1：Experimental Design and Method Selection:

The study involved synthesizing a novel indium-based MOF (1) using solvothermal methods with anthracene-based linkers. Photocatalytic oxidation reactions of benzylamines and sulfides were conducted under visible light irradiation using molecular oxygen or hydrogen peroxide as oxidants. The mechanism was investigated through quenching experiments and EPR trapping studies to identify reactive oxygen species.

2：Sample Selection and Data Sources:

Benzylamine and sulfide derivatives with various substituents were used as substrates. The MOF was synthesized from In(NO3)3·4H2O and ADBEB linker. Data were collected from GC-MS, EPR, UV-vis, PXRD, and other spectroscopic techniques.

3：List of Experimental Equipment and Materials:

Equipment included autoclave for synthesis, Bruker SMART APEXII CCD diffractometer for X-ray diffraction, Rigaku SmartLab X-ray diffractometer for PXRD, HITACHI U-4100 and SHIMADZU UV-2550 spectrophotometers for UV-vis, ASAP 2020 for BET surface area, JES-FA 200 EPR spectrometer, HITACHI SU8010 SEM, Mattson Alpha-Centauri FTIR spectrometer, PerkinElmer TGA-7 thermogravimetric analyzer, FLSP920 fluorescence spectrometer, AGILENT-6890/5973 GC-MS, and a 300 W xenon arc lamp with cut-off filter for photocatalytic experiments. Materials included In(NO3)3·4H2O, ADBEB linker, DMF, HCl, DMSO, CHCl3, MeOH, H2O2, O2, and various amines and sulfides.

4：Experimental Procedures and Operational Workflow:

Synthesis of MOF 1 via solvothermal reaction at 85°C for 3 days. Photocatalytic reactions involved mixing MOF with substrate and oxidant in solvent, stirring under specific atmosphere, and irradiating with visible light. Samples were taken at intervals, filtered, and analyzed by GC-MS. EPR studies used DMPO and TEMP as trapping agents under light irradiation.

5：Data Analysis Methods:

Conversion and selectivity were determined by GC-MS. EPR spectra were analyzed to detect radicals. Other characterizations used standard software for data refinement and analysis.