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The AOTF-based NO<sub>2</sub> camera

DOI:10.5194/amt-9-6025-2016 期刊:Atmospheric Measurement Techniques 出版年份:2016 更新时间:2025-09-23 15:22:29
摘要: The abundance of NO2 in the boundary layer relates to air quality and pollution source monitoring. Observing the spatiotemporal distribution of NO2 above well-delimited (flue gas stacks, volcanoes, ships) or more extended sources (cities) allows for applications such as monitoring emission fluxes or studying the plume dynamic chemistry and its transport. So far, most attempts to map the NO2 field from the ground have been made with visible-light scanning grating spectrometers. Benefiting from a high retrieval accuracy, they only achieve a relatively low spatiotemporal resolution that hampers the detection of dynamic features. We present a new type of passive remote sensing instrument aiming at the measurement of the 2-D distributions of NO2 slant column densities (SCDs) with a high spatiotemporal resolution. The measurement principle has strong similarities with the popular filter-based SO2 camera as it relies on spectral images taken at wavelengths where the molecule absorption cross section is different. Contrary to the SO2 camera, the spectral selection is performed by an acousto-optical tunable filter (AOTF) capable of resolving the target molecule's spectral features. The NO2 camera capabilities are demonstrated by imaging the NO2 abundance in the plume of a coal-fired power plant. During this experiment, the 2-D distribution of the NO2 SCD was retrieved with a temporal resolution of 3 min and a spatial sampling of 50 cm (over a 250 × 250 m2 area). The detection limit was close to 5 × 1016 molecules cm?2, with a maximum detected SCD of 4 × 1017 molecules cm?2. Illustrating the added value of the NO2 camera measurements, the data reveal the dynamics of the NO to NO2 conversion in the early plume with an unprecedent resolution: from its release in the air, and for 100 m upwards, the observed NO2 plume concentration increased at a rate of 0.75–1.25 g s?1. In joint campaigns with SO2 cameras, the NO2 camera could also help in removing the bias introduced by the NO2 interference with the SO2 spectrum.
作者: Emmanuel Dekemper,Jurgen Vanhamel,Bert Van Opstal,Didier Fussen
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To develop and demonstrate a new passive remote sensing instrument for measuring 2-D distributions of NO2 slant column densities with high spatiotemporal resolution, overcoming limitations of existing methods like grating spectrometers.

The AOTF-based NO2 camera successfully measures 2-D NO2 distributions with high spatiotemporal resolution, enabling detailed study of plume dynamics and chemistry. It demonstrates capabilities for emission monitoring and correction of SO2 camera data. Future improvements include temperature stabilization and use of CMOS detectors for higher temporal resolution.

The instrument has a temporal resolution of 3 minutes, which is slower than SO2 cameras (1 Hz). Wavelength drift due to temperature changes can introduce uncertainties in cross-section measurements. The need for homogeneous background illumination and optically thin plumes limits applicability in certain conditions. Detection limit is around 5e16 molecules cm-2, which may not suffice for very low concentrations.

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