研究目的
The development of a sustainable, efficient and renewable energy power is a great challenge for our generation. In this context, particular attention is given to concentrating solar power (CSP) as it is a promising technology to improve the efficiency of the solar-to-electricity conversion. The absorber plays a key role by transferring the energy from solar radiation to a heat transfer fluid (HTF), which will be used in a thermodynamical cycle to produce electricity. The objective is to maximize the energy efficiency by developing materials with high solar absorptance and low emittance (spectral selectivity).
研究成果
The SiC-TiC nanocomposite materials show potential for bulk solar absorber applications. The denser and smoother the sample, the higher its spectral selectivity. With an absorptance of 0.76, an emittance of 0.44 and a selectivity of 1.74, the denser SiC-TiC could be a good candidate for bulk solar applications. The study suggests that a SPS sintering temperature of 1650 °C is sufficient to obtain a composite with interesting optical properties.
研究不足
The study did not thoroughly determine whether the closed porosity has an impact on the optical properties. The emittance should be measured directly from the non-illuminated face of the samples and not calculated from the surface reflectance curve. Additionally, the effects on the oxidation resistance were not studied in detail.
1:Experimental Design and Method Selection:
A semi-molecular sol-gel synthesis route was used to create an intimate mixture of the two metal oxide precursors and the carbon source during the gelling. Titanium isopropoxide (TTIP) and tetraethyl orthosilicate (TEOS) were chosen as the source of titanium and silicon, respectively. The system was kept under inert atmosphere by nitrogen flow to prevent unintended reactions among the raw materials and water.
2:Sample Selection and Data Sources:
The resulting SiC-TiC nanocomposite powder was sintered at different temperatures to produce samples with various relative densities (from 57% to 96%).
3:List of Experimental Equipment and Materials:
Scanning Electron Microscopy (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX), X-Ray Diffraction (XRD), carbon and oxygen elemental analyzers, Spark Plasma Sintering (SPS) apparatus, spectrophotometers for optical properties measurement.
4:Experimental Procedures and Operational Workflow:
The synthesis involved complexation of TTIP with citric acid, addition of TEOS and sucrose, co-condensation, vacuum distillation, freeze drying, grinding, and sifting. The powder was then sintered by SPS at various temperatures.
5:Data Analysis Methods:
The optical properties were analyzed using spectrophotometers to measure the total spectral reflectance in the 0.25–25 μm wavelength range. The data were interpolated and analyzed using Mathematica software.
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