研究目的
To investigate the modification of micro-structural, morphological, optical and electrical characteristics of CdS thin films by different doses of gamma irradiation on CdS/p-Si heterostructure.
研究成果
Gamma irradiation at various doses modifies the structural, optical, and electrical properties of CdS/p-Si heterostructures. It reduces crystallinity, increases particle size, causes a red shift in band gap, induces yellow emission in photoluminescence, and alters electrical parameters such as increased barrier height and series resistance with dose. These changes are attributed to radiation-induced defects and their effects on charge carrier dynamics, highlighting the potential for tuning heterojunction properties through controlled irradiation.
研究不足
The study is limited to gamma irradiation effects on CdS/p-Si heterostructures; other types of radiation or materials were not explored. The dose range (up to 80 kGy) may not cover all possible irradiation effects, and the mechanisms of defect creation and annealing could be further optimized. Sample uniformity and reproducibility might be affected by experimental conditions.
1:Experimental Design and Method Selection:
The study involved fabricating CdS/p-Si heterostructures using thermal evaporation and exposing them to gamma irradiation at various doses (0-80 kGy) to analyze changes in structural, optical, and electrical properties. Theoretical models like Kubelka-Munk theory for band gap calculation and Anderson model for energy band diagram were employed.
2:Sample Selection and Data Sources:
CdS thin films were deposited on p-type Si substrates. Samples were irradiated with gamma doses of 10, 20, 40, and 80 kGy. Data were collected from XRD, SEM, UV-Vis DRS, PL, and I-V measurements.
3:List of Experimental Equipment and Materials:
Equipment included thermal evaporator for deposition, gamma source (60Co, MDS Nordion Model SC220E), X-ray diffractometer (Bruker D8 Discover), spectrofluorometer (JESCO FP-8200), UV-Vis spectrometer (JASCO-V 670), and semiconductor characterization system (KEITHLEY 4200 SCS/CVU). Materials included CdS powder (99.999% pure, Sigma Aldrich), p-Si substrates, and aluminum for electrodes.
4:999% pure, Sigma Aldrich), p-Si substrates, and aluminum for electrodes.
Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: CdS films were deposited by thermal evaporation at 200°C and 10^-5 Torr pressure, with thickness controlled to 300 nm. Gamma irradiation was performed at specified doses. Post-irradiation, Al electrodes were deposited. Structural, optical, and electrical measurements were conducted using the listed equipment under standard conditions (e.g., room temperature for PL and I-V).
5:Data Analysis Methods:
XRD data were analyzed for crystallite size, micro-strain, and dislocation density using standard formulas. Optical band gap was determined from diffuse reflectance spectra using Kubelka-Munk theory and Tauc's plot. I-V characteristics were analyzed to extract ideality factor, saturation current, barrier height, and series resistance using Cheung's method and standard diode equations.
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