摘要： Deep insight into the non-radiative deactivation pathways in phosphorescent cationic iridium complexes is critically important for developing efficient blue-emitting complexes toward advanced applications. Here, we report the synthesis, photophysical and electrochemical characterizations of a blue-green-emitting cationic iridium complex [Ir(ppy)2(bipzpy)]PF6 (Hppy is 2-phenylpyridine and bipzpy is 2,4-di(1H-pyrazol-1-yl)pyridine). The non-radiative deactivation pathways in [Ir(ppy)2(bipzpy)]PF6 have been elucidated through extensive density functional theory calculations. The calculations reveal that the higher-lying charge-transfer (CT) state in [Ir(ppy)2(bipzpy)]PF6, which arises from Ir/ppy→bipzpy transitions, favors non-radiative deactivation because of its large structural distortion compared to the ground state. Both the CT state and the dark metal-centered (3MC) state can be thermally accessed by the lowest-lying emitting triplet state at room temperature, with the former being much more easily accessible, which causes additional non-radiative deactivations for the emitting triplet state. The active roles of the CT and 3MC states in the non-radiative deactivation pathways are, for the first time, confirmed in such blue-emitting complexes with pzpy-type ancillary ligands (pzpy is 2-(1H-pyrazol-1-yl)pyridine).