catalysts exhibited excellent stability under solar light irradiation, making them promising for large-scale applications.
研究不足
The study is limited to the comparison of only two Pt deposition methods and their effects on photocatalytic activities. The scalability and economic viability of the synthesis methods for industrial applications were not addressed.
1:Experimental Design and Method Selection
The study involved the synthesis of TiO2 nanotubes via hydrothermal treatment followed by Pt deposition using photo-deposition and chemical reduction methods. The photocatalytic activities of the synthesized catalysts were evaluated for hydrogen production and dye degradation under solar light irradiation.
2:Sample Selection and Data Sources
TiO2 nanotubes were synthesized from titanium dioxide particles. Pt was deposited on TiO2 nanotubes using hexachloroplatinic acid as the Pt precursor. The photocatalytic activities were measured using gas chromatography for hydrogen production and UV-Vis spectrophotometry for dye degradation.
3:List of Experimental Equipment and Materials
Bruker D8 advance X-ray diffractometer, JASCO V-670 UV-Vis spectrophotometer, Shimadu IR Affinity-1 instrument, Hitachi F-7000 fluorescence spectrophotometer, JEOL JSM-IT-500 SEM, FEI Tecnai F20 S-Twin TEM, Axia Ultra XPS instrument.
4:Experimental Procedures and Operational Workflow
TiO2 nanotubes were synthesized hydrothermally, followed by Pt deposition via photo-deposition and chemical reduction methods. The photocatalytic experiments were conducted in a quartz reactor under solar light irradiation, with periodic sampling for analysis.
5:Data Analysis Methods
XRD for crystal structure analysis, UV-Vis DRS for optical properties, XPS for chemical state analysis, TEM for morphology, and GC for hydrogen production quantification.
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JEOL JSM-IT-500 SEM
JSM-IT-500
JEOL
Used for analyzing the morphology of the catalysts.
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FEI Tecnai F20 S-Twin TEM
Tecnai F20 S-Twin
FEI
Used for high resolution transmission electron microscopy imaging.
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Axia Ultra XPS instrument
Axia Ultra
Kratos Analyticals UK
Used for obtaining X-ray photoelectron spectrum.
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Bruker D8 advance X-ray diffractometer
D8 advance
Bruker
Used for recording powder X-ray diffraction patterns of the catalysts.
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JASCO V-670 UV-Vis spectrophotometer
V-670
JASCO
Used to obtain UV-Vis DRS spectra of the catalysts.
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Shimadu IR Affinity-1 instrument
IR Affinity-1
Shimadu
Used for recording FTIR spectra of the neat samples.
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Hitachi F-7000 fluorescence spectrophotometer
F-7000
Hitachi
Used to collect photoluminescence spectra.
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