研究目的
To improve the stability and reliability of silver nanowire (AgNW) electrodes for high-temperature applications using selective photoresist passivation.
研究成果
Selective photoresist passivation with a 120 s development time significantly improves the optical and electrical stability of AgNW electrodes, reducing Rayleigh instability effects and enhancing durability under high-temperature conditions, making it a promising approach for reliable optoelectronic applications.
研究不足
The method may not be suitable for all substrate types; prolonged development time (e.g., 300 s) can lead to corrosion of AgNWs, reducing effectiveness. The process is specific to the materials and conditions used, and scalability for industrial applications may require further optimization.
1:Experimental Design and Method Selection:
The study employs a photolithography-based selective passivation method to encapsulate AgNWs on a poly[ether sulfone] (PES) substrate using positive photoresist AZ5214. The development time of the UV-exposed photoresist is varied to control the passivation coverage.
2:The development time of the UV-exposed photoresist is varied to control the passivation coverage. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: AgNWs of 20 nm diameter and 20 μm length suspended in solution from C3NANO are used. They are deposited on PES substrates via spin-coating at 3000 rpm for 1 min, followed by annealing at 130 °C to remove solvents. Ag pads are prepared using a paste.
3:List of Experimental Equipment and Materials:
Equipment includes a spin coater, photolithography system (SF-100 XCEL, Intelligent Micro Patterning, LLC), UV-vis spectrophotometer (Cary 5000, Varian), haze meter (COH 400, Nippon Denshoku), field emission scanning electron microscope (FE-SEM), and digital multimeter (Fluke 87 True RMS Digital Multimeter). Materials include AgNWs, PES substrate, photoresist AZ5214, developer AZ-300MIF, and Ag paste.
4:Experimental Procedures and Operational Workflow:
The process involves spin-coating photoresist on AgNWs, soft baking at 110 °C for 1 min, UV exposure (248 nm) for 1 min, development in AZ-300MIF for varying times (3, 120, 300 s), and hard baking at 110 °C for 90 s. Optical and electrical measurements are conducted post-processing.
5:Data Analysis Methods:
Optical properties (transmittance, haze, yellow index) are measured using specified instruments. Morphological features are analyzed via FE-SEM and ImageJ software for diameter distribution. Electrical properties (sheet resistance, resistance between pads) are measured using a multimeter, with data analyzed to assess stability under high-temperature conditions.
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digital multimeter
Fluke 87 True RMS
Fluke
Measures the electrical properties (resistance) of the AgNW electrodes.
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photolithography system
SF-100 XCEL
Intelligent Micro Patterning, LLC
Used for UV exposure in the photolithography process to pattern the photoresist on AgNW substrates.
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UV-vis spectrophotometer
Cary 5000
Varian
Measures the transmittance characteristics of the AgNW substrates.
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haze meter
COH 400
Nippon Denshoku
Measures the haze and yellow index (b*) of the electrodes.
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field emission scanning electron microscope
FE-SEM
Used for morphological examination of the AgNW substrates.
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silver nanowires
C3NANO
Used as the electrode material, deposited on PES substrates.
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photoresist
AZ5214
Used for selective passivation of AgNWs via spin-coating and photolithography.
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developer
AZ-300MIF
Used to remove UV-exposed photoresist during development.
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