研究目的
To fabricate and study the electromagnetic wave absorption properties of quartz ceramics with uniform and gradient distributions of BaTiO3, aiming to enhance absorption for applications in anti-electromagnetic interference and stealth technologies.
研究成果
G-SO-BTO ceramics with gradient BTO distribution exhibit significantly lower electromagnetic reflectivity (down to -13.1 dB) compared to U-SO-BTO, due to reduced impedance mismatch and effective wave absorption. They are suitable for high-temperature applications with good mechanical properties, suggesting potential for use in electromagnetic shielding and stealth technologies.
研究不足
The study is limited to specific BTO content ranges and sample thicknesses; potential oxidation or demagnetization issues at elevated temperatures are noted for other materials but not fully addressed for BTO in this context. Optimization of layer thickness and distribution could be further explored.
1:Experimental Design and Method Selection:
The study involves fabricating U-SO-BTO and G-SO-BTO ceramics using cold pressing and sintering techniques, with a gradient distribution achieved by layering powder blends with increasing BTO content. The rationale is to compare electromagnetic wave absorption properties between uniform and gradient distributions.
2:Sample Selection and Data Sources:
Samples are prepared with varying BTO content (0-11 wt%) and thicknesses (6, 8, 10 mm for U-SO-BTO; layer thicknesses of 1.0, 1.5, 2.0 mm for G-SO-BTO). Data on electromagnetic reflectivity, microstructure, linear shrinkage, and flexural strength are collected.
3:0, 5, 0 mm for G-SO-BTO). Data on electromagnetic reflectivity, microstructure, linear shrinkage, and flexural strength are collected.
List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Materials include quartz (SiO2, 99.5 wt%, 100 mesh), calcium sulphate (CaSO4, 99.9 wt%, 800 mesh), talc (Mg3[Si4O10](OH)2, 99.5 wt%, 200 mesh), albite (NaAlSi3O8, 95.0 wt%, 400 mesh), microcline (KAlSi3O8, 95.0 wt%, 600 mesh), and BaTiO3 (BTO, 99.5 wt%, 0.5 μm). Equipment includes a planetary ball grinder, steel mould for pressing, sintering furnace, vector network analyzer (VNA, N5245A, Agilent, USA), scanning electron microscope (SEM, JSM–7610F, JEOL, Japan), energy dispersive X-ray spectrometer (EDS), and three-point bending test machine (WDW-50, Hensgrand Instrument Co., Ltd. Jinan, China).
4:5 wt%, 100 mesh), calcium sulphate (CaSO4, 9 wt%, 800 mesh), talc (Mg3[Si4O10](OH)2, 5 wt%, 200 mesh), albite (NaAlSi3O8, 0 wt%, 400 mesh), microcline (KAlSi3O8, 0 wt%, 600 mesh), and BaTiO3 (BTO, 5 wt%, 5 μm). Equipment includes a planetary ball grinder, steel mould for pressing, sintering furnace, vector network analyzer (VNA, N5245A, Agilent, USA), scanning electron microscope (SEM, JSM–7610F, JEOL, Japan), energy dispersive X-ray spectrometer (EDS), and three-point bending test machine (WDW-50, Hensgrand Instrument Co., Ltd. Jinan, China).
Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Powder blends are prepared by mixing and ball-milling. For G-SO-BTO, layers are spread sequentially with increasing BTO content, cold pressed at
5:4 MPa, and sintered at 1150°C for 2 hours. Samples are machined for testing:
large samples for electromagnetic reflectivity, small samples for SEM and flexural strength.
6:Data Analysis Methods:
Electromagnetic reflectivity is measured using VNA and NRL testing system in 8.0-18.0 GHz range. Microstructure is observed via SEM and EDS. Linear shrinkage and flexural strength are calculated and tested statistically.
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